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1.
The eighth virial coefficient for hard hyperspheres is calculated by Monte Carlo techniques. It is found that B8/B(7)2=0.000 274+/-0.000 014 and -0.000 115+/-0.000 012 in four and five dimensions, respectively. The results are in good agreement with the findings of Clisby and McCoy (e-print arXiv:cond-mat0410511), and confirm that B8 is negative in five dimensions. 相似文献
2.
Andrew Masters 《Liquid Crystals Today》2016,25(2):30-37
While much liquid crystal research is on either thermotropic liquid crystals or on lyotopic, surfactant systems, a fascinating third class of materials is that of chromonic liquid crystals. These systems show fascinating properties but are, as yet, poorly understood. This article reports a recent meeting in which the status of our current knowledge is reviewed. 相似文献
3.
Solar Hydrogen from an Aqueous,Noble‐Metal‐Free Hybrid System in a Continuous‐Flow Sampling Reaction System 下载免费PDF全文
Dr. Xiaobo Li Dr. Antony J. Ward Prof. Anthony F. Masters Prof. Thomas Maschmeyer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(24):7345-7350
We introduce the visible‐light photocatalytic H2 evolution reaction as catalyzed by a cobaloxime/carbon nitride (C3N4) noble‐metal‐free hybrid photosystem by using a continuous‐flow sampling reaction system. The photocatalytic H2 evolution rate is highly dependent on the structure of C3N4, in which porous C3N4 shows the best activity compared with bulk C3N4 (lamellar) and C3N4 nanosheets. When using porous C3N4, the system is neither affected by the solution pH, nor the C3N4 concentration, nor the structure of the cobaloxime complex. 相似文献
4.
Dimelow RJ Bryce RA Masters AJ Hillier IH Burton NA 《The Journal of chemical physics》2006,124(11):114113
The transition path sampling (TPS) method is a powerful approach to study chemical reactions or transitional properties on complex potential energy landscapes. One of the main advantages of the method over potential of mean force methods is that reaction rates can be directly accessed without knowledge of the exact reaction coordinate. We have investigated the complementary nature of these two differing approaches, comparing transition path sampling with the weighted histogram analysis method to study a conformational change in a small model system. In this case study, the transition paths for a transition between two rotational conformers of a model disaccharide molecule, methyl beta-D-maltoside, were compared with a free energy surface constrained by the two commonly used glycosidic (phi,psi) torsional angles. The TPS method revealed a reaction channel that was not apparent from the potential of mean force method, and the suitability of phi and psi as reaction coordinates to describe the isomerization in vacuo was confirmed by examination of the transition path ensemble. Using both transition state theory and transition path sampling methods, the transition rate was estimated. We have estimated a characteristic time between transitions of approximately 160 ns for this rare isomerization event between the two conformations of the carbohydrate. We conclude that transition path sampling can extract subtle information about the dynamics not apparent from the potential of mean force method. However, in calculating the reaction rate, the transition path sampling method required 27.5 times the computational effort than was needed by the potential of mean force method. 相似文献
5.
Sandra J. Atkinson Heather E. Robertson Margit Hölbling Wolf-Walther du Mont Cristina Mitrofan Karl Hassler Sarah L. Masters 《Structural chemistry》2013,24(3):851-857
The gas-phase molecular structures of a series of halogen-substituted disilanes [X3SiSiMe3 (X = H, F, Cl and Br)], 1,1,1-trimethyldisilane (H3SiSiMe3), 1,1,1-trifluoro-2,2,2-trimethyldisilane (F3SiSiMe3), 1,1,1-trichloro-2,2,2-trimethyldisilane (Cl3SiSiMe3) and 1,1,1-tribromo-2,2,2-trimethyldisilane (Br3SiSiMe3), have been determined in the gas phase by electron diffraction. Ab initio calculations at the HF and MP2 level were used to support the experimental investigation using the SARACEN method. All of the investigated structures were determined to adopt a staggered structure with C 3v symmetry. The effect of substitution on the Si–Si bond and the Si–Si–X bond angle was investigated and these results were compared to results obtained from a recent study of halogen-substituted disilanes [X3SiSiXMe2 (X = F, Cl, Br and I)] to consider the effect of the methyl groups on the substituted disilanes. 相似文献
6.
Revealing the Distribution of the Atoms within Individual Bimetallic Catalyst Nanoparticles 下载免费PDF全文
Dr. Peter Felfer Dr. Paul Benndorf Prof. Anthony Masters Prof. Thomas Maschmeyer Prof. Julie M. Cairney 《Angewandte Chemie (International ed. in English)》2014,53(42):11190-11193
To be able to correlate the catalytic properties of nanoparticles with their structure, detailed knowledge about their make‐up on the atomic level is required. Herein, we demonstrate how atom‐probe tomography (APT) can be used to quantitatively determine the three‐dimensional distribution of atoms within a Au@Ag nanoparticle with near‐atomic resolution. We reveal that the elements are not evenly distributed across the surface and that this distribution is related to the surface morphology and residues from the particle synthesis. 相似文献
7.
8.
We discuss the notion of spin squeezing considering two mutually exclusive classes of spin-s states, namely, oriented and non-oriented states. Our analysis shows that the oriented states are not squeezed while non-oriented
states exhibit squeezing. We also present a new scheme for construction of spin-s states using 2s spinors oriented along different axes. Taking the case of s=1, we show that the ‘non-oriented’ nature and hence squeezing arise from the intrinsic quantum correlations that exist among
the spinors in the coupled state. 相似文献
9.
10.
Masters KS 《Macromolecular bioscience》2011,11(9):1149-1163
Growth factors play a critical role in regulating processes involved in cellular differentiation and tissue regeneration, and are therefore considered essential elements in many tissue engineering strategies. The covalent immobilization of growth factors to biomaterial matrices addresses many of the challenges associated with delivering freely-diffusible growth factors and has thus emerged as a promising method of achieving localized and sustained growth factor delivery. This Feature Article discusses methods that have been used to immobilize growth factors to substrates, followed by an overview of several tissue repair and regeneration applications in which immobilized growth factors have been used. 相似文献