首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   809篇
  免费   75篇
  国内免费   113篇
化学   485篇
晶体学   34篇
力学   36篇
综合类   12篇
数学   135篇
物理学   295篇
  2023年   11篇
  2022年   13篇
  2021年   27篇
  2020年   25篇
  2019年   25篇
  2018年   21篇
  2017年   22篇
  2016年   30篇
  2015年   36篇
  2014年   43篇
  2013年   71篇
  2012年   53篇
  2011年   38篇
  2010年   55篇
  2009年   31篇
  2008年   60篇
  2007年   61篇
  2006年   37篇
  2005年   52篇
  2004年   33篇
  2003年   27篇
  2002年   31篇
  2001年   24篇
  2000年   19篇
  1999年   14篇
  1998年   15篇
  1997年   8篇
  1996年   10篇
  1995年   7篇
  1994年   12篇
  1993年   9篇
  1992年   12篇
  1991年   4篇
  1990年   11篇
  1989年   4篇
  1988年   3篇
  1987年   2篇
  1986年   4篇
  1985年   4篇
  1984年   8篇
  1983年   3篇
  1982年   3篇
  1980年   3篇
  1979年   2篇
  1978年   5篇
  1976年   3篇
  1974年   1篇
  1972年   1篇
  1965年   1篇
  1948年   1篇
排序方式: 共有997条查询结果,搜索用时 15 毫秒
1.
2.
讨论了C2(×)Cn量子系统的最大纠缠混合态,得到了Negativity纠缠度下的最大纠缠混合态的解析结果,并计算了该态在非满秩情形下的量子相对熵纠缠度.  相似文献   
3.
Based on the Lenard relations, we completely classify integrable deformations of general algebraic curves. We construct the general solution of the Lenard relation from the invariance condition with respect to an element of the Galois group of the curve. We give some examples and also some associated conservation laws. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 151, No. 3, pp. 458–469, June, 2007.  相似文献   
4.
High-spin states in196Pb have been populated using the reaction170Er(30Si,4n). The previously observed shears bands in this nucleus have been extended and some of their transitions have been reordered. They now form regular bands with band crossings. One of the bands splits into two pathways at high spin.  相似文献   
5.
6.
7.
 We study the relation of to the subspaces and quotients of Banach spaces of continuous vector-valued functions , where K is an arbitrary dispersed compact set. More precisely, we prove that every infinite dimensional closed subspace of totally incomparable to X contains a copy of complemented in . This is a natural continuation of results of Cembranos-Freniche and Lotz-Peck-Porta. We also improve our result when K is homeomorphic to an interval of ordinals. Next we show that complemented subspaces (resp., quotients) of which contain no copy of are isomorphic to complemented subspaces (resp., quotients) of some finite sum of X. As a consequence, we prove that every infinite dimensional quotient of which is quotient incomparable to X, contains a complemented copy of . Finally we present some more geometric properties of spaces. Received 8 November 2000; in revised form 7 December 2001  相似文献   
8.
Different mass analysers [(quadrupole (Q), time-of-flight (TOF) and multicollector (MC) sector-field (SF)] of ions produced in an inductively coupled plasma were evaluated for the determination of lead isotope ratios in wine samples. A population of 20 wines of different origin including two reference wines from the EC Standards, Measurement and Testing Programme with concentrations varying between 7-140 mug Pb l(-1) was investigated. Wines were analyzed directly by Q ICP MS and MC ICP MS. The poor sensitivity of the TOF instrument, further aggravated by matrix signal suppression, did not allow the acquisition of data for wine samples that contained less than 50 mug l(-1) in the direct sample introduction mode. The separation and preconcentration of lead were therefore required. The precision obtained for the (206)Pb/(207)Pb and (208)Pb/(206)Pb were similar and equal to 0.14-2.7% for Q ICP MS, 0.04-0.17% for TOF ICP MS and 0.01-0.12% for MC ICP MS. The precision for (206)Pb/(204)Pb was 0.44-5.29, 0.15-1.7, 0.08-1.6%, respectively. On the level of accuracy, the data from TOF ICP MS and MC ICP MS were in good agreement. The accuracy of Q ICP MS data was judged satisfactory in comparison with the other techniques but their poor precision was a significant obstacle on the way of using these data for the determination of the geographic origin of wine.  相似文献   
9.
酞侧基聚芳醚砜和聚芳醚酮共混物的高温流变行为   总被引:7,自引:0,他引:7  
用锥板粘度计测试了酞侧基聚芳醚砜(PES-C)和酞侧基聚芳醚酮(PEK-C)及其共混物的熔体流变行为.试样的流动活化能分别为145、133和112KJ/mol.共混物的熔体粘度显著低于PES-C和PEK-C粘度的对数加和值.并证明试样的熔体流动性和加工稳定性都已达到注射成型工艺的要求.  相似文献   
10.
Two different rehydration procedures in the liquid or gas phase have been applied to reconstruct mixed oxides derived from calcined hydrotalcite-like materials to be used as catalysts for aldol condensation reactions. The as-synthesized hydrotalcite, its decomposition product, as well as the reconstructed solids upon rehydration were characterized by XRD, N(2) adsorption, He pycnometry, FTIR, SEM, TEM, (27)Al MAS-NMR and CO(2)-TPD (TPD=temperature-programmed desorption). Compared to the Mg-Al mixed oxide rehydrated in the gas phase (HT-rg), that rehydrated in the liquid phase (HT-rl) exhibits a superior catalytic performance with respect to the aldol condensation of citral with ketones to yield pseudoionones and in the self-aldolization of acetone. The textural properties of HT-rl and HT-rg differ strongly and determine the catalytic behavior. A memory effect led to a higher degree of reconstruction of the lamellar structure when the mixed oxide was rehydrated in the gas phase rather than in the liquid phase, although liquid-phase rehydration under fast stirring produced a surface area that was 26 times greater. This contrasts to typical statements in the literature claiming a higher degree of reconstruction in the presence of large amounts of water in the medium. CO(2)-TPD shows that the number of OH(-) groups and their nature are very similar in HT-rg and HT-rl, and cannot explain the markedly different catalytic behavior. Accordingly, only a small fraction of the available basic sites in the rehydrated samples is active in liquid-phase aldol condensations. Our results support the model in which only basic sites near the edges of the hydrotalcite platelets are partaking in aldol reactions. Based on this, reconstructed materials with small crystallites (produced by exfoliation during mechanical stirring), that is, possessing a high external surface area, are beneficial in the reactions compared to larger crystals with a high degree of intraplatelet porosity.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号