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排序方式: 共有113条查询结果,搜索用时 15 毫秒
1.
Mathilde Kammerer-Colin de Verdière 《Comptes Rendus Mathematique》2004,339(9):625-629
For generic families of vector fields or transformations, normally hyperbolic invariant products of spheres appear near partially elliptic rest points. To cite this article: M. Kammerer-Colin de Verdière, C. R. Acad. Sci. Paris, Ser. I 339 (2004). 相似文献
2.
Marc Chaperon Mathilde Kammerer-Colin De Verdière Santiago López De Medrano 《Comptes Rendus Mathematique》2006,342(5):301-305
Near partially elliptic rest points of generic families of vector fields or transformations, many types of normally hyperbolic invariant compact manifolds can appear, diffeomorphic to intersections of quadrics. To cite this article: M. Chaperon et al., C. R. Acad. Sci. Paris, Ser. I 342 (2006). 相似文献
3.
Yingyongnarongkul BE How SE Díaz-Mochón JJ Muzerelle M Bradley M 《Combinatorial chemistry & high throughput screening》2003,6(7):577-587
Advances in high throughput screening (HTS), together with the rapid progress in combinatorial chemistry, genomic and proteomic sciences have dramatically stimulated the development of a variety tools to enable the drug discovery process to become more efficient. Major future challenges in HTS include obtaining high density and good quality data based on assays that are rapid, reliable, inexpensive, sensitive, simple and miniaturised. This paper reviews the development and role of bead-based assays for HTS including DNA and single nucleotide polymorphism (SNP) assays, particularly from a multiplex perspective and evaluating the recent advances in bead-based arrays. The encoding strategies that are commonly used in bead-based assays are highlighted, while the importance of magnetic beads in genomic and proteomic purifications is discussed. In conclusion, bead-based assays offer a powerful promising approach for many aspects of drug discovery. 相似文献
4.
The kinetics of the gas-phase reaction of the NO3 radical with naphthalene have been investigated at 150 torr O2 + 590 torr N2 and 600 torr O2 + 140 torr N2 at 298 ± 2 K. Relative rate measurements were carried out in reacting NO3? N2O5-naphthalene-propene-O2? N2 mixtures by longpath Fourier transform infrared absorption spectroscopy. A rate constant ratio for the reactions of O2 and NO2 with the NO3-naphthalene adduct of k/k < 4 × 10?7 was obtained from the competition between O2 and NO2 for reaction with the NO3-naphthalene adduct and thermal decomposition of the adduct back to reactants. Atmospheric pressure ionization MS/MS measurements of the nitronaphthalene products of the NO3 radical-initiated reaction of naphthalene are consistent with the proposed reaction mechanism, and the atmospheric implications of the data are discussed. © 1994 John Wiley & Sons, Inc. 相似文献
5.
A convenient method for the conjugation of ruthenium complex on oligonucleotides and peptides through chemoselective oxime linkage is reported. Novel Ru(II) complexes sustaining an aminooxy containing ligand were prepared and efficiently coupled with the oligonucleotides and peptides functionalized with the complementary reactive aldehyde group. The method described herein could be a useful tool for preparing a broad range of metal complex-oligonucleotide and peptide conjugates. 相似文献
6.
7.
Laura Febvay Erwann Hamon Raphaël Recht Nicolas Andres Mathilde Vincent Dalal Aoudé-Werner Hervé This 《Magnetic resonance in chemistry : MRC》2019,57(9):589-602
Roasting of Coffea arabica L. seeds gives rise to chemical reactions that produce more than 800 compounds, some being responsible for the desired organoleptic properties for which the beverage called “coffee” is known. In the industry, the “roasting profile,” that is, the times and temperatures applied, is key to influence the composition of roasted coffee beans and the flavour of the beverage made from them. The impact of roasting on the chemical composition of coffee has been the subject of numerous studies, including by nuclear magnetic resonance (NMR) spectroscopy. However, the roasting equipment and profiles applied in these studies are often far from real industrial conditions. In this work, the effects of two critical technological parameters of the roasting process, namely, the “development time” (the period of time after the “first crack,” a characteristic noise due to seed disruption) and the final roasting temperature on coffee extracts, were investigated. Seeds were roasted at pilot scale according to 13 industrial roasting profiles and extracted in D2O. The extracts were analysed by 1H NMR experiments. The NMR spectra were compared using (a) quantitative analysis of main signals by successive orders of magnitude and (b) chemometric tools (principal component analysis, partial least squares and sparse-orthogonal partial least squares analysis). This allowed to identify compounds, which may serve as markers of roasting and showed that changes in chemical composition can be detected even for slight change in final temperature (~1°C) or in total roasting time (~25 s). 相似文献
8.
Wei Duo Orlandi Ezequiel Barriet Mathilde Simon Sébastien Sjöblom Johan 《Journal of Thermal Analysis and Calorimetry》2015,121(1):463-468
Journal of Thermal Analysis and Calorimetry - This paper describes the self-association of tetrameric acids (TA) and their interactions with asphaltenes using isothermal titration calorimetry. In... 相似文献
9.
Two approaches to the strigolactone tricyclic lactone skeleton 2 were investigated using ketene/ketene-iminium cycloaddition to olefins. Finally, the first enantioselective access to the four stereoisomers of 5-deoxystrigol 1 is reported using an intramolecular [2+2] cycloaddition of homochiral ketene-iminium salts 5. Very high asymmetric control was achieved with C-2 symmetric pyrrolidines as chiral auxiliary. 相似文献
10.
Mathilde Montibus Xavier Vitrac Vronique Coma Anne Loron Laetitia Pinson-Gadais Nathalie Ferrer Marie-Noëlle Verdal-Bonnin Julien Gabaston Pierre Waffo-Tguo Florence Richard-Forget Vessela Atanasova 《Molecules (Basel, Switzerland)》2021,26(2)
Fusarium graminearum is a fungal pathogen that can colonize small-grain cereals and maize and secrete type B trichothecene (TCTB) mycotoxins. The development of environmental-friendly strategies guaranteeing the safety of food and feed is a key challenge facing agriculture today. One of these strategies lies on the promising capacity of products issued from natural sources to counteract crop pests. In this work, the in vitro efficiency of sixteen extracts obtained from eight natural sources using subcritical water extraction at two temperatures was assessed against fungal growth and TCTB production by F. graminearum. Maritime pine sawdust extract was shown to be extremely efficient, leading to a significant inhibition of up to 89% of the fungal growth and up to 65% reduction of the mycotoxin production by F. graminearum. Liquid chromatography/mass spectrometry analysis of this active extract revealed the presence of three families of phenolics with a predominance of methylated compounds and suggested that the abundance of methylated structures, and therefore of hydrophobic compounds, could be a primary factor underpinning the activity of the maritime pine sawdust extract. Altogether, our data support that wood/forest by-products could be promising sources of bioactive compounds for controlling F. graminearum and its production of mycotoxins. 相似文献