Generalized anisotropic scaling theory and the transverse meissner transition

We consider a depinning transition in vortex systems with columnar disorder and tilted applied magnetic fields. From scaling arguments and Monte Carlo simulations, we find that this transverse Meissner transition is governed by a fixed point which is anisotropic in all three directions. This generalization of conventional anisotropic scaling means that the correlation length in different directions diverges with different rates, and we derive exact results for the anisotropy exponents. We make predictions which can be tested in experiments on superconductors with columnar disorder.     

Acoustic characteristics of a heavy duty vehicle cooling module

Studies dedicated to the determination of acoustic characteristics of an automotive cooling package are presented. A shrouded subsonic axial fan is mounted in a wall separating an anechoic- and a reverberation room. This enables a unique separation of the up- and downstream sound fields. Microphone measurements were acquired of the radiated sound as a function of rotational speed, fan type and components included in the cooling module. The aim of the present work is to investigate the effect of a closely mounted radiator upstream of the impeller on the SPL spectral distribution. Upon examination of the SPL spectral shape, features linked specifically to the source and system are revealed. The properties of a reverberant sound field combined with the method of spectral decomposition permit an estimation of the source spectral distribution and the acoustic transfer response, respectively. Additionally, purely intrinsic acoustic properties of the radiator are scrutinized by standardized ISO methods. A new methodology comprising a dipole sound source is adopted to circumvent limitation of transmission loss measurement in the low frequency range. The sound attenuation caused by the radiator alone was found to be negligible.     

Subwavelength terahertz spin-flip laser based on a magnetic point-contact array

We present a theoretical design for a single-mode, truly subwavelength terahertz disk laser based on a nanocomposite gain medium comprising an array of normal-metal/ferromagnetic (FM) point contacts embedded in a thin dielectric layer. Stimulated emission of light occurs due to spin-flip relaxation of spin-polarized electrons injected from the FM side of the contacts. Ultrahigh electrical current densities in the contacts and a dielectric material with a large refractive index, neither condition being achievable in conventional semiconductor media, enables the thresholds of lasing to be overcome for the lowest-order modes of the disk, making single-mode operation possible.     

Rapid Method to Screen Unopened Bottles to Detect Concealed Drugs

A bottle screening method to detect smuggling drugs was developed based on a series of rapid and automated magnetic resonance measurements. Liquid alteration is detected by evaluating chemical and physical properties of the liquid, scanning the bottle with a compact, non-contact magnetic resonance probe. Chemical and molecular diffusion changes are detected by means of the magnetic resonance relaxation time. The inspection device automatically detects the presence of concealed powders dissolved in liquids in a second timescale. The non-ionizing, non-contact method effectively screens bottles, regardless of their shape, size, and color. The proposed system configuration does not require a large magnet generating uniform magnetic fields; rather it inspects the liquid using a compact probe positioned on the wall of the bottle. For a variety of samples tested, the screening does not require detailed information on the expected content of the bottle.     

Existence of the Ginzburg--Landau Vortex Number

The existence of the Ginzburg–Landau vortex number is established for any configuration with finite action. As a consequence, Bogomol'nyi's formula for the critical action is valid for any finite action configuration. Received: 16 November 1999 / Accepted: 7 July 2000     

Synthesis,characterization, and curing of hyperbranched allyl ether–maleate functional ester resins

A model two-step synthesis of a saturated hyperbranched hydroxyl-terminated ester has been developed to show a synthesis route. Three different series of hyperbranched esters with different terminations have been synthesized to relate some of their properties to their structures. This route has then been used to synthesize three different allyl ethermaleate functional hyperbranched ester resins in a two-step procedure. The resins have been characterized with respect to rheology, structure, and properties, and the differences are discussed. The allyl ether-maleate functional resins have also been studied with respect to curing performance and final film properties. © 1993 John Wiley & Sons, Inc.     

Crosslinked polystyrene with improved mechanical properties

The synthesis of some divinyl monomers—bis(vinylphenyl)ethane ( 2 ), bis(vinylbenzyloxy)hexane ( 3a ), and bis(vinylbenzyloxy)dodecane ( 3b ) is reported. Copolymers of the new monomers and styrene were evaluated as an alternative to divinylbenzene-crosslinked polymers for use as matrices and absorbents. The mechanical properties and the amount of residual double bonds in the copolymers were compared. It was found that the new copolymers, unlike the divinylbenzene-crosslinked polymers, retained their mechanical strength even at high crosslinking degrees. Stress at break values of 79, 68, and 18 N/mm² were found for the polymers crosslinked with 20 mol % of 3a, 2 , and divinylbenzene; 5, 25 and 45% of the divinyl units in these polymers were left as pendant double bonds. Porous styrene– 2 copolymers were synthesized and shown to have lower surface areas than the corresponding divinylbenzene-crosslinked polymers. The pore size distribution showed that this was due to the absence of the smallest pores which are found in the divinylbenzene-crosslinked polymers in between heavily crosslinked nodules. © 1993 John Wiley & Sons, Inc.     

Regiochemical Control and Suppression of Double Bond Isomerization in the Heck Arylation of 1-(Methoxycarbonyl)-2,5-dihydropyrrole

Arylation of 1-(methoxycarbonyl)-2,5-dihydropyrrole under standard Heck reaction conditions produces a mixture of compounds. The olefin undergoes two types of palladium-catalyzed reactions: (a) arylation to provide C-3 arylated derivatives and (b) competing double bond isomerization. Addition of silver carbonate and thallium acetate fully suppressed the isomerization, and good yields of C-3 substituted compounds were achieved after arylation with aryl halides. With regard to aryl triflates as arylating agents, addition of lithium chloride was necessary to promote the Heck reaction. This additive excluded the use of silver and thallium salts, but high regioselectivity and good yields could be obtained by employing tri-2-furylphosphine as ligand. Arylation was rendered both regioselective and enantioselective (58% ee) with 1-naphthyl triflate as substrate utilizing a (R)-BINAP/thallium acetate combination. The C-3 arylated enamides were converted further into the corresponding 3-arylpyrrolidines.     

Alkaloids ofDelphinium grandiflorum

Chemistry of Natural Compounds -