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1.
Hasani M Shamsipur M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(5):815-821
Interactions of diaza-18-crown-6 and diaza-15-crown-5, as electron donors, with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), as an electron acceptor, have been investigated spectrophotometrically in acetonitrile and chloroform solutions. The results indicated immediate formation of an electron donor-electron acceptor complex DA: [reaction in text] which is followed by two relatively slow consecutive reactions: [reaction in text]. The pseudo-first-order rate constants for the formation of the ionic intermediate and the final product have been evaluated at various temperatures by computer fitting of the absorbance time data to appropriate equations. The formation constants of the resulting DA complexes have also been determined. The influences of both the azacrown's structure and the solvent properties on the formation of DA complexes and the rates of subsequent reactions are discussed. 相似文献
2.
A flow injection gas-phase molecular absorption spectrophotometric method is described for the determination of sulphite in aqueous solution. The sulphite solution, 200 microl, is introduced into a stream of distilled water. The carrier stream containing a sulphite zone is reacted, in the first mixing coil, with a stream of sulphuric acid (1 M). The evolved sulphur dioxide is purged to the segments of nitrogen flow through the second mixing coil. The gaseous phase is separated from the liquid stream by the use of a purpose built gas-liquid separator and then is swept into a purpose built flow-through cell. The absorbance of the gaseous phase is measured at 200 nm using a UV/VIS spectrophotometer. Up to 440 microg of sulphite is determined. The limit of detection is 0.8 microg and the R.D.S. for the determination of 70 and 220 microg of sulphite are 1.02 and 0.76%, respectively. Up to 40 samples h(-1) can be analyzed. The effect of several anions and cations on the determination of sulphite was studied and the results showed that the method is relatively free from interferences. The proposed method was applied to the determination of sulphite in a synthetic sample, water sample and lemon juice. 相似文献
3.
Spectroscopical Properties of Di(phthalocyaninato)metalates(III) of the Rare Earth Elements. Part 2: The Multinuclear (1H, 13C, 15N, 17O, and 31P) NMR Spectra and Determination of Complex Bound Water The 1H, 13C, 15N, 17O and 31P NMR spectra of (PNP)[Ln(Pc2?)2] and (TDOA)[Ln(Pc2?)2] (Ln = La …? (—Pm) …? Lu); PNP: di(triphenylphosphine)-iminium; TDOA: Tri(n-dodecyl)n-octylammonium dissolved in CD2Cl2 are reported. With the exception of the nitrogen atoms of the cations all light atoms of both homologues complex salt rows have been detected and assigned. Proof of the presence of additional water contained in the (solid) complex salts has been given unambigously. The otherwise strong Fermi contact interactions diminuish rapidly with growing distance from the paramagnetic centre favouring dipolar (pseudo-contact) interactions. As a consequence the mostly element independent paramagnetic shifts of the atoms situated on the periphery of the anion as well as those of the cations and water are determined by the distance factor. Therefore a first glance of the structure of the ion-pair present in solution emerges, in which the water molecule seems to play an important role. 相似文献
4.
Masoumeh Hasani Mojtaba Shamsipur 《Journal of inclusion phenomena and macrocyclic chemistry》1993,16(2):123-137
The formation of ammonium complexes with several crown ethers and cryptands in nitrobenzene, acetonitrile and dimethylformamide solutions was investigated by conductometry at 25°C. Stability constants of the resulting 1:1 complexes sere determined from the molar conductance-mole ratio data and found to vary in the order DC18C6>18C6>DB30C10>DB21C7>DB24C8>DB18C6>15C5>B15C5>12C4, in the case of crown complexes, and in the order C222>C221>C211>C22>C21 for the ammonium cryptates. The stabilities of the complexes varied inversely with the Gutmann donicity of the solvents. Influences of the number of members in the macrocycle, nature of the substituents in the polyether ring, cavity size and dimensionality, conformations of the free and complexed ligands and number of N+–H bonds available for hydrogen bonding are discussed. 相似文献
5.
The triethylamine-based nanomagnetic ionic liquid, [(Et)3 N-H]FeCl4, was synthesized, and its structural and chemical characteristics were detected. The thermogravimetric analysis indicated its high thermal stability with a decomposition temperature higher than 300 °C. Additionally, [(Et)3 N-H]FeCl4 was used to efficiently catalyze the synthesis of xanthene derivatives under solvent-free conditions at 120 °C. [(Et)3 N-H]FeCl4 was recycled and reused at least five times.
Graphical abstract 相似文献6.
Ali H. Abdollahi Bafghi Mahtab Mirmohseni Masoumeh Nasiri-Kenari 《Entropy (Basel, Switzerland)》2022,24(8)
In this paper, we study the degrees of freedom (DoF) of a frequency-selective K-user interference channel in the presence of an instantaneous relay (IR) with multiple receiving and transmitting antennas. We investigate two scenarios based on the IR antennas’ cooperation ability. First, we assume that the IR receiving and transmitting antennas can coordinate with each other and that the transmitted signal of each transmitting antenna can depend on the received signals of all receiving antennas, and we derive lower and upper bounds for the sum DoF of this model. In an interference alignment scheme, we divide receivers into two groups called clean and dirty receivers. We design our scheme such that a part of the messages of clean receivers can be de-multiplexed at the IR. Thus, the IR can use these message streams for an interference cancellation at the clean receivers. Next, we consider an IR, the antennas of which do not have coordination with each other and where the transmitted signal of each transmitting antenna depends only on the received signal of its corresponding receiving antenna. We also derive lower and upper bounds for the sum DoF for this model of IR. We show that the achievable sum DoF decreases considerably compared with the coordinated case. In both of these models, our schemes achieve the maximum K sum DoF if the number of transmitting and receiving antennas is more than a finite threshold. 相似文献
7.
Vahedi Mohammad Mollaei Barzi Yaser Firouzi Masoumeh 《Journal of Thermal Analysis and Calorimetry》2021,146(3):1297-1321
Journal of Thermal Analysis and Calorimetry - The aim of this paper is to achieve a smaller and cheaper heat exchanger with similar performance. To fulfill this demand, ANSYS-Fluent software and... 相似文献
8.
Acoustic performance of dissipative silencer was evaluated to determine the effectiveness of perforated duct porosity and absorbent material density in reducing occupational noise exposure propagated from centrifugal fan. Design charts were applied to predict noise reduction and length of a dissipative silencer. Dissipative silencers with various punched duct porosity (14%, 30% and 40%) and sound absorbent density (80 Kg/m3, 120 Kg/m3, and 140 Kg/m3) were designed and fabricated. According to ISO9612 and ISO11820, noise level was measured before and after installing all nine test silencers at fixed workstations around the discharge side of a centrifugal fan in a manufacturing plant. On average, the noise level at the discharge side of a fan without silencer was measured to be 93.6 dBA, whereas it was significantly mitigated by 67.4 dBA to 70.1 dBA after installing all silencers. Dynamic insertion loss for a dissipative silencer with 100 cm length was predicted to be 27.9 dB, which was in agreement with experimental ones. Although, there was no significant differences between insertion loss of silencers, the one with 30% porosity and 120 Kg/m3 rock wool density had the highest insertion loss of 26.2 dBA. Dissipative silencers noticeably reduced centrifugal fan noise exposures. Increasing sound absorbent density and duct porosity up to a certain limit could probably be effective in noise reduction of dissipative silencers. 相似文献
9.
Efficient removal of hexavalent chromium and lead from aqueous solutions by s‐triazine containing nanoporous polyamide 下载免费PDF全文
s‐Triazine containing dicarboxylic acid was synthesized. Then, it was reacted with 1,3‐phenylenediamine in molten tetrabutylammonium bromide to formed soluble aromatic polyamide with good yield and moderate inherent viscosity of 0.35 dL g?1. The solubility and flexibility of polyamides are low. So, we used ether group such as di(4‐aminephenyl) ether in building polyamide. The structure of monomer and polymer was confirmed by Fourier transform infrared spectroscopy, elemental analysis, and proton nuclear magnetic resonance techniques. Thermogravimetric analysis was used to evaluate the thermal properties of synthesized polyamide, and their results show that this polymer had a good thermal stability. The surface morphology of s‐triazine containing polyamide was studied by field emission‐scanning electron microscopy and transmission electron microscopy, and the results show that it has a porous morphology and moderate Brunauer–Emmett–Teller specific surface (367 m2 g?1). It was further investigated for Pb (II) and Cr(VI) ion removal by optimizing the parameters including pH and contact time. The maximum uptakes of Pb(II) and Cr(VI) at pH 5.0 and pH 4.0 are 57% and 76%, respectively. Also, sorption kinetics of this polymer was investigated. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
10.
Farhad Shirini Mohammad Ali Zolfigol Masoumeh Abedini 《Monatshefte für Chemie / Chemical Monthly》2009,141(10):61-64