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排序方式: 共有292条查询结果,搜索用时 62 毫秒
1.
High mobility of dithiophene-tetrathiafulvalene single-crystal organic field effect transistors 总被引:1,自引:0,他引:1
Mas-Torrent M Durkut M Hadley P Ribas X Rovira C 《Journal of the American Chemical Society》2004,126(4):984-985
Single-crystal field effect transistors of the organic semiconductor dithiophene-tetrathiafulvalene (DT-TTF) were prepared by drop casting. Long, thin crystals connected two microfabricated gold electrodes, and a silicon substrate was used as a back gate. The highest hole mobility observed was 1.4 cm2/Vs, which is the highest reported for an organic semiconductor not based on pentacene. A high ON/OFF ratio of at least 7 x 105 was obtained for this device. 相似文献
2.
Elena Laukhina Vladislava Tkacheva Salavat Khasanov Leokadia Zorina Jordi Gómez-Segura Angel Pérez del Pino Jaume Veciana Vladimir Laukhin Concepció Rovira 《Chemphyschem》2006,7(4):920-923
Temperature has great impact on the structure and size of the linked crystallites of the conducting topmost layer formed at the surface of a polycarbonate film via the reaction BEDT-TTF+IBr [BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene]. We show that fine temperature control permits formation of a semiconducting topmost layer of alpha'-(BEDT-TTF)(2)(I(x)Br(1-x))(3) crystallites with either micro- or nanometre size, a result that opens a route to miniaturized conducting plastic materials. 相似文献
3.
The self-assembly mechanisms of polyoxometalates (POMs) are still a matter of discussion owing to the difficult task of identifying all the chemical species and reactions involved. We present a new computational methodology that identifies the reaction mechanism for the formation of metal-oxide clusters and provides a speciation model from first-principles and in an automated manner. As a first example, we apply our method to the formation of octamolybdate. In our model, we include variables such as pH, temperature and ionic force because they have a determining effect on driving the reaction to a specific product. Making use of graphs, we set up and solved 2.8 × 105 multi-species chemical equilibrium (MSCE) non-linear equations and found which set of reactions fitted best with the experimental data available. The agreement between computed and experimental speciation diagrams is excellent. Furthermore, we discovered a strong linear dependence between DFT and empirical formation constants, which opens the door for a systematic rescaling.The self-assembly mechanisms of polyoxometalates (POMs) are still a matter of discussion owing to the difficult task of identifying all the chemical species and reactions involved. The POMSimulator deals with that complexity in an automated manner. 相似文献
4.
Maspoch D Catala L Gerbier P Ruiz-Molina D Vidal-Gancedo J Wurst K Rovira C Veciana J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(16):3635-3645
Investigation of the transmission of magnetic interactions through hydrogen bonds has been carried out for two different benzoic acid derivatives which bear either a tert-butyl nitroxide (NOA) or a poly(chloro)triphenylmethyl (PTMA) radical moiety. In the solid state, both radical acids formed dimer aggregates by the complementary association of two carboxylic groups though hydrogen bonding. This association ensured that atoms with most spin density are separated from one another by more than 15 A. Thus, no competing through-space magnetic exchange interactions are expected in these dimers and, hence, they provide good models to investigate whether noncovalent hydrogen bonds play a role in the long-range transmission of magnetic interactions. The nature of the magnetic exchange interaction and their strengths within similar dimer aggregates in solution was assessed by electron spin resonance (ESR) spectroscopy. In the case of radical NOA, low-temperature ESR experiments showed a weak ferromagnetic interaction between the two radicals in the dimer aggregates (which have the same geometry as in the solid state). In contrast, the corresponding solution ESR study performed with radical PTMA did not lead to any conclusive results, as aggregates were formed by noncovalent interactions other than hydrogen bonds. However, the bulkiness of the poly(chloro)triphenylmethyl radical prevented interdimer contacts in the solid state between regions of high spin density. Hence, solid-state measurements of the alpha phase of PTMA radical provided evidence of the intradimer interaction to confirm the transmission of a weak ferromagnetic interaction through the carboxylic acid bridges, as found for the NOA radical. Moreover, crystallization of the PTMA radical in presence of ethanol to form the beta phase of PTMA radical prevented the dimer formation; this resulted in the suppression of this interaction and provides further evidence of the magnetic exchange mechanism through noncovalent hydrogen bonds at long distances. 相似文献
5.
Let {
s,t
,(s,t
+
2
} be a white noise on
+
2
. We consider the hyperbolic stochastic partial differential equation {ie863-3} The purpose of this paper is to study the law of the solution to this equation. We analyze the existence and smoothness of the density using the tools of Malliavin Calculus. Finally we prove a large deviation principle on the space of continuous functions, for the family of probabilities obtained by perturbation of the noise in the equation.This work has been partially supported by the grant of the DGICYT No. PB 930052 and the EU Science project CT 910459. 相似文献
6.
Baudron SA Batail P Rovira C Canadell E Clérac R 《Chemical communications (Cambridge, England)》2003,(15):1820-1821
Neutral pi-conjugated molecules and their radical cations co-exist in [(EDT-TTF-CONHMe+*)4(EDT-TTF-CONHMe0)2] [Re6Se8(CN)6]4- (CH3CN)2(CH2Cl2)2 whose crystal structure reveals that, upon one-electron oxidation, an activation of the N-H and C-H hydrogen bond donor ability is coupled to a deactivation of the hydrogen bond acceptor character of the carbonyl oxygen atom: this is expressed in the supramolecular hydrogen bond pattern and, ultimately, into charge localisation and partition in the solid state. 相似文献
7.
Nam K Prat-Resina X Garcia-Viloca M Devi-Kesavan LS Gao J 《Journal of the American Chemical Society》2004,126(5):1369-1376
Reactive flux molecular dynamics simulations have been carried out using a combined QM/MM potential to study the dynamics of the nucleophilic substitution reaction of dichloroethane by a carboxylate group in haloalkane dehalogenase and in water. We found that protein dynamics accelerates the reaction rate by a factor of 2 over the uncatalyzed reaction. Compared to the thermodynamic effect in barrier reduction, protein dynamic contribution is relatively small. However, analyses of the friction kernel reveal that the origins of the reaction dynamics in water and in the enzyme are different. In aqueous solution, there is significant electrostatic solvation effect, which is reflected by the slow reorganization relaxation of the solvent. On the other hand, there is no strong electrostatic coupling in the enzyme and the major effect on reaction coordinate motion is intramolecular energy relaxation. 相似文献
8.
Mireia Segado Centellas Madeleine Piot Raphaël Salles Anna Proust Ludovic Tortech Dalil Brouri Sbastien Hupin Benjamin Abcassis David Landy Carles Bo Guillaume Izzet 《Chemical science》2020,11(40):11072
The formation of hierarchical nanostructures using preformed dumbbell-like species made of covalent organic–inorganic polyoxometalate (POM)-based hybrids is herein described. In this system, the presence of charged subunits (POM, metal linkers, and counter ions) in the complex molecular architecture can drive their aggregation, which results from a competition between the solvation energy of the discrete species and intermolecular electrostatic interactions. We show that the nature of the POM and the charge of the metal linker are key parameters for the hierarchical nanoorganization. The experimental findings were corroborated with a computational investigation combining DFT and molecular dynamics simulation methods, which outlines the importance of solvation of the counter ion and POM/counter ion association in the aggregation process. The dumbbell-like species can also form gels, in the presence of a poorer solvent, displaying similar nanoorganization of the aggregates. We show that starting from the designed molecular building units whose internal charges can be controlled by redox trigger we can achieve their implementation into soft nanostructured materials through the control of their supramolecular organization.The formation of hierarchical nanostructures using supramolecular dumbbell-like species made of organic–inorganic polyoxometalate-based hybrids is investigated by combination of SAXS and computational methods. 相似文献
9.
Summary The distribution equilibria of 3-phenyl-3-methyl-2-mercaptopropenoic acid (PhMMP), pyridine and the titanium (IV)-PhMMP complex in the presence of pyridine have been studied in the chloroform-water system. An extraction-photometric method for the determination of micro amounts of titanium has been developed. The synergistic effect of pyridine, and the influence of pH, the reagent concentration and the presence of electrolytes and masking agents on the equilibrium have been determined. From slope analysis of the distribution curves, the composition of the extracted species has been found to be Ti(OH)2(HR)2·py. The complex is extracted quantitatively. Beer's law is obeyed over the range 0.09–4.30g/ml titanium (IV) and the molar absorptivity is 1.30×1041·mole–1·cm–1 at 447 nm. The method has been applied to the determination of titanium in ceramics.
Über die Extraktion und spektrophotometrische Bestimmung von Titan(IV) mit 3-Phenyl-3-methyl-2-mercaptopropensäure mit Hilfe der synergistischen Wirkung des Pyridins
Zusammmenfassung Das Verteilungsgleichgewicht von 3-Phenyl-3-methyl-2-mercaptopropensäure (PhMMP), Pyridin und Titan-PhMMP-Komplex in Gegenwart von Pyridin wurde in einem Wasser-Chloroform-System untersucht. Eine extraktionsphotometrische Methode für die Bestimmung von Mikromengen Titan(IV) wurde ausgearbeitet. Die synergistische Wirkung des Pyridins sowie der Einfluß des pH, des Reagens und der Gegenwart von Elektrolyten und maskierenden Reagenzien in der wäßrigen Phase auf das Gleichgewicht wurden bestimmt. Aus der Richtung der Verteilungskurven wurde für den extrahierten Komplex die Zusammensetzung Ti(OH)2(HR)2·py ermittelt. Der Komplex wird quantitativ extrahiert. Das Beersche Gesetz ist von 0,09–4,30g·ml–1 Ti(IV) erfüllt, der molare Absorptionskoeffizient ist 1,13·1041·mol–1·cm–1; die Sandell-Empfindlichkeit beträgt 3,7ng·cm–2 bei 447 nm. Diese Methode wurde für die Bestimmung von Titan in keramischem Material verwendet.相似文献
10.
Andrew J. Thompson Dr. Jerome Dabin Javier Iglesias‐Fernández Dr. Albert Ardèvol Dr. Zoran Dinev Assoc. Prof. Spencer J. Williams Dr. Omprakash Bande Dr. Aloysius Siriwardena Carl Moreland Dr. Ting‐Chou Hu David K. Smith Prof. Harry J. Gilbert Prof. Carme Rovira Prof. Gideon J. Davies 《Angewandte Chemie (International ed. in English)》2012,51(44):11171-11171