全文获取类型
收费全文 | 79篇 |
免费 | 0篇 |
国内免费 | 1篇 |
专业分类
化学 | 70篇 |
数学 | 8篇 |
物理学 | 2篇 |
出版年
2020年 | 1篇 |
2019年 | 1篇 |
2013年 | 1篇 |
2012年 | 2篇 |
2011年 | 2篇 |
2010年 | 5篇 |
2009年 | 1篇 |
2007年 | 3篇 |
2006年 | 1篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2002年 | 3篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1974年 | 1篇 |
1973年 | 2篇 |
1972年 | 1篇 |
1971年 | 4篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1965年 | 3篇 |
1964年 | 3篇 |
1963年 | 3篇 |
1961年 | 1篇 |
排序方式: 共有80条查询结果,搜索用时 46 毫秒
1.
Several extraction procedures are described allowing arsenic speciation in sediments. The extraction of organometallic compounds
such as dimethylarsinic acid or monomethylarsonic acid is quite simple since these compounds are stable in the different extraction
media (HCl/ HNO3, H3PO4, ammonium oxalate) and are easily released independent of the extraction mode (magnetic stirring or microwave solubilization).
Extraction yields are higher than 96% for these two arsenic forms. An HCl/HNO3 microwave solubilization procedure allows the quantitative solubilization of mineral arsenic, but the differentiation between
the two oxidation states is not possible owing to the oxidation of As(III) to As(V). Extractions with orthophosphoric acid
or ammonium oxalate allow the solubilization of mineral arsenic with extraction yields ranging from 90 to 95% and the differentiation
between As(III) and As(V). Nevertheless, the amount of As(III) is underestimated owing to its partial oxidation. The usefulness
and advantages of microwave solubilization compared with conventional extraction procedures are discussed.
Received: 17 May 1996 / Revised: 19 September 1996 / Accepted: 25 September 1996 相似文献
2.
—The results of two studies are reported. In the first study, the carotenoid pigments, β-carotene. canthaxanthin and phytoene were administered to mice after one UV-B-induced skin tumor had developed, to see if carotenoid administration would delay the development of subsequent tumors. Canthaxanthin significantly delayed the development of subsequent tumors. In the second study, the same pigments were administered starting 10 weeks before, and for 24 weeks after, exposure to a large single fluence (8 × 104 J/m2 ) of UV-B radiation, to determine the effect of the pigments on tumor development. Phytoene significantly prevented the development of tumors to this fluence of radiation. 相似文献
3.
Micheline Grignon-Dubois Jacques Dunogues Raymond Calas 《Journal of organometallic chemistry》1979,181(2):285-291
Studies of the electrophilic substitution on two 1-sila-3-cyclopentenes and their cyclopropane homologues revealed the important role of silicon and provided a new route to alkenylfluorosilanes and novel β,γ or especially γ,δ-unsaturated silylated ketones. 相似文献
4.
Abstract— Phytoene, the colorless triene precursor of β-carotene (17 mg/g body weight) or a placebo was given to guinea pigs by daily intraperitoneal injection for 14 days, after which the animals were exposed to radiation (> 280 nm). It was found that the animals receiving phytoene developed significantly less erythema to the radiation than did the animals receiving placebo. 相似文献
5.
M. Viltange 《Journal of Thermal Analysis and Calorimetry》1973,5(1):101-110
Résumé L'étude par TG, ATD, analyse chimique et IR du système Na2O2/Ga2O3 a montré qu'au début du chauffage, sous l'action de la soude, il se formait de l'hydroxogallate qui se transformait en gallate vers 130–150C. Entre 287 et 350, Na2O2 et NaOH attaquent conjointement Ga2O3. NaGaO2 obtenu possède des groupements GaO4. La sensibilité de l'ATD permet de différencier les domaines de réactivité maximale des deux composés sodiques. Audelà de 350, une nouvelle réaction de Na2O2 produit principalement du gallate à groupements GaO6. L'attaque de Ga2O3 au cours de ces différentes phases dépend essentiellement de sa variété cristalline.
Thermogravimetric, differential thermoanalytical and infrared spectroscopic studies of the system Na2O2/Ga2O3 have shown that in the reaction with sodium hydroxide hydroxogallate is formed, which transforms to gallate in the range of 130 to 150. Between 287 and 350 Na2O2 and NaOH attack Ga2O3 together, and the NaGaO2 obtained contains GaO4 groups. The DTA method permitted to distinguish the ranges of maximum reactivity of the two sodium compounds. Above 350 gallate containing GaO6 groups is mainly formed in a new reaction of Na2O2. The attack of Ga2O3 in the course of the different steps depends mainly on its crystal structure.
Zusammenfassung Thermogravimetrische, differentialthermoanalytische und infrarotspektroskopische Untersuchungen des Systems Na2O2/Ga2O3 zeigten, daß bei Einwirkung von Natriumhydroxyd Hydroxogallat gebildet wurde, das zwischen 130–150 in Gallat überging. Zwischen 287 und 350 greifen Na2O2 und NaOH gemeinsam das Ga2O3 an, das erhaltene NaGaO2 enthält GaO4 Gruppen. Durch DTA gelang es die Gebiete der maximalen Reaktivität der zwei Natriumverbindungen zu differenzieren. über 350 entsteht durch eine neue Reaktion von Na2O2 hauptsächlich Gallat mit GaO6 Gruppen. Der Aufschluß von Ga2O3 hängt während dieser verschiedenen Phasen im wesentlichen von seiner kristallinen Beschaffenheit ab.
Na2O2/Ga2O3 , , , 130–150. 287 350 Na2O2, NaOH, Ga2O3 NaGaO2 G4-. . Na2O2 350, , G6-. G23 .相似文献
6.
7.
8.
Norbert De Kimpe Roland Verhé Laurent De Buyck Niceas Schamp Micheline Charpentier-Morize 《Tetrahedron letters》1982,23(28):2853-2856
α-Chloroaldimines are arylated at the α-position under Friedel-Crafts conditions via intermediacy of α-imidoylcarbenium ions. 相似文献
9.
The stoichiometric lanthanum disulfide LaS2 presents a reversible phase transition at about 750°C. The α low-temperature form is monoclinic with the LaSe2 type. All the crystals are twinned with the same twin law (100). The cell parameters are a = 8.18, b = 8.13, c = 4.03Å, γ = 90°, space group . The β high-temperature form has the orthorhombic structure previously described with the parameters a = 8.13, b = 16.34, c = 4.14 Å; space group Pnma. The two structures are compared. 相似文献
10.
Lévêque JM Desset S Suptil J Fachinger C Draye M Bonrath W Cravotto G 《Ultrasonics sonochemistry》2006,13(2):189-193
The replacement of common organic solvents by room-temperature ionic liquids (RTILs) is a topical subject in both academia and industry. In the last decades, the number of applications for RTILs has followed an exponential curve and spilled over the boundaries of chemistry. Still, one of the main drawbacks of these compounds is their difficult access. The present ultrasound-assisted method affords a general and easy access to a large variety of room-temperature ionic liquids. 相似文献