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Shakir Mohammed Islam Khan Shoukat Mohamed Ajax K. Shagufta Minnat Hasan Syed Sirajul 《Transition Metal Chemistry》1999,24(5):577-580
A new series of 14–16-membered hexaazamacrocyclic complexes [ML1X2] and [ML2X2] (M = CoII, NiII, CuII and ZnII; X = Cl or NO3) have been synthesized by template condensation of phenylenediamine, primary diamines and formaldehyde solution 35% in MeOH and have been characterized by i.r., 1H-n.m.r., e.p.r., and u.v. spectroscopy as well as by magnetic susceptibility and conductivity measurements. An octahedral geometry has been suggested for all the complexes. 相似文献
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Template condensation of 1,4-phenylenediamine, formaldehyde, 1,3-diaminopropane and benzil in a 1:4:4:2, molar ratio results in the formation of a new series of binuclear decaazamacrocyclic complexes: dichloro/nitrato [1-phenyl bis(8,9-diphenyl-1,3,7,10,14 pentaazacyclo-pentadeca-7,9-diene) metal (II)], [M2LX4](M = MnII, CoII, NiII, CuII and ZnII, X = Cl or NO3), which were characterised by i.r., 1H-n.m.r., e.p.r., u.v–vis. spectral studies, conductivity and magnetic susceptibility measurements. All the complexes show octahedral geometry. 相似文献
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