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1.
Natalia L. Calvo Sebastian O. SimonettiRubén M. Maggio Teodoro S. Kaufman 《Analytica chimica acta》2015
Exposure of cimetidine (CIM) to dry heat (160–180 °C) afforded, upon cooling, a glassy solid containing new and hitherto unknown products. The kinetics of this process was studied by a second order chemometrics-assisted multi-spectroscopic approach. Proton and carbon-13 nuclear magnetic resonance (NMR), as well as ultraviolet and infrared spectroscopic data were jointly used, whereas multivariate curve resolution with alternating least squares (MCR-ALS) was employed as the chemometrics method to extract process information. It was established that drug degradation follows a first order kinetics. 相似文献
2.
Jonathan M. Levin Lawrence L. Wald Marc J. Kaufman Marjorie H. Ross Luis C. Maas Perry F. Renshaw 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):292-295
Residual effects of an initial bolus of gadolinium contrast agent have been previously demonstrated in sequential dynamic susceptibility contrast MR experiments. While these residual effects quickly reach a saturation steady state, their etiology is uncertain, and they can lead to spurious estimates of hemodynamic parameters in activation experiments. The possible influence ofT1effects is now investigated with experiments in whichT1weighting is varied as well as with serial regionalT1measurements. Little evidence for significant residualT1effects is found, suggesting instead that susceptibility effects underlie these observations. An initial saturation dose of contrast agent minimizes this effect. 相似文献
3.
R. Kaufman 《Israel Journal of Mathematics》1989,67(1):117-122
A closed setE is constructed so thatA∼(E) is an inseparable Banach space but its maximal ideal space isE.
Supported in part by the National Science Foundation. 相似文献
4.
A short introduction of Hamilton, Cartan and Generalized Hamilton spaces is provided. The Hamilton--Jacobi equations are deduced by variational calculus. 相似文献
5.
A three-step synthesis of grisan (spiro[benzofuran-2(3H)-1′-cyclohexane]), using methoxymethoxybenzene and 1-chloromethylcyclohexene as starting materials, is described. 相似文献
6.
Radu Miron 《Reports on Mathematical Physics》2004,54(2):131-147
The Randers spaces RFn were introduced by R. S. Ingarden. They are considered as Finsler spaces Fn = (M, α + β) equipped with the Cartan nonlinear connection. In the present paper we define and study what we call the Ingarden spaces, I Fn, as Finsler spaces I Fn = (M, α + β) equipped with the Lorentz nonlinear connection. The spaces R Fn and I Fn are completely different. For I Fn we discuss: the variational problem, Lorentz nonlinear connection, canonical N-metrical connection and its structure equations, the Cartan 1-form ω, the electromagnetic 2-form tF and the almost symplectic 2-form 0. The formula dω = F+θ is established. It has as a consequence the generalized Maxwell equations. Finally, the almost Hermitian model of I Fn is constructed. 相似文献
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9.
Vibrational chemiluminescence in the Δν1 = Δν3 = ?1 band of NO2 is observed both in the O + NO and O3 + NO reactions and shown to be emitted by molecules with up to 11 000 cm?1 of vibrational energy. Quenching rate constants of NO23 are estimated ranging from about 6 × 10?14 for Ar to about 3 × 10?12 cm3 s?1 for NO2. The ratio of vibrational to electronic emission is 0.06 ± 0.03 for O + NO and 5.3 ± 1.0 for O3 + NO. It is suggested that vibrationally excited NO2 is a major product of that channel of the O3 + NO reaction which forms ground-state NO2(2A1) directly. 相似文献
10.
Michael Michman Vered R. Kaufman Sophia Nussbaum 《Journal of organometallic chemistry》1979,182(4):547-553
Methyltris(triarylphosphine)cobalt (Ar3P)3CoCH3, decomposes in solutions of THF, benzene or chlorobenzene to yield biaryls. Coupling to biaryls occurs at the ring carbon originally bonded to phosphorus. Mixed biaryls are obtained from crossover reactions of complexes bearing different triarylphosphine ligands and reactions of complexes with free triarylphosphines. 相似文献