THE PRESENCE OF PHOTOREACTIVE β-CARBOLINE FLUOROPHORES IN WEATHERED WOOL KERATIN

Abstract Solvent-cleaned Merino wool, which was enzymatically digested with protease K, displayed a fluorescence maximum at 500 nm when excited at 430 nm. The yield of this emission was approximately 15 times greater for a fiber tips digest than for a digest of the mid-length region of the same fibers.
Separation of the components in the wool tip digest by silica gel thin-layer chromatography revealed the presence of several fluorescent species. The chromatographic mobility of these species was similar to the behavior observed in a preparation of authentic 1-methyltetrahydro-P-carboline, 1,3-dicarboxylic acid.
Mass spectroscopy of the fluorescent compounds in the wool tip digest displayed molecular ions, [M + H]⁺ with m/z = 273.0890 and 257.0560, and molecular weights that define the formulae C₁₄H₁₂N₂O₄ and C₁₁H₈O₄N₂, respectively, which correspond to β-carboline 1,3-dicarboxylic acids. Mass spectral evidence also indicates the presence of two other β-carbolines.     

Urine utilisation by microbial fuel cells; energy fuel for the future

This communication reports for the first time the direct utilisation of urine in MFCs for the production of electricity. Different conversion efficiencies were recorded, depending on the amount treated. Elements such as N, P, K can be locked into new biomass, thus removed from solution, resulting in recycling without environmental pollution.     

The effect of optically-induced random anisotropic disorder on a two-dimensional electron system

We have studied the effect of optically-induced random, anisotropic disorder on the magnetoresistance of a Al_0.3Ga_0.7As/ GaAs two-dimensional electron system by exposing the heterojunction to an asymmetric laser speckle pattern. Changes in the amplitude of the Shubnikov-de Haas oscillations can be explained in terms of easy and hard conductivity paths parallel and perpendicular to the long axis of the oval speckle grains. We also observe corresponding changes in the electron scattering rates.     

Manipulating objects by discrete excitable media coupled with contact-less actuator array: Open-loop case

A two-dimensional cellular automaton (CA) model of an excitable medium is coupled with an array of micro-actuators in the form of abstract air-jets. Each cell of the CA is linked to a unique air-jet. A cell state determines the orientation and intensity of the airflow generated by the air-jet corresponding to the cell. We explore the phenomenology of an open-loop configuration in which CA cells do not sense the presence of the object being moved. Excitation waves generated in the initial stimulation of the medium, travel on the lattice and cause waves of actuation in the air-jets, resulting in changing airflow patterns. Thus, the waves of actuation move and rotate the manipulated object. We study the manipulation of three convex shapes by excitable CA, and provide the classification of various types of object motion from straight to sinuous and oscillatory trajectories. The relation between the excitation dynamic and resulting trajectories of the object will be used in future designs of hardware prototypes of massive-parallel manipulators controlled by non-linear media.