首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   196篇
  免费   33篇
  国内免费   36篇
化学   103篇
晶体学   3篇
力学   2篇
综合类   3篇
数学   30篇
物理学   124篇
  2023年   2篇
  2022年   3篇
  2021年   3篇
  2020年   3篇
  2019年   2篇
  2018年   5篇
  2017年   2篇
  2016年   5篇
  2015年   8篇
  2014年   10篇
  2013年   13篇
  2012年   5篇
  2011年   11篇
  2010年   11篇
  2009年   13篇
  2008年   18篇
  2007年   19篇
  2006年   7篇
  2005年   18篇
  2004年   14篇
  2003年   5篇
  2002年   8篇
  2001年   12篇
  2000年   13篇
  1999年   12篇
  1998年   7篇
  1997年   4篇
  1996年   1篇
  1995年   3篇
  1994年   1篇
  1993年   2篇
  1992年   4篇
  1991年   2篇
  1990年   2篇
  1989年   2篇
  1987年   4篇
  1986年   1篇
  1985年   2篇
  1984年   1篇
  1982年   1篇
  1980年   2篇
  1979年   1篇
  1973年   1篇
  1972年   1篇
  1967年   1篇
排序方式: 共有265条查询结果,搜索用时 15 毫秒
1.
本文对广义风险过程中的渐近方差作了非参数估计,得出并证明了两个定理,为广义风险过程中破产概率的区间估计作了理论准备.  相似文献   
2.
标题化合物C23H25对O3Cl是由邻氯苯甲醛与5,5-二甲基1,3-环己二酮在N,N-二甲基甲酸腹中反应而得。结构通过单晶X-射线衍射法确定,其晶体属于单科晶系,空间群=1632。晶体结构用直接法解出,使用全矩阵最小二乘法对原子参数进行修正,最后的偏离因子为R=0.054,Rw一0.063。在晶体结构中,吡喃环与苯环之间的两面角为92.43°。  相似文献   
3.
8,8"-Biflavonoidsareantw0rtantclass0fbiflavonoids.Asasystematicresearchofthe8,8"-biflav0noids,wehavepreviouslyreportedthestudyonthereactionof2'-hydroxychaloneswithl2-H2SO4-DMSOsystem.'InthispaPer,thesynthesisof5,5",7,7',-tetTameth0xy-8,8"-biflavonela2,4,4",7,7"-tetramethoxy-8,8"-biflavone1b',4',4",,5,5,',7,7"-hexamethoxy-8,8"-biflav0ne1c4and4,4"-dibenZyl0xy-5,5",7,7"-tetramothoxy-8,8"-biflavoneldisreported.ThesyntheticmethodisshownintheSchemebelow.2-Hydroxyacet0phenonescondensedwithsubsti…  相似文献   
4.
高效液相色谱氮杂冠醚键合固定相的合成及性能研究   总被引:2,自引:0,他引:2  
我们曾用γ-氯丙基键合硅胶(CPS),在氢化钠(NaH)作用下合成了3-(氮杂-18-冠-6)丙基键合固定相(BCP)[1].该固定相对碱基、核苷酸、硝基苯酚等有较好的分离选择性,但由于NaH对硅胶基质腐蚀作用较大,导致BCP柱效及渗透性较低.本文采...  相似文献   
5.
制备了用于分离C60和C70的2,4,6-三硝基苯酚改性锆铝复合氧化物高效液相色谱固定相,考察了流动相中甲苯的含量、柱温及流速对C60和C70分离的影响,同时比较了酸腐蚀前后锆铝复合氧化物基质对分离的影响,结果表明,2,4,6-三硝基苯酚改性酸腐蚀后锆铝复合氧化物填料对富勒烯表现出较强的分离能力,具有作为富勒烯制备分离的潜力。  相似文献   
6.
The Diels-Alder reaction of spirolactones with cyclopentadiene afforded the adduct with high pi-facial selectivity; a hydrophilic analogue of scyphostatin was synthesized from the Diels-Alder adduct.  相似文献   
7.
酸性化合物在十二胺-N; N-二亚甲基膦酸改性氧化锆固定相上的分离;氧化锆;色谱固定相;十二胺-N; N-二亚甲基膦酸  相似文献   
8.
The purpose of this study was to evaluate the bitterness of 18 different antibiotic and antiviral drug formulations, widely used to treat infectious diseases in children and infants, in human gustatory sensation tests and using an artificial taste sensor. Seven of the formulations were found to have a bitterness intensity exceeding 1.0 in gustatory sensation tests (evaluated against quinine as a standard) and were therefore assumed to have an unpleasant taste to children. The bitterness intensity scores of the medicines were examined using suspensions in water or an acidic sports drink. In the case of three macrolide antibiotic formulations containing erythromycin (ERYTHROCIN dry syrup), clarithromycin (CLARITH dry syrup for pediatric), and azithromycin (ZITHROMAC fine granules for pediatric use), the bitterness intensities of suspensions in acidic sports drinks were dramatically enhanced compared with the corresponding scores of suspensions in water. This enhancement could be predicted using the taste sensor. On the other hand, a reduction of bitterness intensity was observed for an acidic sports drink suspension of an amantadine product (SYMMETREL fine granules) compared with an aqueous suspension. This reduction in bitterness could also be predicted using the taste sensor output value. Thus, the taste sensor could predict whether or not suspension in an acidic sports drink would enhance or reduce the bitterness intensity of pediatric drug formulations, compared with suspensions in water.  相似文献   
9.
Development of new or improved methods for the asymmetric preparation of chiral propargylic alcohols has gained considerable significance during the past years because they are useful building blocks for the synthesis of many biologically active compounds and natural products.[1] A series of chiral tridentate ligands were conveniently synthesized from amino acids with good yields (Scheme 1).[2] A preliminary study of the enantioselective alkynylation of benzaldehyde catalyzed by this chiral tridentate ligand was carried out and up to 83% ee of chiral propargyl alcohols was obtained (Table 1 ). A further investigation of the tridentate ligand is currently underway.  相似文献   
10.
A simple, selective, and sensitive method for the simultaneous determination of anions (sulfate, nitrate, and chloride) and cations (sodium, ammonium, potassium, magnesium, and calcium) in acid rain waters was developed using ion-exclusion/ cation-exchange chromatography with conductimetric detection. A weakly acidic cation-exchange resin column (Tosho TSKgel OA-PAK-A) and a sulfosalicylic acid-methanol-water eluent was used. With a mobile phase comprising 1.25 mM sulfosalicylic acid in methanol-water (7.5:92.5) at 1.2 ml/min, simultaneous separation and detection of the above anions and cations was achieved in about 30 min. Linear calibration plots of peak area versus concentration were obtained over the concentration ranges 0-1.0 mM for anions (R=0.9991) and 0-0.5 mM for cations (R=0.9994). Detection limits calculated at S/N=3 ranged from 4.2 to 14.8 ppb for the anions and from 2.4 to 12.1 ppb for the cations. The reproducibility of retention times was 0.14-0.15% relative standard deviation (RSD) for anions and 0.18-0.31% for cations, and reproducibility of chromatographic peak areas was 1.22-1.75% RSD for anions and 1.81-2.10% for cations. The method was applied successfully to the simultaneous determination of anions and cations in aerosols transported from mainland China to central Japan, as determined by a meteorological satellite data analyzer.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号