全文获取类型
收费全文 | 547篇 |
免费 | 16篇 |
国内免费 | 3篇 |
专业分类
化学 | 446篇 |
晶体学 | 5篇 |
力学 | 2篇 |
数学 | 34篇 |
物理学 | 79篇 |
出版年
2022年 | 7篇 |
2021年 | 7篇 |
2019年 | 6篇 |
2018年 | 4篇 |
2016年 | 12篇 |
2015年 | 6篇 |
2014年 | 5篇 |
2013年 | 29篇 |
2012年 | 39篇 |
2011年 | 33篇 |
2010年 | 14篇 |
2009年 | 13篇 |
2008年 | 29篇 |
2007年 | 37篇 |
2006年 | 32篇 |
2005年 | 31篇 |
2004年 | 35篇 |
2003年 | 25篇 |
2002年 | 24篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 4篇 |
1998年 | 12篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 7篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 8篇 |
1987年 | 7篇 |
1985年 | 11篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 9篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1973年 | 7篇 |
1972年 | 2篇 |
1968年 | 1篇 |
1966年 | 1篇 |
1960年 | 1篇 |
排序方式: 共有566条查询结果,搜索用时 31 毫秒
1.
2.
Takuji Hirose Kumiko Naito Megumi Nakahara Hiroaki Shitara Yoshio Aoki Hiroyuki Nohira Bruce W. Baldwin 《Journal of inclusion phenomena and macrocyclic chemistry》2002,43(1-2):87-93
Two Kemp's acid diamides were synthesized and applied to chiral amine recognition using 1H NMR analysis. One derivative based on 1-(1-naphthyl)ethylamine had good chiral recognition of six amines and was useful to determine the optical purity for three amines, i.e., methylbenzylamine, 1-(1-naphthyl)ethylamine and 1- henylpropylamine,however, the cyclohexylethylamine derivative showed little discrimination for the amines studied. Together with the results for alkylamines, it was shown that aromatic structure was important for aromatic shielding anisotropy and –– interactions between host and guest. The structure of the 1-(1-naphthyl)ethylamine derivative in solution was also considered based on 1H NMR data and computer simulation. 相似文献
3.
A poly(N-isopropylacrylamide) (PNIPAAm)-like biodegradable thermosensitive polydepsipeptide, poly[Glc-Asn(N-isopropyl)], was synthesized by introducing an isopropyl amide group into poly[Glc-Asn]. Poly[Glc-Asn(N-isopropyl)] was degraded in vitro by cleavage of the ester bonds in the main chain in water at room temperature. The non-toxic nature of the polymer and its degradation products, coupled with a cloud point at 29 degrees C in water, make this polymer attractive for biomedical implant applications. 相似文献
4.
Yamamoto T Mukai SR Endo A Nakaiwa M Tamon H 《Journal of colloid and interface science》2003,264(2):532-537
Growth of colloidal particles formed during the sol-gel transition of a resorcinol-formaldehyde (RF) solution was simulated based on the population balance equation by using the discrete-sectional model (DSM). During the early stage of the sol-gel transition, the transient change of sizes of colloidal particles estimated by this method agreed well with the previous experimental observation by dynamic light scattering (DLS), which confirmed the influence of the catalyst concentration of a starting RF solution on the growth rate of the particles. From the size distribution of colloidal particles predicted at the gelation time, the surface area of a RF hydrogel after the completion of the sol-gel transition was estimated, which coincided with the BET surface area of a RF aerogel because the porous structure of a hydrogel was maintained and few micropores were formed during supercritical drying. 相似文献
5.
Utilizing a commercially available helium-purging device and PEEK tubes for all tubing, especially for connection between the mobile phase and pump, high performance liquid chromatography with an electrochemical detector (ECD/HPLC) at the cathodic mode is a simple and precise method for the determination of p-nitrophenol (NP). Studies with cyclic and hydrodynamic voltammetry indicated that 25% aqueous MeOH containing 0.1% (v/v) CF(3)CO(2)H and -0.8 V vs. Ag/AgCl are the best mobile phase and detection potential for cathodic ECD/HPLC. With the present system, the limits of detection and determination were 0.2 and 0.25 microM, respectively, and up to 50 microM, a linear calibration curve was afforded. Within-day precisions for the analysis of 5 and 50 microM NP were 0.8 and 0.7% (n=6), respectively, and between-day precisions (n=6) for these samples were 3.5 and 2.2%, respectively. Compared with the commonly used Bessey-Lowry-Brock method, cathodic ECD/HPLC was useful for the assay of acid phosphatase in urine samples with p-nitrophenyl phosphate disodium salt as a substrate. 相似文献
6.
The effect of antimony concentration (C(Sb)/mass%) on the surface tension of molten silicon has been determined with the sessile drop method in the temperature range from 1693 to 1773 K and in the range of the oxygen partial pressure, Po(2), in an Ar atmosphere from 10(-23) to 10(-21) MPa. The results show that the surface tension of molten silicon decreases with increasing Sb concentration in the range of C(Sb)<0.9 mass%, which indicates positive adsorption of Sb in molten silicon and can be fairly described with the Szyszkowski's equation. The maximum decrease rate of surface tension is about 65 mN m(-1) (mass% C(Sb))(-1), and the temperature coefficient of surface tension, (partial differential sigma/ partial differential T)C(Sb), increases with increasing C(Sb). The evaporation of the systems was only observed between the melting points of antimony (904 K) and silicon (1683 K), and the surface tension presents no dependence on measuring time above the melting point of silicon. 相似文献
7.
Reaction of 3-methoxy- or 3-chloropyrazine 1-oxides with refluxing phosphoryl chloride in the presence of amine led to a high regioselective formation of 3-substituted 2-chloropyrazines. In contrast, the use of chloroacetyl chloride instead of phosphoryl chloride enabled different regioselectivity to yield 6-substituted 2-chloropyrazines, particularly 3-methoxycarbonylpyrazine 1-oxide was almost exclusively converted into methyl 6-chloropyrazinecarboxylate under the conditions without the amine. 相似文献
8.
Masanari KimuraRyutaro Mukai Naoko TanigawaShuji Tanaka Yoshinao Tamaru 《Tetrahedron》2003,59(39):7767-7777
Without prior activation of allyl alcohols, allylation of a variety of active methylene compounds with allyl alcohols proceeds smoothly at rt-50°C in the presence of catalytic amounts of Pd(OAc)2 (1-10 mol%), Et3B (30-240 mol%), a phosphine ligand (1-20 mol%), and a base (0 to 50-60 mol%). 相似文献
9.
10.
Yamamoto Y Yamamoto A Furuta SY Horie M Kodama M Sato W Akiba KY Tsuzuki S Uchimaru T Hashizume D Iwasaki F 《Journal of the American Chemical Society》2005,127(42):14540-14541
The oxidized octaethyltetraphenylporphyrin (1, OETPP) and the corresponding newly prepared octaisobutyltetraphenylporphyrin (3, OisoBuTPP) could be isolated from the reaction of OETPPLi2 (or OisoBuTPPLi2) with SOCl2. The X-ray analysis and the characteristic UV-vis spectra of 1 and 3 revealed that these are the first examples of 16 pi nonaromatic porphyrins. 相似文献