X-ray determination of the mean amplitudes of vibration and debye temperatures of some rare earth monochalcogenides

The x-ray diffraction intensities of Bragg reflections have been measured at room temperature for thulium selenide, samarium sulphide, samarium selenide and samarium telluride. On the basis of a common amplitude approximation, the Debye-Waller factor, the mean amplitude of vibration and the Debye temperature have been evaluated. The values of the Debye temperatures and mean amplitudes of vibration are 176±16°K, 0·185 ± 0·017 Å (TmSe), 155 ± 7°K, 0·244 ± 0·012 Å (SmS), 153 ± 14°K, 0·221 ± 0·020 Å (SmSe) and 151 ± 20°K, 0·204 ± 0·027 Å (SmTe).     

Crosscut-Simplicial Lattices

We call a finite lattice crosscut-simplicial if the crosscut complex of every nuclear interval is equal to the boundary of a simplex. Every interval of such a lattice is either contractible or homotopy equivalent to a sphere. Recently, Hersh and Mészáros introduced SB-labelings and proved that if a lattice has an SB-labeling then it is crosscut-simplicial. Some known examples of lattices with a natural SB-labeling include the join-distributive lattices, the weak order of a Coxeter group, and the Tamari lattice. Generalizing these three examples, we prove that every meet-semidistributive lattice is crosscut-simplicial, though we do not know whether all such lattices admit an SB-labeling. While not every crosscut-simplicial lattice is meet-semidistributive, we prove that these properties are equivalent for chamber posets of real hyperplane arrangements.     

One‐dimensional chains in sodium tetraphenylphosphonium bis(2‐mercapto‐4‐methylphenolato‐O,S)oxovanadate(IV)

The title compound, Na(C₂₄H₂₀P)[V(C₇H₆OS)₂O], contains oxovanadium(IV) in a square‐pyramidal coordination geometry with a basal plane consisting of a cis‐S₂O₂ donor group. The [VO(mmp)₂]^2? (mmpH₂ = 2‐mercapto‐4‐methyl­phenol) units are linked into infinite chains by the sodium ions.     

Observation of occupation and dispersion of 2π1 associated states for CO adsorbed on Cu{100}

Angle-resolved photoemission observations of CO adsorbed on Cu{100} to form the (√2 × √2)R45° structure show emission from a CO 2π¹ related state away from the centre of the surface Brillouin zone. These observations are shown to be compatible with the anticipated dispersion of such states and with weak 2π¹ backbonding on this substrate.     

Homotopy Type of Intervals of the Second Higher Bruhat Orders

The higher Bruhat order is a poset generalizing the weak order on permutations. Another special case of this poset is an ordering on simple wiring diagrams. For this case, we prove that every interval is either contractible or homotopy equivalent to a sphere. This partially proves a conjecture due to Reiner. Our proof uses some tools developed by Felsner and Weil to study wiring diagrams.     

Direct equilibration of soil water for delta(18)O analysis and its application to tracer studies

Current methods for stable oxygen isotopic (delta (18)O) analysis of soil water rely on separation of water from the soil matrix before analysis. These separation procedures are not only time consuming and require relatively large samples of soil, but also have been shown to introduce a large potential source of error. Current research at Queen's University Belfast is focused on using direct equilibration of CO(2) with the pore water to eliminate this extraction step using the automated Multiprep system and a Micromass Prism III isotope ratio mass spectrometer (IRMS). The findings of this research indicate the method is less time consuming, more reliable, and reproducible to within accepted limits (+/-0.1% per thousand delta (18)O). In this study the direct equilibration method is used to analyse delta (18)O tracer profiles in the unsaturated zone of field soils, concurrently with chloride tracer profiles, which can be used to assess infiltration rates and mechanisms through the unsaturated zone. Copyright 1999 John Wiley & Sons, Ltd.