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1.
Magnetization measurements in the (Dy
x
Y1−x
)Fe2 intermetallic compounds show evidence of blocking of domain wall motion. This effect is a function of concentrationx. The direction of magnetization is also dependent on the Dy concentration. We have used the Mossbauer spectroscopy of57Fe to verify the direction of magnetization in the series as a function ofx and temperature. The results show that this change in easy direction occurs at higher temperatures than those where the blocking
is detected through DC magnetization measurements.
supported by RHAE/SCT. 相似文献
2.
M. Alves Da Silva M. Helena Gil A. P. Piedade J. S. Redinha A. M. Oliveira Brett J. M. Caridade Costa 《Journal of polymer science. Part A, Polymer chemistry》1991,29(2):269-274
The immobilization of catalase on grafted membranes of poly(ethylene)-g-co-acrylic acid and poly(tetrafluoroethylene)-g-co-acrylic acid and their application in hydrogen peroxide electrochemical sensors is described. The introduction of carboxylic acid groups onto a hydrophobic support provides a good environment for subsequent enzyme immobilization. This single membrane, hydrogen peroxide sensor showed significant improvement with respect to the double membrane versions. The response is very rapid, the linear range being from 10 μM up to 6 mM, with a detection limit of 4.7 μM, and a lifetime of more than 4 months. 相似文献
3.
Scaling impacted structures 总被引:1,自引:0,他引:1
Summary The problem of non-scalability of structures under impact loads caused by strain-rate effects is solved in this article by properly correcting the impact velocity. The technique relies on the use of an alternative dimensionless basis, together with a mathematical model which allows the calculation of a correction factor for the impact velocity. This new velocity, when applied to the model, makes it to assure the satisfaction of the scaling laws. The indirect similitude method detailed here is applied to two strain-rate sensitive structures, a double plate under in-plane impact and a beam subjected to a blast load. The results show a very good agreement so that the model and a prototype made from strain rate sensitive materials behave the same.accepted for publication 3 March 2004 相似文献
4.
A.C. Marques R.M. Almeida A.R. Ramos E. Alves 《Journal of Sol-Gel Science and Technology》2004,32(1-3):287-291
Photosensitive organic-titania hybrid materials have been prepared from metal alkoxides and various organic ester compounds with
double bonds. The refractive index of the film increases with the decrease of the concentration of the organic ester compound, and the highest refractive index of 1.62 is obtained when 2-hydroxymethyl acrylate (HOA) is used as the organic ester and the molar ratio of HOA to Ti is 0.5. The material with the highest refractive index is exposed to femtosecond pulse using the multi-beam laser interference technique. After laser irradiation, the irradiated parts of the material are photopolymerized and periodic structures can be obtained by development of the unirradiated parts. In the case of laser irradiation of 120 J total energy for 5 min, the periodic structure obtained corresponds to 2D photonic crystal structure which is composed of two parts; the material with the highest refractive index and the air. 相似文献
5.
Alves Lourdes A. Felipe Maria G. A. Silva JoÃo B. Almeida E. Silva Silvio S. Prata Arnaldo M. R. 《Applied biochemistry and biotechnology》1998,70(1):89-98
Applied Biochemistry and Biotechnology - In order to remove or reduce the concentrations of toxic substances present in the sugarcane bagasse hemicellulose hydrolysate for xyloseto-xylitol... 相似文献
6.
Pyrazol-l'-ylpyridines undergo electrophilic substitution reactions (bromination, chlorination, and nitration) preferentially in the pyrazole ring. There is some evidence of the mutual influence of the pyrazole and the pyridine ring on the reactivity of the system. Some modifications of the substituents were also carried out. A dihydro derivative of a new ring system, pyrazolo[1′,2′-a]pyrido[2,1-c][l,2,4]triazine was also obtained. 相似文献
7.
Subramaniam V Alves ID Salgado GF Lau PW Wysocki RJ Salamon Z Tollin G Hruby VJ Brown MF Saavedra SS 《Journal of the American Chemical Society》2005,127(15):5320-5321
Transmembrane proteins (TMPs), particularly ion channels and receptors, play key roles in transport and signal transduction. Many of these proteins are pharmacologically important and therefore targets for drug discovery. TMPs can be reconstituted in planar-supported lipid bilayers (PSLBs), which has led to development of TMP-based biosensors and biochips. However, PSLBs composed of natural lipids lack the high stability desired for many technological applications. One strategy is to use synthetic lipid monomers that can be polymerized to form robust bilayers. A key question is how lipid polymerization affects TMP structure and activity. In this study, we have examined the effects of UV polymerization of bis-Sorbylphosphatidylcholine (bis-SorbPC) on the photoactivation of reconstituted bovine rhodopsin (Rho), a model G-protein-coupled receptor. Plasmon-waveguide resonance spectroscopy (PWR) was used to compare the degree of Rho incorporation and activation in fluid and poly(lipid) PSLBs. The results show that reconstitution of Rho into a supported lipid bilayer composed only of bis-SorbPC, followed by photoinduced lipid cross-linking, does not measurably diminish protein function. 相似文献
8.
Mixtures of dioctadecyldimethylammonium chloride (DODAC) cationic vesicle dispersions with aqueous micelle solutions of the anionic sodium cholate (NaC) were investigated by differential scanning calorimetry, DSC, turbidity and light scattering. Within the concentration range investigated (constant 1.0 mM DODAC and varying NaC concentration up to 4 mM), vesicle → micelle → aggregate transitions were observed. The turbidity of DODAC/NaC/water depends on time and NaC/DODAB molar concentration ratio R. At equilibrium, turbidity initially decreases smoothly with R to a low value (owing to the vesicle–micelle transition) when R = 0.5–0.8 and then increases steeply to a high value (owing to the micelle–aggregate transition) when R = 0.9–1.0. DSC thermograms exhibit a single and sharp endothermic peak at Tm ≈ 49 °C, characteristic of the melting temperature of neat DODAC vesicles in water. Upon addition of NaC, Tm initially decreases to vanish around R = 0.5, and the main transition peak broadens as R increases. For R > 1.0 two new (endo- and exothermic) peaks appear at lower temperatures indicating the formation of large aggregates since the dispersion is turbid. All samples are non-birefringent. Dynamic light scattering (DLS) data indicate that both DODAC and DODAC/NaC dispersions are highly polydisperse, and that the mean size of the aggregates tends to decrease as R increases. 相似文献
9.
R. D. Sinisterra R. Najjar O. L. Alves P. S. Santos C. A. Alves De Carvalho A. L. Conde Da Silva 《Journal of inclusion phenomena and macrocyclic chemistry》1995,22(2):91-98
The preparation and characterization of the 1:1 inclusion compound of rhodium(II) -methyl cinnamate in -cyclodextrin is reported. Evidence of inclusion was obtained from X-ray powder diffraction results, Raman, IR and UV-Vis spectroscopic studies and thermal analysis. Given the potential antitumor activity of the rhodium(II) carboxylate and its virtual insolubility in water, its inclusion in -cyclodextrin opens the possibility for its transference to the aqueous phase. 相似文献
10.
Abachi S Abbott B Abolins M Acharya BS Adam I Adams DL Adams M Ahn S Aihara H Alitti J Álvarez G Alves GA Amidi E Amos N Anderson EW Aronson SH Astur R Avery RE Baarmand MM Baden A Balamurali V Balderston J Baldin B Banerjee S Bantly J Bartlett JF Bazizi K Bendich J Beri SB Bertram I Bezzubov VA Bhat PC Bhatnagar V Bhattacharjee M Bischoff A Biswas N Blazey G Blessing S Bloom P Boehnlein A Bojko NI Borcherding F Borders J Boswell C Brandt A Brock R Bross A Buchholz D Burtovoi VS Butler JM 《Physical review letters》1996,77(4):595-600