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1.
Dominik Huber P. G. Anil Kumar Paul S. Pregosin Igor S. Mikhel Antonio Mezzetti 《Helvetica chimica acta》2006,89(8):1696-1715
Chloride abstraction from the half‐sandwich complexes [RuCl2(η6‐p‐cymene)(P*‐κP)] ( 2a : P* = (Sa,R,R)‐ 1a = (1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl bis[(1R)‐1‐phenylethyl)]phosphoramidite; 2b : P* = (Sa,R,R)‐ 1b = (1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl bis[(1R)‐(1‐(1‐naphthalen‐1‐yl)ethyl]phosphoramidite) with (Et3O)[PF6] or Tl[PF6] gives the cationic, 18‐electron complexes dichloro(η6‐p‐cymene){(1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl {(1R)‐1‐[(1,2‐η)‐phenyl]ethyl}[(1R)‐1‐phenylethyl]phosphoramidite‐κP}ruthenium(II) hexafluorophosphate ( 3a ) and [Ru(S)]‐dichloro(η6‐p‐cymene){(1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl {(1R)‐1‐[(1,2‐η)‐naphthalen‐1‐yl]ethyl}[(1R)‐1‐(naphthalen‐1‐yl)ethyl]phosphoramidite‐κP)ruthenium(II) hexafluorophosphate ( 3b ), which feature the η2‐coordination of one aryl substituent of the phosphoramidite ligand, as indicated by 1H‐, 13C‐, and 31P‐NMR spectroscopy and confirmed by an X‐ray study of 3b . Additionally, the dissociation of p‐cymene from 2a and 3a gives dichloro{(1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl [(1R)‐(1‐(η6‐phenyl)ethyl][(1R)‐1‐phenylethyl]phosphoramidite‐κP)ruthenium(II) ( 4a ) and di‐μ‐chlorobis{(1Sa)‐[1,1′‐binaphthalene]‐2,2′‐diyl [(1R)‐1‐(η6‐phenyl)ethyl][(1R)‐1‐phenylethyl]phosphoramidite‐κP}diruthenium(II) bis(hexafluorophosphate) ( 5a ), respectively, in which one phenyl group of the N‐substituents is η6‐coordinated to the Ru‐center. Complexes 3a and 3b catalyze the asymmetric cyclopropanation of α‐methylstyrene with ethyl diazoacetate with up to 86 and 87% ee for the cis‐ and the trans‐isomers, respectively. 相似文献
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Igor S. Mikhel Ivan A. Shuklov Detlef Selent Haijun Jiao Robert Franke 《Journal of organometallic chemistry》2011,696(19):3050-3057
Oxidative coupling of 3-(3-tert-butyl-4-hydroxyphenyl)propionic acid methyl ester (2) gave dimethyl 3,3′-(5,5′-di-tert-butyl-6,6′-dihydroxybiphenyl-3,3′-diyl)-dipropionate (1c), which upon phosphorylation/transesterification with a phosphochloridite derived from (R)-binaphthol, formed the new unsymmetrical binaphthol-bridged diphosphite 4. A rhodium catalyst based on 4 as ligand gave predominantly iso-selectivity in the hydroformylation of selected styrenes but opposite regioselectivity with 2,6-disubstituted derivatives. New chelate metal complexes (acac)RhL, PdCl2L and PtCl2L have been synthesized by reacting 4 with (acac)Rh(CO)2, PdCl2(MeCN)2 and PtCl2(COD), respectively. The structure of obtained compounds is determined based on 1H, 13C, 31P and 195Pt NMR spectroscopy and mass spectrometry data. 相似文献
4.
K. N. Mikhel’son 《Russian Journal of General Chemistry》2008,78(12):2445-2454
The review considers ionophore-based electrochemical sensors (ion-selective electrodes). In general the progress in the field is subdivided in two distinctly different trends: (1) an extensive development (enhancing of the list of ions whose concentration can be selectively measured with the corresponding new sensors) and (2) an intensive development (improvement of the analytical capabilities of already known sensors). Recent articles (mostly published after the year 2000) describing the ionophore-based ion-selective electrodes are classified and briefly characterized from this viewpoint. 相似文献
5.
M.?V.?Sokolovskaya S.?E.?LyubimovEmail author I.?S.?Mikhel K.?P.?Birin V.?A.?Davankov 《Russian Chemical Bulletin》2018,67(2):260-264
A series of phosphoramidite ligands was tested in the asymmetric hydrogenation of 4-arylsubstituted 1,3-dihydro-2H-benzodiazepine-2-ones and up to 52% ee was achieved. The effects of various factors (solvents, hydrogen pressure, and addition of phosphine ligands) on the hydrogenation were studied. 相似文献
6.
I. S. Mikhel K. N. Gavrilov A. I. Polosukhin A. I. Rebrov 《Russian Chemical Bulletin》1998,47(8):1585-1588
Reactions of phosphoramidites based on (−)-ephedrine and [(1S)-endo]-(−)-borneol with the complexes M(COD)Cl2 (M is Pd or Pt, and COD is cycloocta-1,5-diene) were studied. The formation ofcis andtrans complexes of the general formulas MCl2L2 and M2Cl2(μ-Cl)2L2 was observed. The structures of the resulting compounds were established by31P,13C, and195Pt NMR and IR spectroscopy and by plasma desorption mass spectrometry.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1627–1630, August, 1998. 相似文献
7.
The application of ion-selective electrodes (ISE) with ionophore-based membranes under galvanostatic polarization conditions
is briefly reviewed. The possibilities offered by polarization for expanding the working range of ISE and for varying their
selectivity and the type of electrode response (cationic or anionic) are discussed. 相似文献
8.
Bondarev O. G. Mikhel I. S. Tsarev V. N. Petrovskii P. V. Davankov V. A. Gavrilov K. N. 《Russian Chemical Bulletin》2003,52(1):116-121
The complex formation of bi- and tricyclic hydrophosphorane derivatives of isoleucinol with [Pt(COD)Cl2], [Rh(CO)2Cl]2, and [Rh(THF)2(COD)]+BF4
– (COD is cycloocta-1,5-diene) was investigated. In all cases, bicyclic hydrospirophosphorane selectively forms the metal chelates [M(2-PN)(X)Cl] (M = Pt, X = Cl; M = Rh, X = CO) and [Rh(2-PN)(COD)]+BF4
–. («» denotes the residue of the hydrospirophosphorane ligand, which does not contain the P and N atoms). In addition, tricyclic hydrophosphorane (L) generates the phosphoranide complexes [Pt(1-L)(COD)Cl]+Y– (Y = Cl or BF4). The structures of the new compounds were established by IR spectroscopy, 31P, 13C, 1H, 2H, 11B, 19F, and 195Pt NMR spectroscopy, and plasma-desorption and electrospray ionization mass spectrometry. The possible mechanism of coordination of hydrophosphoranes is discussed. 相似文献
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K. N. Gavrilov S. V. Zheglov I. M. Novikov V. K. Gavrilov I. A. Zamilatskov I. S. Mikhel 《Russian Chemical Bulletin》2016,65(9):2278-2285
New chiral amidophosphite and diamidophosphite ligands with exocyclic pyridyl-containing substituents were obtained. Their efficiency in the Pd-catalyzed enantioselective allylic substitution was compared: in the sulfonylation of (E)-1,3-diphenylallyl acetate with sodium p-toluenesulfinate, the ee can reach 77%; its alkylation with dimethyl malonate and amination with pyrrolidine gave up to 80% and 74% ee, respectively. The asymmetric alkylation of cinnamyl acetate with ethyl 2-oxocyclohexanecarboxylate can provide to 68% ee. The complexation of zinc(ii) 5,10,15,20-tetraphenylporphyrinate with diamidophosphite ligand and its influence on conversion and enantioselectivity of the process were studied. 相似文献