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1.
Masakazu Uramoto Kimie Kobinata Kiyoshi Isono Tsutomu Higashijima Tatsuo Miyazawa Ellen E. Jenkins James A. McCloskey 《Tetrahedron》1982,38(11):1599-1608
New chitin synthetase inhibitors, neopolyoxins A, B, and C were isolated from the culture filtrate of Streptomyces cacaoi subsp. asoensis. Their absolute structures have been established on the basis of chemical and spectroscopic evidence. They are structural analogs of the polyoxins. As a nucleobase, neopolyoxin C possesses uracil, while neopolyoxins A and B contain the imidazoline moiety. A ring contraction reaction of pyrimidine nucleoside into imidazoline nucleoside played a key role in the structure determination of the nucleoside moiety. A similar transformation was suggested for the biosynthesis of neopolyoxins A and B. 相似文献
2.
P. F. Crain James A. McCloskey Arthur F. Lewis Karl H. Schram Leroy B. Townsend 《Journal of heterocyclic chemistry》1973,10(5):843-847
The mass spectrum of pyrazomycin has been obtained and reveals a fragmentation pattern with several important peaks which are not normally found in the mass spectra of C-nucleosides. It has now been established, using model compounds, that these unusual fragment ions are a direct result of the juxtaposition of the exocyclic hydroxy and carboxamido groups of the aglycon. It appears that a facile elimination of ammonia and ethanol from o-hydroxycarboxamides and o-hydroxyethylesters, respectively, may be a general fragmentation reaction for aromatic heterocycles. A mass spectrum of the TMS derivative of pyrazomycin has also been obtained and factors which may result in exceptions to the empirical B+30 (M-103) rule for C-nucleosides are discussed. 相似文献
3.
Joachim G. Liehr Gareth A. Brenton John H. Beynon James A. McCloskey Wolfgang Blum Wilhelm J. Richter 《Helvetica chimica acta》1981,64(3):835-843
In isobutane chemical ionization mass spectrometry benzyl alcohol exhibits ions at m/z 147 (‘M + 39’) that arise by a loss of H2O from [M + C4H9]+, i.e. ‘M + 57’ complex ions. Electrophilic aromatic substitution of a proton at an ortho-position of neutral C6H5CH2OH with [t-C4H9]+ and, alternatively, nucleophilic substitution of H2O at the benzylic carbon in \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm C_6 H_5 CH_2}\mathop {\rm O}\limits^+ {\rm H}_2 $\end{document} with CH2?C (CH3)2 are discussed as possible pathways. Evidence in favor of the latter is derived from the analysis of C6D5CH2OH and C6H5CD2OH for the origin of the H-atoms lost in H2O. The inferred ion structure of m/z 147 is verified by mass-analyzed ion kinetic energy (MIKE.) measurements of its collision-activated (CA.) decomposition. MIKE./CA. spectra of mass-selected m/z 147 ions, once generated by (CI(i-C4H10) from benzyl alcohol and, once, from 2-methyl-4-phenyl-2-butanol match closely and, thus, reflect identical ion structures. With reference to the simple genesis of this ion from the latter precursor, the structure in question can be concluded to be \documentclass{article}\pagestyle{empty}\begin{document}$ {\rm C_6 H_5 CH_2 CH_2}\mathop {\rm C}\limits^+ ({\rm CH}_3)_2 $\end{document} . 相似文献
4.
E. V. McCloskey A. Dey R. M. Parr N. Aras A. Balogh J. Bostock A. Borell S. Krishnan G. Lobo L. L. Qin Y. Zhang S. Cvijetic V. Zaichick M. Lim-Abraham K. Bose S. Wynchank G. V. Iyengar 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(2):341-345
In 1994, the International Atomic Energy Agency (IAEA) initiated a 5-year Co-ordinated Research Project (CRP) to determine
geographical and racial differences in peak bone mineral density (BMD) in men and women aged 15-49 years. The study demonstrates
that there are distinct global differences in BMD at the hip and spine in both men and women approximating to one population
standard deviation between populations with the highest and lowest BMD. These differences persist following adjustments for
age, sex and body size. Such information is valuable in understanding the reasons for global differences in fracture rate
and predicting future trends in fracture incidence.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
5.
Mass spectra of oligonucleotides derived from collision-induced dissociation following electrospray ionization provide an effective means of sequence determination, at the 20-mer level and below. An interactive, stand-alone computer program, Simple Oligonucleotide Sequencer (SOS) has been developed for rapid oligonucleotide sequencing from mass spectra, under user control on a residue by residue basis. Modifications can be defined in any combination for the base, sugar or backbone. Sequence ladders can be independently constructed in both the 5' --> 3' directions and 3' --> 5' directions, and graphically compared for homology and overlap. A particular advantage of this method is the ability to easily erase and rebuild alternate subsequences. The program can be used for ab initio sequencing of modified or unmodified oligonucleotides, for rapid verification of sequence, and in studies of fragmentation processes of model oligonucleotide derivatives. 相似文献
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8.
Paul McCloskey Brice Jamieson Terence O’Donnell Donald Gardner Michael A. Morris Saibal Roy 《Journal of magnetism and magnetic materials》2008
Electroplating is compatible with the deposition of relatively thick layers i.e. several μm to 10s- of μm. However eddy current losses mean that thick layers will have an inferior frequency response. We have used a low content phosphorous bath together with pulse reverse plating to generate Co-rich and Co-deficient multi-nanolayers of CoP having improved saturation magnetisation and a better frequency response. The plating parameters have been optimised in order to produce a material with low loss, and a high permeability of around 700 retained up to 103 MHz for a sample with a thickness of 1.7 μm and a resistivity of 136 μΩ cm. 相似文献
9.
Nika Mahne Sara E. Renfrew Prof. Bryan D. McCloskey Dr. Stefan A. Freunberger 《Angewandte Chemie (International ed. in English)》2018,57(19):5529-5533
Solid alkali metal carbonates are universal passivation layer components of intercalation battery materials and common side products in metal‐O2 batteries, and are believed to form and decompose reversibly in metal‐O2/CO2 cells. In these cathodes, Li2CO3 decomposes to CO2 when exposed to potentials above 3.8 V vs. Li/Li+. However, O2 evolution, as would be expected according to the decomposition reaction 2 Li2CO3→4 Li++4 e?+2 CO2+O2, is not detected. O atoms are thus unaccounted for, which was previously ascribed to unidentified parasitic reactions. Here, we show that highly reactive singlet oxygen (1O2) forms upon oxidizing Li2CO3 in an aprotic electrolyte and therefore does not evolve as O2. These results have substantial implications for the long‐term cyclability of batteries: they underpin the importance of avoiding 1O2 in metal‐O2 batteries, question the possibility of a reversible metal‐O2/CO2 battery based on a carbonate discharge product, and help explain the interfacial reactivity of transition‐metal cathodes with residual Li2CO3. 相似文献
10.
G. H. Draffan R. N. Stillwell James A. McCloskey 《Journal of mass spectrometry : JMS》1968,1(5):669-685
Mass spectra of trimethylsilyl (TMS) derivatives of long chain dicarboxylic acids, hydroxy acids, cyano acids, and terminal diols, dithiols and diamines have been examined. A number of fragmentation pathways involving rearrangement of partial or intact TMS groups between the termini or remote points in the chain have been determined, using deuterium and carbon-13 labeling, and high resolution mass spectrometry. Knowledge of the occurrence of functional group migrations of this type is essential to the correct interpretation of mass spectra of TMS derivatives, which are now in wide use in mass spectrometry and gas chromatography. These data in addition provide further evidence for the general ability of remote functional groups to interact, by winding or coiling of long chains. A number of interesting doubly-charged ions are reported, in which the charges are reported, in which the charges are located at opposite ends of long chains, and for which no singly-charged counterparts are observed. 相似文献