全文获取类型
收费全文 | 784篇 |
免费 | 15篇 |
国内免费 | 4篇 |
专业分类
化学 | 629篇 |
晶体学 | 11篇 |
力学 | 6篇 |
数学 | 20篇 |
物理学 | 137篇 |
出版年
2022年 | 9篇 |
2021年 | 7篇 |
2020年 | 11篇 |
2019年 | 10篇 |
2018年 | 5篇 |
2017年 | 6篇 |
2016年 | 8篇 |
2015年 | 14篇 |
2014年 | 11篇 |
2013年 | 41篇 |
2012年 | 26篇 |
2011年 | 39篇 |
2010年 | 30篇 |
2009年 | 29篇 |
2008年 | 35篇 |
2007年 | 43篇 |
2006年 | 35篇 |
2005年 | 46篇 |
2004年 | 37篇 |
2003年 | 32篇 |
2002年 | 38篇 |
2001年 | 17篇 |
2000年 | 19篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 8篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 16篇 |
1991年 | 9篇 |
1989年 | 5篇 |
1986年 | 11篇 |
1985年 | 18篇 |
1984年 | 9篇 |
1982年 | 12篇 |
1981年 | 20篇 |
1980年 | 13篇 |
1979年 | 13篇 |
1977年 | 7篇 |
1976年 | 12篇 |
1975年 | 6篇 |
1974年 | 4篇 |
1973年 | 6篇 |
1972年 | 5篇 |
1971年 | 5篇 |
1970年 | 7篇 |
1967年 | 5篇 |
1966年 | 4篇 |
排序方式: 共有803条查询结果,搜索用时 171 毫秒
1.
Hirofumi Kuroda Emi Hanaki Hironori Izawa Michiko Kano Hiromi Itahashi 《Tetrahedron》2004,60(8):1913-1920
α-Vinylfurans were obtained by phosphine-initiated cyclization of various enynes bearing a carbonyl group at the ene end in the presence of various aldehydes, in moderate to high yields. The reaction may consist of 1,6-addition of phosphine to the enynes, ring closure, and Wittig reaction between the ylid resulting from cyclization and an aldehyde. Thus, various aldehydes were able to be used in the reaction. The reaction was influenced greatly by the substituents at the acetylene position (R1) and the α-position of the carbonyl group (R3). 相似文献
2.
The effect of the cation concentration, hydrolysis temperature, and composition in the CeO2–ZrO2 system on the direct precipitation of ceria–zirconia solid solutions and the structure of the precipitates from acidic aqueous solutions of (NH4)2Ce(NO3)6 and ZrOCl2 by hydrolysis under hydrothermal conditions were investigated. Nanometer-sized (8–10 nm) ceria–zirconia solid solution particles in a composition range of 0 to 60 mol% ZrO2 were directly precipitated from the solutions with total metal cation concentration less than 0.2 mol/dm3 by simultaneous thermal hydrolysis at 150–240°C. The crystalline phase of the precipitates gradually changed from cubic and/or tetragonal to monoclinic with increasing the cation concentration of the solution from 0.2 to 0.8 mol/dm3 at the starting composition of 50 mol% ZrO2 under hydrolysis condition of 150°C for 48 h, which was attributed to decrease in the supply of hydrolyzed Ce component caused by decrease in the hydrolysis ratio of (NH4)2Ce(NO3)6. Ceria–zirconia solid solutions containing large amount of ZrO2 maintained high specific surface area and small-sized crystallite after heat-treatment at 900–1000°C for 1 h. 相似文献
3.
Michiko Tamura 《Geometriae Dedicata》1992,42(3):311-315
LetM be a complete smooth surface of constant mean curvature in the Euclidean 3-space. If there exists two helical geodesics onM through each point ofM, thenM is either a plane, a sphere, or a circular cylinder. 相似文献
4.
I Kitagawa A Matsuda T Nishimura S Hirai I Yoshioka 《Chemical & pharmaceutical bulletin》1967,15(9):1435-1437
5.
6.
7.
8.
Hiromi Matsuhashi Masakazu Oikawa Hiromi Shibata Michiko Tanaka 《Reaction Kinetics and Catalysis Letters》1998,65(2):253-258
Reversible formation of F+-centers was observed over platinum promoted sulfated zirconia in the presence and absence of hydrogen. The intensity of ESR
signal of F+-centers was increased by treatment in He stream and it was decreased rapidly by supply of hydrogen in gas phase. This behavior
seems to be related to proton spillover. 相似文献
9.
Preparation of Sr2CeO4:Eu3+,Dy3+ white luminescence phosphor particles and thin films by using an emulsion liquid membrane system 总被引:3,自引:0,他引:3
Sr(2)CeO(4) and Sr(2)CeO(4):Eu(3+),Dy(3+) phosphor particles and thin films were prepared by using an emulsion liquid membrane (ELM, water-in-oil-in-water (W/O/W) emulsion) system, containing VA-10 (2-methyl-2-ethylheptanoic acid) as extractant (cation carrier). A two-step extraction enabled efficient extraction for Sr(3+) and rare earth ions, and the resulting precursor metal oxalate particles produced in the internal water phase of the ELM system were about 60 nm in diameter. Calcination of the oxalate particles in air gave submicrometer-sized Sr(2)CeO(4) and Sr(2)CeO(4):Eu(3+),Dy(3+) particles, which showed blue and white luminescence, respectively, by UV excitation. Blue and white luminescence phosphor thin films were also prepared by soaking alumina substrates into the W/O emulsion containing precursor oxalate particles, followed by calcination in air. 相似文献
10.
Itoh T Nagata K Yokoya M Miyazaki M Kameoka K Nakamura S Ohsawa A 《Chemical & pharmaceutical bulletin》2003,51(8):951-955
Chiral 1-substituted isoquinoline derivatives, which were obtained by the reaction using alanine derivatives as chiral auxiliaries, were transformed to (S)-2,3,9,10,11-pentamethoxyhomoprotoberberine (7) and a synthetic intermediate for O-methylkreysigine (9) in good yields and high stereoselectivity. The corresponding chiral allyl derivative of isoquinoline was transformed to a pyrrolidinoisoquinoline (16) in a highly enantioselective manner. 相似文献