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Accurate quantitation of the four lipid components in a vesicle formulation has been accomplished by selectively changing the high-performance liquid chromatographic mobile phase composition to arrive at an optimal separation requiring less than 10 min. A systematic approach to selection of the mobile phase conditions has minimized the number of experiments required to achieve the necessary separation. Relative standard deviations between one and four percent are obtained for the four lipid components. Accuracy, as measured by recovery experiments for spiked vesicle formulations, varies between one and two percent of target levels at the nominal lipid concentrations investigated. 相似文献
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Yimin Jin J. Bonilla Ye-Gang Lin J. Morgan Linda McCracken J. Carnahan 《Journal of Thermal Analysis and Calorimetry》1996,46(3-4):1047-1059
Two poly(butylene terephthalate)/polycarbonate (PBT/PC) blends with different formulations were analyzed by modulated DSC (MDSC) and conventional DSC to determine differences in crystallization behavior. A significant difference (30°C in cold crystallization temperature) between the two samples was detectable by MDSC while no significant difference was seen by conventional DSC. That indicatesthe total heat flow from MDSC is not always equivalent to the heat flow from conventional DSC as we have assumed or seen before. The reason has not been fully understood, but may be related to unusual nucleation and crystallization induced by modulation. Alternative conventional DSC methods were developed and compared to the MDSC results.Dedicated to Professor Bernhard Wunderlich on the occasion of his 65th birthdayThe authors like to thank Drs. Bernhard Wunderlich and Robert Gallucci for helpful discussion, David Shaker and Mary Parsonage for some DSC experiments. Technical support from TA Instruments is also greatly appreciated. 相似文献
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A new automated reaction-rate method for the quantitative determination of phosphorus in grains and feeds is presented. The chemical methodology has been investigated, resulting in a high analytical throughput with precise, accurate results. The phosphomolybdenum blue reaction is used for the reaction-rate determination. After digestion of the samples by the official AOAC block digestion procedure, automated instrumentation is used for precise and rapid combination of the reactants and transfer of the mixed solution to an automated spectrophotometer. The rate of formation of the product during 5 sec is automatically determined and compared with rates obtained for phosphorus standards to determine the phosphorus content of the sample. Relative standard deviations of about 0.3% are obtained and results for determinations of phosphorus in grains and feeds are accurate as indicated by comparison with the average obtained by all laboratories participating in the AAFCO check sample programme. 相似文献
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Regulatory problems caused by contamination, a frequently overlooked cause of veterinary drug residues 总被引:5,自引:0,他引:5
The occurrence of violative residues of veterinary medicines and other, unauthorised, drugs in food of animal origin is an issue of popular concern within the European Union. Violations can occur as a result of improper use of a licensed product or through the illegal use of an unlicensed substance. However, a "violative" analytical result does not necessarily mean that abuse has occurred. Contamination of animal feedingstuffs, environmental contamination and animal-to-animal transfer of drugs can also cause residue violations. This paper reviews these inadvertent causes of residues violations in food, and includes data generated using chromatographic and non-chromatographic methods of analysis. 相似文献
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<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods. 相似文献
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CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献
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John W.Grove 《数学物理学报(B辑英文版)》2010,30(2):563-594
This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described. 相似文献