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排序方式: 共有79条查询结果,搜索用时 31 毫秒
1.
Maly J Di Meo C De Francesco M Masci A Masojidek J Sugiura M Volpe A Pilloton R 《Bioelectrochemistry (Amsterdam, Netherlands)》2004,63(1-2):271-275
Electrochemical synthesis of nickel-nitrilotriacetic acid (Ni-NTA) chelators, for subsequent immobilization of (His)(6)-tagged proteins (Photosystem II (PSII) as model molecule), on Au or Au-graphite electrodes is compared to chemical synthesis. Results show: (i) higher Ni-NTA surface density, (ii) shorter treatment time (1-12 min vs. 16 h normally needed for self-assembled monolayer (SAM)), (iii) possibility of addressing the chelator to only one Au electrode, in a sensor micro-array. 相似文献
2.
A method to synthesize 2-phenylselenenyl-1,3-anti-diols and 2-phenyl- selenenyl-1,3-anti-azidoalcohols via hydroxy- or azido-selenenylation of trans-allylic alcohols is reported. Moreover, the first example of hydroxyl-selenenylation of an allylic azide is presented. Yields ranging from moderate to good and diastereomeric ratios up to 95:5 are achieved. 相似文献
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This paper presents an imaging method for the localization of the impact point in complex anisotropic structures with diffuse field conditions, using only one passive transducer. The proposed technique is based on the reciprocal time reversal approach (inverse filtering) applied to a number of waveforms stored into a database containing the experimental Green's function of the structure. Unlike most acoustic emission monitoring systems, the present method exploits the benefits of multiple scattering, mode conversion, and boundaries reflections to achieve the focusing of the source with high resolution. Compared to a standard time reversal approach, the optimal refocusing of the back propagated wave field at the impact point is accomplished through a "virtual" imaging process. The robustness of the inverse filtering technique is experimentally demonstrated on a dissipative stiffened composite panel and the source position can be retrieved with a high level of accuracy in any position of the structure. Its very simple configuration and minimal processing requirements make this method a valid alternative to the conventional imaging Structural Health Monitoring systems for the acoustic emission source localization. 相似文献
6.
Antonella Fontana Paolo Lo Meo Stefano Morganti Egon Rizzato Romina Zappacosta 《Tetrahedron》2008,64(4):733-740
Rate constants, kA,R, for the rearrangement of the (Z)-phenylhydrazones (1a-e) of a series of 5-alkyl-3-benzoyl-1,2,4-oxadiazoles substituted at C(5) with linear alkyl chains of different length (from C4 up to C12) into the relevant 4-acylamino-2,5-diphenyl-1,2,3-triazoles (2a-e) have been measured in dioxan/water in the base-catalyzed region (pS+ 10.5-12.6). For each substrate log kA,R are linearly related to pS+. The significant decrease of the slopes of these straight lines (from 0.96 down to 0.78) upon increasing the length of the linear alkyl chain at C(5) and that of the reactivity (down to 14-26%) upon increasing the substrate concentration suggest a decrease of the polarity of the ‘actual’ reaction medium and provide indirect evidence of the tendency of the substrates (Z)-1a-e to self-assemble. To confirm the above outcome direct evidence of the formation of self-assemblies in solution were obtained from 1H NMR and spectrofluorimetry measurements while ESI-MS experiments point out the presence of aggregated substrates also in the gas phase. 相似文献
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Paolo Lo Meo 《Tetrahedron》2009,65(10):2037-39
Complexation equilibria, in mixed water-methanol solvent media, between native β-cyclodextrin and a set of suitably selected p-nitro-aniline derivatives were studied by means of polarimetry. The effects exerted by the organic co-solvent on the conditional inclusion free energies ΔGcond0 and the differential molar optical rotations ΔΘ were thoroughly analyzed under the perspective of the enthalpy-entropy compensation effect. Experimental data suggest an intimate participation (‘dynamic co-inclusion’) of solvent molecules in the formation and in the conformational dynamics of the host-guest inclusion complex. 相似文献
9.
S.L. Angioni F. Ciampa F. Pinto G. Scarselli D.P. Almond M. Meo 《Experimental Mechanics》2016,56(6):1111-1122
The use of pulsed thermography as a non-destructive evaluation tool for damage monitoring of composite materials has dramatically increased in the past decade. Typically, optical flashes are used as external heating sources, which may cause poor defect definition especially for thicker materials or multiple delaminations. SMArt thermography is a new alternative to standard pulsed thermography as it overcomes the limitations on the use of external thermal sources. Such a novel technology enables a built-in, fast and in-depth assessment of both surface and internal material defects by embedding shape memory alloy wires in traditional carbon fibre reinforced composite laminates. However, a theoretical model of thermal wave propagation for SMArt thermography, especially in the presence of internal structural defects, is needed to better interpret the observations/data measured during the experiments. The objective of this paper was to develop an analytical model for SMArt thermography to predict the depth of flaws/damage within composite materials based on experimental data. This model can also be used to predict the temperature contrast on the surface of the laminate, accounting for defect depth, size and opening, thermal properties of material and defect filler, thickness of the component, and intensity of the excitation energy. The results showed that the analytical model gives good predictions compared to experimental data. This paper is one of the first pioneering work showing the use thermography as a quantitative non-destructive tool where defect size and depth could be assessed with good accuracy. 相似文献
10.
Ansari SA Matricardi P Meo CD Alhaique F Coviello T 《Molecules (Basel, Switzerland)》2012,17(3):2283-2297
Scleroglucan is a natural polysaccharide that has been proposed for various applications. However there is no investigation on its property variations when the molecular weight of this polymer is reduced. Scleroglucan was sonicated at two different polymer concentrations for different periods of time and the effect of sonication was investigated with respect to molecular weight variations and rheological properties. Molar mass, estimated by viscometric measurements, was drastically reduced already after a sonication for a few min. Sonicated samples were used for the preparation of gels in the presence of borate ions. The effect of borax on the new samples was investigated by recording the mechanical spectra and the flow curves. A comparison with the system prepared with the dialysed polymer was also carried out. The anisotropic elongation, observed with tablets of scleroglucan and borax, was remarkably reduced when the sonicated samples were used for the preparation of the gels. 相似文献