全文获取类型
收费全文 | 1205篇 |
免费 | 47篇 |
国内免费 | 12篇 |
专业分类
化学 | 733篇 |
晶体学 | 6篇 |
力学 | 23篇 |
数学 | 293篇 |
物理学 | 209篇 |
出版年
2023年 | 5篇 |
2022年 | 19篇 |
2021年 | 22篇 |
2020年 | 33篇 |
2019年 | 30篇 |
2018年 | 27篇 |
2017年 | 28篇 |
2016年 | 25篇 |
2015年 | 47篇 |
2014年 | 44篇 |
2013年 | 69篇 |
2012年 | 78篇 |
2011年 | 62篇 |
2010年 | 58篇 |
2009年 | 56篇 |
2008年 | 48篇 |
2007年 | 49篇 |
2006年 | 41篇 |
2005年 | 54篇 |
2004年 | 58篇 |
2003年 | 35篇 |
2002年 | 40篇 |
2001年 | 22篇 |
2000年 | 22篇 |
1999年 | 18篇 |
1998年 | 10篇 |
1997年 | 13篇 |
1996年 | 14篇 |
1995年 | 8篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1990年 | 5篇 |
1988年 | 5篇 |
1986年 | 6篇 |
1985年 | 14篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1979年 | 10篇 |
1978年 | 10篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1975年 | 13篇 |
1974年 | 16篇 |
1973年 | 9篇 |
1972年 | 9篇 |
1971年 | 7篇 |
1970年 | 9篇 |
1969年 | 5篇 |
排序方式: 共有1264条查询结果,搜索用时 15 毫秒
1.
2.
Marius Lupu Adnana Zaulet Prof. Dr. Francesc Teixidor Prof. Dr. Eliseo Ruiz Prof. Dr. Clara Viñas 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(18):6888-6897
The metallacarborane [3,3′‐Co(1,2‐closo‐C2B9H11)2]? has been synthesized. This species allows the formation of redox couples in which both partners are negatively charged. The E1/2 potential can be tuned by adjusting the nature and number of substituents on B and C. The octaiodinated species [3,3′‐Co(1,2‐closo‐C2B9H7I4)2]? is the most favorable, as it is isolatable and stable in air. A DFT study on stability and redox potentials of complexes has been performed. 相似文献
3.
Dorina Mitrea Marius Mitrea Jill Pipher 《Journal of Fourier Analysis and Applications》1997,3(2):131-192
We study boundary value problems for the time-harmonic form of the Maxwell equations, as well as for other related systems
of equations, on arbitrary Lipschitz domains in the three-dimensional Euclidean space. The main goal is to develop the corresponding
theory for Lp-integrable bounday data for optimal values of p's. We also discuss a number of relevant applications in electromagnetic scattering. 相似文献
4.
S. Schrader A. Penzkofer W. Holzer R. Velagapudi B. Grimm 《Journal of luminescence》2004,110(4):303-308
Optical, structural and morphological properties of thin films of polyparaphenylenevinylene (PPV) formed by an alkyl sulfinyl precursor route have been studied. Thin films were fabricated on an optical glass and on quartz glass either by spin-coating of the precursor solution or by layer-by-layer deposition using Langmuir–Blodgett technique. PPV precursor films were also spin-coated on gold-coated glass in order to study thin-film optical parameters by surface plasmon spectroscopy. We have been successful in forming about 40 precursor mono layers on quartz glass by Langmuir–Blodgett technique using optimized surface pressure and dipping conditions. After thermal conversion of the precursor layers good quality fluorescent PPV films of yellow colour have been obtained. Optical characterization of the films was carried out by linear absorption and emission spectroscopy, ellipsometry, and surface plasmon spectroscopy. Structural and morphological studies on the thin films were carried out by using X-ray scattering and atomic force microscopy. Wave-guided travelling-wave laser action has been achieved in a PPV film on quartz glass. The sample was transversally pumped with picosecond laser pulses (wavelength 347.15 nm, duration 35 ps). Laser emission occurred at 550 nm for pump pulse energy densities above . 相似文献
5.
One of the successful transformations within the field of organocatalysis, the organocatalytic asymmetric addition of nitromethane to α,β‐unsaturated aldehydes and ketones, has been studied by quantum chemical modeling. The level of accuracy of the hybrid density functional theory method B3LYP/6‐31G(d) was compared to a high level ab initio benchmark for this reaction. It is concluded that B3LYP/6‐31G(d) performs very well for this reaction type, giving good estimates of critical energies. The reaction between acrolein and nitromethane was studied in detail. The reaction mechanism revealed an intermediate oxazolidin structure, which is currently unknown. Alkyl substitution in various positions on the amine catalyst or α,β‐unsaturated carbonyl compound influences the reactivity in a predictive fashion. The iminium ion, prop‐2‐en‐iminium, is less activated towards nucleophilic attack compared to protonated acrolein. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
6.
In this paper we consider operators of the form H=λ(-i∇), with λ analytic in a strip and with some specific growth conditions at infinity, and prove Hardy type estimates in L
2(ℝ
n
) with exponential weights. In fact we extend our previous results [19] from bounded analytic functions on a strip to analytic
functions with polynomial growth in that strip. 相似文献
7.
Dans ce travail on détermine quelques probabilités géométriques concernant des réseaux irréguliers dans le plan euclidienE
2 et dans l'espace euclidienE
n
. Les propriétés généralisent certains résultats de Buffon, Deltheil et Stoka.
Travail effectué avec l'aide du MURST (40%, 60%). 相似文献
8.
Using recursive variants of Baire notions of nowhere dense and meagre sets we study the topological size of speedable and infinitely often speedable functions in a machine-independent framework. We show that the set of speedable functions is not “small” whereas the set of infinitely often speedable functions is “large”. In this way we offer partial answers to a question in [4]. 相似文献
9.
József Kaizer József Pap Gábor Speier Marius Réglier Michel Giorgi 《Transition Metal Chemistry》2004,29(6):630-633
The preparation, spectroscopic properties, and crystal structure of [Cu(ind)(mco)] [ind is the anion of 1,3-bis(2-pyridylimino)isoindoline and mco is the anion of 3-hydroxy-(4H)-benzopyran-4-one] are reported. The complex exhibits a distorted square pyramidal geometry. The oxygenation of the title compound results in oxidative cleavage of the heterocyclic ring to give the (acetylsalicylato)copper(II) complex [Cu(asp)(ind)] (asp is the anion of acetylsalicylic acid) and CO as primary products, which reaction resembles the enzymatic reaction of quercetinase. 相似文献
10.
In this paper we study the Navier–Stokes boundary‐initial value problem in the exterior of a rotating obstacle, in two and three spatial dimensions. We prove the local in time existence and uniqueness of strong solutions. Moreover, we show that the solutions are global in time, in two spatial dimensions. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献