Forward mixing model in a rotating disc contactor for kerosene–acetic acid–water system

The application of an extraction column model which takes into account the influence of the forward mixing model is brought forward by generation of values of the mass transfer and axial dispersion coefficients required by the model. Values of these coefficients were generated from solute concentration profile measurements in a rotary disc contactor (RDC). The use of the Handlos–Baron drop mass transfer model was justified. The resulting continuous phase transfer coefficients were found to be dependent largely on disc speed. The accuracy of the forward mixing model for kerosene–acetic acid–water system was adequately presented and explained by the axial dispersion coefficient.     

Simulated fractal permeability for porous membranes

Fractal permeability model for bi-dispersed porous media is developed based on the fractal characteristics of pores in the membrane. The fractal permeability model is found to be a function of the tortuosity fractal dimension, pore area fractal dimension, sizes of particles and clusters, micro-porosity inside clusters, and the effective porosity of a medium. The pore area fractal dimension and the tortuosity fractal dimension of the porous membranes are determined by the box counting method. To verify the validity of the model, the predicted permeability were compared with the experimental data utilizing H₂ gas permeating through porous Pd-alumina, silicalite-1 and B-ZSM-5, and O₂ across perovskite-alumina membranes form the past effort.     

Synthetic hydrotalcites from different routes and their application as catalysts and gas adsorbents: a review

In this paper, widely accepted methods of hydrotalcite preparation such as co‐precipitation, urea hydrolysis, hydrothermal, sol–gel, microwave irradiation, steam activation and solvothermal have been selected and reviewed. Our review indicates that the nature of the divalent cations, the synthesis method, the calcination temperature and the nature of the interlayer species are determinant factors in shaping the surface properties of the layered double hydoxides. The basic strength of the surface base site and structural changes produced in the mixed oxides can be adjusted conveniently by varying the Al content during the synthesis. The combination of sol–gel with microwave irradiation during the gelling and crystallization steps has also been found to increase the surface area of the hydrotalcite‐like compound. Copyright © 2009 John Wiley & Sons, Ltd.