全文获取类型
收费全文 | 1937篇 |
免费 | 57篇 |
国内免费 | 8篇 |
专业分类
化学 | 1607篇 |
晶体学 | 18篇 |
力学 | 21篇 |
综合类 | 1篇 |
数学 | 81篇 |
物理学 | 274篇 |
出版年
2022年 | 10篇 |
2021年 | 13篇 |
2020年 | 21篇 |
2019年 | 20篇 |
2018年 | 18篇 |
2017年 | 20篇 |
2016年 | 44篇 |
2015年 | 27篇 |
2014年 | 42篇 |
2013年 | 84篇 |
2012年 | 106篇 |
2011年 | 119篇 |
2010年 | 63篇 |
2009年 | 61篇 |
2008年 | 131篇 |
2007年 | 124篇 |
2006年 | 114篇 |
2005年 | 112篇 |
2004年 | 122篇 |
2003年 | 93篇 |
2002年 | 87篇 |
2001年 | 39篇 |
2000年 | 22篇 |
1999年 | 28篇 |
1998年 | 13篇 |
1997年 | 23篇 |
1996年 | 17篇 |
1995年 | 17篇 |
1994年 | 18篇 |
1993年 | 27篇 |
1992年 | 20篇 |
1991年 | 18篇 |
1990年 | 18篇 |
1989年 | 12篇 |
1988年 | 26篇 |
1987年 | 12篇 |
1986年 | 12篇 |
1985年 | 30篇 |
1984年 | 24篇 |
1983年 | 12篇 |
1982年 | 15篇 |
1981年 | 28篇 |
1980年 | 8篇 |
1979年 | 17篇 |
1978年 | 17篇 |
1977年 | 18篇 |
1976年 | 19篇 |
1975年 | 8篇 |
1974年 | 10篇 |
1973年 | 6篇 |
排序方式: 共有2002条查询结果,搜索用时 15 毫秒
1.
2.
Masakatu Sugimoto 《Finite Elements in Analysis and Design》1989,4(4):279-289
A new matrix is proposed here which is based on rigid elements. The efficiency and usefulness of this method has been demonstrated for plane problems. The purpose of this paper is to formulate the method and to indicate its validity. 相似文献
3.
Takayuki Yaegashi Shinya Yodoya Masahiko Nakamura Hiroki Takeshita Katsuhiko Takenaka Tomoo Shiomi 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):999-1007
Free‐radical homo‐ and copolymerization behavior of N,N‐diethyl‐2‐methylene‐3‐butenamide (DEA) was investigated. When the monomer was heated in bulk at 60 °C for 25 h without initiator, rubbery, solid gel was formed by the thermal polymerization. No such reaction was observed when the polymerization was carried out in 2 mol/L of benzene solution with with 1 mol % of azobisisobutyronitrile (AIBN) as an initiator. The polymerization rate (Rp) equation was Rp ∝ [DEA]1.1[AIBN]0.51, and the overall activation energy of polymerization was calculated 84.1 kJ/mol. The microstructure of the resulting polymer was exclusively a 1,4‐structure where both 1,4‐E and 1,4‐Z structures were included. From the product analysis of the telomerization with tert‐butylmercaptan as a telogen, the modes of monomer addition were estimated to be both 1,4‐ and 4,1‐addition. The copolymerizations of this monomer with styrene and/or chloroprene as comonomers were also carried out in benzene solution at 60 °C. In the copolymerization with styrene, the monomer reactivity ratios obtained were r1 = 5.83 and r2 = 0.05, and the Q and e values were Q = 8.4 and e = 0.33, respectively. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 999–1007, 2004 相似文献
4.
Atsuhiro Fujimori Mikako Ishitsuka Hiroo Nakahara Eisuke Ito Masahiko Hara Kaname Kanai Hisao Ishii Yukio Ouchi Kazuhiko Seki 《Journal of Polymer Science.Polymer Physics》2004,42(12):2329-2336
Photopolymerization of cadmium 10,12-pentacosadiynoate (CdDA) in Langmuir–Blodgett (LB) films, with the molecular packing well arranged by moderate preannealing, was investigated with near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. Greenish films of polydiacetylene with an absorption wavelength of 705 nm were obtained through the photopolymerization of preannealed monomer LB films, and this resulted in an extended π-conjugate system based on the well-ordered monomer in a two-dimensional arrangement. The electronic structures of the polydiacetylenes were found to be correlated to the variation of the molecular arrangements in the films from the changes in the NEXAFS spectra through photopolymerization in the LB films. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2329–2336, 2004 相似文献
5.
Yoshinori Nishiwaki Masahiko Shimoyama Toshio Nakanishi Toshio Ninomiya Izumi Nakai 《Analytical sciences》2006,22(10):1297-1300
Total reflection X-ray fluorescence spectrometry (TXRF) has been applied for trace elemental analysis of small glass fragments. A small glass sample (a fragment with weight less than 0.5 mg) was decomposed by 100 microg of HF/HNO3 acid; the material was condensed to 10 microl and was dried on a Si wafer. Since the size of the dried residue on the Si wafer was less than 1 cm in diameter, an incident X-ray beam with about 1 cm in width could effectively excite elemental components in such a small glass fragment. The precision of the present technique was checked by analyzing the glass fragments (<0.5 mg) from NIST SRM612; the relative standard deviations (RSD) of less than 8.1% were achieved for elemental ratios that were normalized by Sr. Fragments (<0.5 mg) obtained from 23 figured sheet glasses were used as samples for estimating the utility of this technique to forensic discrimination. Comparison of five elemental ratios of Ti/Sr, Mn/Sr, Zn/Sr, Rb/Sr, and Pb/Sr calculated from X-ray fluorescence spectra was effective in distinguishing glass fragments that could not be differentiated by their refractive indexes (RI). 相似文献
6.
7.
The anti-tumor agent, tamoxifen, is easily synthesized by the successive allylation of benzaldehyde and the Friedel-Crafts alkylation reaction of anisole with the intermediary homoallyl silyl ethers, followed by the migration of the double bond to form the desired tetra-substituted ethylenes. Several derivatives of tamoxifen are also produced according to a similar synthetic strategy. 相似文献
8.
Hiroshi Sugimoto Hiromitsu Ohshima Shohei Inoue 《Journal of polymer science. Part A, Polymer chemistry》2003,41(22):3549-3555
The first successful example of the formation of polycarbonate from 1-atm carbon dioxide and epoxide was demonstrated by the alternating copolymerization of carbon dioxide and epoxide with manganese porphyrin as a catalyst. The copolymerization of carbon dioxide and cyclohexene oxide with (porphinato)manganese acetate proceeded under the 1-atm pressure of carbon dioxide to give a copolymer with an alternating sequence. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3549–3555, 2003 相似文献
9.
Mitsuru Sugimoto 《Journal of Functional Analysis》1998,160(2):1
We discuss the problem of boundedness fromLp(Rn) toLp′(Rn) (1/p+1/p′=1, 1?p?2) of operators of the typeM=F−1ei?(ξ)a(ξ) F, which is related to the study of hyperbolic equations with constant coefficients. The boundedness is dependent on a geometrical property ofΣ=?−1(1), and its dependence has been exactly determined in the casesn=2, 1?p?2 andn?3,p=1, 2 (M. Sugimoto,Math. Z.215(1994), 519–531;222(1996), 521–531). This paper is devoted to the unsolved case 1<p<2, and a strange phenomenon is exhibited in the simplest casen=3. 相似文献
10.
Katsuhiro Inomata Chieko Fukuda Kuniyoshi Hori Hideki Sugimoto Eiji Nakanishi 《Journal of Polymer Science.Polymer Physics》2007,45(2):129-137
The phase behavior and crystallization of graft copolymers consisting of poly(n‐hexyl methacrylate) (PHMA) as an amorphous main chain and poly(ethylene glycol) (PEG) as crystallizable side chains (HMAx with 15 ≤ x ≤ 73, where x represents the weight percentage of PEG) were investigated. Small‐angle X‐ray scattering profiles measured above the melting temperature of PEG suggested that a microdomain structure with segregated PHMA and PEG domains was formed in HMA40 and HMA46. This phase behavior was qualitatively described by a calculated phase diagram based on the mean‐field theory. Because of the segregation of PEG into microdomains, the crystallization temperature of the PEG side chains in HMAx was higher than that in poly(methyl acrylate)‐graft‐poly(ethylene glycol) having a similar value of x, which was considered to be in a disordered state above the melting temperature. In HMAx with x ≤ 40, PEG crystallization was strongly restricted, probably because the PEG microdomains were isolated in the PHMA matrix. As a result, the growth of PEG spherulite was not observed because the PEG crystallization occurred after vitrification of the PHMA segregated domains. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 129–137, 2007 相似文献