氧化石墨烯调控钼酸铋在可见光下选择性光催化降解环境水中的抗生素

以氧化石墨烯(GO)作为增强光催化剂活性的调节剂, 采用一步水热法制备钼酸铋/氧化石墨烯(Bi₂MoO₆/GO)异质结光催化剂, 其可见光响应拓展至570 nm, 带隙能降至2.56 eV. 当m_Bi2MoO6/m_GO=100∶1时, Bi₂MoO₆/GO(100∶1)光催化剂在可见光的辐射下, 对水溶液中四环素和喹诺酮类抗生素选择性的高效催化降解去除能力为Bi₂MoO₆的2.1倍. Bi₂MoO₆/GO(100∶1)光催化剂活性的提高依赖于范德华力作用下的二维Bi₂MoO₆纳米片-二维GO纳米片界面的紧密接触. 有效的界面接触改善了光生电子的转移和光生载流子的分离. 自由基清除实验结果表明, ?OH起主要作用. 结合高效液相色谱-质谱(HPLC-MS)法对降解产物的分析, 提出了不同光催化剂催化降解恩诺沙星具有相似的降解途径和降解产物.     

Asymptotic behavior of the reaction–diffusion model of plankton allelopathy with nonlocal delays

In this paper, we consider a reaction–diffusion model of plankton allelopathy with nonlocal delays. Using an iterative technique, the global stability of the positive steady state and the semi-trivial steady states of the system is investigated under some weaker conditions than those assumed in Tian et al. [C.R. Tian, L. Zhang and Z. Ling, The stability of a diffusion model of plankton allelopathy with atio-temporal delays, Nonlinear Anal. RWA 10 (2009) 2036–2046]. We also show that toxic substances and nonlocal delays are harmless for the stability of the positive steady state. Finally, some examples are presented to verify our main results.     

Stability of random impulsive coupled systems on networks with Markovian switching

Abstract

This article is intended to study global asymptotical stability in probability for random impulsive coupled systems on networks with Markovian switching. Two cases are considered. (1) Continuous dynamics are stable while impulses are unstable; (2) impulses are stable while continuous dynamics are unstable. To begin with, based on Lyapunov method as well as graph-theoretic technique, several new stability criteria in two cases are derived, that are, the Lyapunov-type criteria and the coefficients-type criteria. Then main results are used for a class of random impulsive coupled oscillators. Finally, the effectiveness of the obtained results is verified by numerical simulations.     

Optimization and Validation of a Headspace Solid-Phase Microextraction with Comprehensive Two-Dimensional Gas Chromatography Time-of-Flight Mass Spectrometric Detection for Quantification of Trace Aroma Compounds in Chinese Liquor (Baijiu)

The detection of trace aroma compounds in samples with complex matrices such as Chinese liquor (Baijiu) requires a combination of several methods, which makes the analysis process very complicated. Therefore, a headspace solid-phase microextraction (HS-SPME) method coupled with two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was developed for the quantitation of a large number of trace compounds in Baijiu. Optimization of extraction conditions via a series of experiments revealed that dilution of the alcohol content of 8 mL of Baijiu to 5%, followed by the addition of 3.0 g of NaCl and subsequent SPME extraction with DVB/CAR/PDMS fiber coating over 45 min at 45 °C was the most suitable. To check the matrix effects, various model Baijiu matrices were investigated in detail. The quantitative method was established through an optimized model synthetic solution, which can identify 119 aroma compounds (esters, alcohols, fatty acids, aldehydes and ketones, furans, pyrazines, sulfur compounds, phenols, terpenes, and lactones) in the Baijiu sample. The developed procedure provided high recovery (86.79–117.94%), good repeatability (relative standard deviation < 9.93%), high linearity (R² > 0.99), and lower detection limits than reported methods. The method was successfully applied to study the composition of volatile compounds in different types of Baijiu. This research indicated that the optimized HS-SPME–GC×GC-TOFMS method was a valid and accurate procedure for the simultaneous determination of different types of trace compounds in Baijiu. This developed method will allow an improved analysis of other samples with complex matrices.     

Spatiotemporal complexity in a diffusive Brusselator model

Journal of Mathematical Chemistry - Turing–Hopf bifurcation of the diffusive Brusselator model with homogeneous Neumann boundary conditions is considered in this paper. By stability analysis,...     

Patterns in the predator–prey system with network connection and harvesting policy

A diffusive predator–prey system with the network connection and harvesting policy is investigated in the present paper. The global existence and boundedness of the positive solutions to the parabolic equations are analyzed. Hereafter, a priori estimates and non-existence of the non-constant steady states are investigated for the corresponding elliptic equation. Next, we focus on the network connect model. The stability of the positive equilibrium, the Hopf bifurcation, and the Turing instability of networked system are explored. By using the multiple time scale (MTS), the direction of the Hopf bifurcation is determined. It is found that the networked system may admit a supercritical or subcritical Hopf bifurcation. For the Turing instability, the positive equilibrium will change its stability from an unstable state to a stable one with the change of the connecting probability. That is not the case in the model without network structure. Theoretical results also show that the model can create rich dynamical behaviors and numerical simulations well verify the validity of the theoretical analysis.     

Pore Water Pressure Distribution and Dissipation During Thaw Consolidation

A novel apparatus was developed for measurement of pore water pressure distribution and dissipation during thaw consolidation. Thaw consolidation tests were conducted to verify the applicability of nonlinear stress–strain relationship in 3-D large strain thaw consolidation theory. During thawing process, the measured pore pressure at different layers of soil samples increased sharply at first; when a certain value was approached, it stepped into dissipation stage. It was proved that the calculated results have a good agreement with tested results on both pore pressure distribution and dissipation. Further analysis indicated that nonlinearity of pore pressure distribution was proportionally related to thaw consolidation ratio (R), while it was opposite for thaw consolidation degree.     

贫燃/富燃循环气氛下原位活化Pd负载钙钛矿催化剂促进NOx还原消除

稀燃发动机通过提高空燃比来改善燃油经济性,减少CO2排放.但由于空燃比较高,稀燃发动机尾气中的NOx无法通过传统的三效催化技术有效消除.为了解决这一问题,适用于稀燃条件的NOx储存还原(NSR)技术得到了开发和应用.传统的NSR催化剂以贵金属Pt作为其氧化还原活性中心.Pt基催化剂具有较高的NOx消除活性,然而热稳定性...     

窄丝化工艺对第二代高温超导带材临界电流特性的影响

超导带材应用于超导电力设备时,其临界电流特性受外界交变磁场大小和方向的影响,展现出明显的各向异性.为了减小外场对超导带材的影响,本文通过窄丝化工艺将4 mm宽的高温超导带材分切成2 mm宽的高温超导细丝.本文通过冷热循环疲劳测试实验和带材显微观察两个角度相互验证,对2 mm超导细丝临界电流性能做了具体评估.创新性地提出"在窄丝化工艺中引入电镀铜工艺作为过渡来改善超导细丝临界电流特性",通过实验以及显微观察证实"电镀铜工艺能够在超导细丝表面生成铜保护层,有效降低超导细丝临界电流的衰减".本文也为后续超导细丝在复合结构的应用中提供了重要参考.