共轭二烯烃的Ziegler─Natta催化聚合

共轭二烯烃的聚合是配位阴离子聚合，双金属配合物是聚合的活性中心，控制单体的构象是控制聚合物结构的关键。单体在低值配位场稳定化能（ＬＦＳＥ）过渡金属离子，如Ｃｏ~（２＋）、Ｔｉ~（３＋）上螯合，螯合单体具有顺式构象，所得聚合物具有顺１，４结构；在中等ＬＦＳＥ的过渡金属离子，如Ｖ~（３＋）、Ｃｒ~（３＋）上配位，配位单体具有反式构象，所得聚合物具有反１，４结构或是１，２聚合物；高ＬＦＳＥ值过渡金属离子不易控制活性价态，双金属配合物不够稳定，所得聚合物分子量常较低，结构规整性也常不够理想。     

Metal–Organic Gels from Silver Nanoclusters with Aggregation-Induced Emission and Fluorescence-to-Phosphorescence Switching

Luminescent metal nanoclusters (NCs) are emerging as a new class of functional materials that have rich physicochemical properties and wide potential applications. In recent years, it has been found that some metal NCs undergo aggregation-induced emission (AIE) and an interesting fluorescence-to-phosphorescence (F-P) switching in solutions. However, insights of both the AIE and the F-P switching remain largely unknown. Now, gelation of water soluble, atomically precise Ag₉ NCs is achieved by the addition of antisolvent. Self-assembly of Ag₉ NCs into entangled fibers was confirmed, during which AIE was observed together with an F-P switching occurring within a narrow time scale. Structural evaluation indicates the fibers are highly ordered. The self-assembly of Ag₉ NCs and their photoluminescent property are thermally reversible, making the metal–organic gels good candidates for luminescent ratiometric thermometers.     

Characterization of a pectic polysaccharide from the fruit of <Emphasis Type="Italic">Ziziphus jujuba</Emphasis>

A pectic polysaccharide was isolated from the fruits of Ziziphus jujuba Mill. cv. jinsixiaozao Hort. and its structure was characterized by acid hydrolysis, methylation, and NMR spectroscopies. The purified fraction Ju-B-7 had a molecular mass of over 2000 kDa. Chemical and spectroscopic analyses indicated that Ju-B-7 is composed mainly of α-1,4-linked D-galactopyranosyluronic acid and 1,2-linked L-rhamnose with a molar ratio of 8.1:1. It can significantly stimulate spleen cell proliferation in vitro (P<0.01, 10 μmg/mL). Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 311–312, July–August, 2007.     

颗粒增强复合材料的椭圆形刚性夹杂呈双周期分布模型的反平面问题研究

在遵循复合材料中各夹杂相互影响的重要条件下，构造呈双周期分布且相互影响的椭圆形刚性夹杂模型的复应力函数，采用坐标变换和复变函数的依次保角映射方法，达到满足各个夹杂的边界条件，利用围线积分将求解方程化为线性代数方程，推导出了在无穷远双向均匀剪切，椭圆形刚性夹杂呈双周期分布的界面应力解析表达式，最后的算例分析给出了夹杂的形状对界面应力最大值(应力集中系数)的影响规律，并描绘出了曲线。     

胶补加筋板应力强度因子及胶层剪应力计算

在铆钉力法的基础上，提出计算胶接修补加筋板结构应力强度因子及胶层剪应力的解析法，对分析胶接修补的加筋板强度具有现实意义．利用影响系数，可以得到筋条、补片及蒙皮位移的表达式，根据位移协调条件，建立联立方程，从而得到胶层剪应力及铆钉力．通过解析式，计算裂纹尖端的应力强度因子，分析补片对结构修补的效果，综合考虑了筋条及补片对应力强度因子的影响．     

Carbene adduct of cyclopalladated ferrocenylimine: Efficient catalyst for the Suzuki coupling of sterically hindered aryl chlorides with a weaker base and low catalyst loading

One-pot synthesis of the N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) adduct of cyclopalladated ferrocenylimine complex 1 has been described. This complex has been successfully applied to Suzuki coupling reaction. Various aryl chlorides and boronic acids can be coupled efficiently with a mild base K₃PO₄·7H₂O and low catalyst loadings. This system has been proven to be compatible with the sterically hindered aryl chlorides and some boronic acids leading to form di- and tri-ortho-substituted biaryls in high yields.