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1.
Oil migration in filled chocolates limits shelf life due to texture changes and loss of visual appeal. Spatial and temporal
oil concentration changes of a two-layer chocolate and peanut butter filling system, which models a filled chocolate, were
monitored by magnetic resonance imaging. Formulations of chocolate varied with respect to particle size, milk fat content
and emulsifier level. Sorption-time experimental data was used to establish the best fit diffusion coefficient for a Fickian
diffusion model. On the basis of the comparison of spatial experimental data to the model, Fickian diffusion alone does not
account for oil migration.
Authors' address: Michael J. McCarthy, Department of Food Science and Technology, University of California, One Shields Avenue,
Davis, CA 95616, USA 相似文献
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Using the Ward-Takahashi identity, on-shell condition, bound Dirac equation and off-shell expansion, a reduced version of half off-shell virtual photon nucleon vertex has been suggested. The vertex are decomposed into several different order terms: the on-shell terms, first and second off-shell terms. The off-shell behaviour of the form factors is discussed in the one meson loop model. Using the reduced vertex and parametrized off-shell form factors the quasielastic response functions are calculated for several nuclei at ¦q¦–kf and for56Fe at large ¦q¦ up to 1.14 GeV/c and at ?q2=0.9 (GeV/c)2. The Coulomb sums are evaluated and a comparison of the theoretical prediction with data is given. The off-shell electron nucleon cross section is calculated and compared with the “cc1” off-shell extrapolation. 相似文献
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Jaffe DE Straub PB Adams MR Brown CN Charpak G Cooper WE Crittenden JA Finley DA Glass HD Gray R Hemmi Y Hsiung YB Hubbard JR Jonckheere AM Jöstlein H Kaplan DM Lederman LM Luk KB Maki A Mangeot P McCarthy RL Miyake K Plaag RE Rutherfoord JP Sakai Y Santiard JC Sauli F Smith SR Yoshida T Young KK 《Physical review D: Particles and fields》1989,40(9):2777-2795
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Improved high-performance liquid chromatographic assay for the determination of ethionamide in serum
A solid-phase extraction (SPE) method was developed to simplify the preparation of human serum prior to high-performance liquid chromatography of ethionamide (ETA). Octadecyl SPE columns were used. Serum constituents were removed from the column with water, and ETA was eluted with methanol. Samples were evaporated to dryness, reconstituted in mobile phase, and assayed. The method is reproducible, with a recovery of ETA of 64%, comparable to the more tedious liquid-liquid extraction method for ETA. 相似文献
8.
The rotational spectra of the three carbon chain molecules vinyldiacetylene (hex-1-ene-3,5-diyne, C(6)H(4)), vinyltriacetylene (oct-1-ene-3,5,7-triyne, C8H4), and its cyano analog vinylcyanodiacetylene (1-cyanohex-5-ene-1,3-diyne, C7H3N) have been observed for the first time by Fourier transform microwave spectroscopy of a supersonic molecular beam. The molecules were observed as products of an electrical discharge through selected precursor mixtures: ethylene/diacetylene and vinylacetylene/diacetylene for the pure hydrocarbon molecules and vinylacetylene/cyanoacetylene for vinylcyanodiacetylene. The measurements yield precise sets of rotational constants that compare very well with theoretical constants obtained by quantum chemical calculations at the B3LYP/cc-pVTZ level of theory. Since these three carbon chains are similar in structure and composition to known astronomical molecules and because of their significant polarity, all three are candidates for radio astronomical detection. 相似文献
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10.
Stanton JF Dudek J Theulé P Gupta H McCarthy MC Thaddeus P 《The Journal of chemical physics》2005,122(12):124314
The C 1B1<--X 1A1 band system of the potential interstellar species Si3C has been recorded in a silane/acetylene discharge by resonant two-color two-photon ionization spectroscopy. The origin band is located near 24,925 cm-1 (3.09 eV). Several other features in the spectrum are assigned to progressions in the Si-Si stretching modes as well as to sequence and hot band transitions. The assignment was facilitated by ab initio calculations, which also indicate that this is the strongest electronic transition of Si3C in the visible region of the spectrum. Features in the spectrum are broadened considerably (ca. 10 cm-1), and suggest an excited state lifetime of a few picoseconds. Possible reasons for the short-lived nature of the excited state are discussed. 相似文献