全文获取类型
收费全文 | 183篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
化学 | 130篇 |
晶体学 | 8篇 |
力学 | 1篇 |
数学 | 8篇 |
物理学 | 46篇 |
出版年
2023年 | 8篇 |
2022年 | 5篇 |
2021年 | 2篇 |
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 8篇 |
2017年 | 3篇 |
2016年 | 15篇 |
2015年 | 8篇 |
2014年 | 10篇 |
2013年 | 10篇 |
2012年 | 18篇 |
2011年 | 33篇 |
2010年 | 10篇 |
2009年 | 17篇 |
2008年 | 2篇 |
2007年 | 3篇 |
2005年 | 1篇 |
2004年 | 1篇 |
2003年 | 2篇 |
2002年 | 3篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1994年 | 2篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1980年 | 1篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有193条查询结果,搜索用时 15 毫秒
1.
Milind V. Kulkarni Annamraju Kasi Viswanath R. Marimuthu Tanay Seth 《Journal of polymer science. Part A, Polymer chemistry》2004,42(8):2043-2049
Spectroscopic [UV–visible and Fourier transform IR (FTIR)] and thermal properties of chemically synthesized polyanilines are found to be affected by varying the protonation media (acetic, citric, oxalic, and tartaric acid). The optical spectra show the presence of a greater fraction of fully oxidized insulating pernigraniline phase in polyaniline doped with acetic acid. In contrast, the selectivity in the formation of the conducting phase is higher in oxalic acid as a protonic acid media. The FTIR spectra of these polymers reveal a higher ratio of the relative intensities of the quinoid to benzenoid ring modes in acetic acid doped polyaniline. Scanning electron micrographs revealed a sponge‐like structure derived from the aggregation of the small granules in acetic acid and oxalic acid doped polyaniline. A three‐step decomposition pattern is observed in all the polymers, regardless of the protonic acid used for the doping. The second step loss related to the loss of dopant is found to be higher in the oxalic acid doped polymer. In accordance with these results the conductivity is also found to be higher in oxalic acid doped material. The temperature dependent conductivity measurements show the thermal activated behavior in all the polymers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2043–2049, 2004 相似文献
2.
The maximum number of non-vanishing and independent second order photoelastic coefficients required by the seven pentagonal
and the two icosahedral point groups 5(C5),
(S10),
(C5h
),
m2(D5h
), 52(D5), 5m(C5v
),
2m(D5d
); 235(I), 2/m
(I
h
)—that describe the quasicrystals symmetry groups in two and three dimensions—is obtained. The schemes of non-vanishing and
independent coefficients have been calculated and listed. Finally the results of this group-theoretical study are briefly
discussed. 相似文献
3.
The transport coefficients for the nine point groups
—which represent the symmetry groups of the quasicrystals in two and three dimensions—have been evaluated and tabulated in
this work, employing group-theoretical methods. 相似文献
4.
Chokalingam Saravanan Marimuthu Senthilkumaran Bosco Christin Maria Arputham Ashwin Palaniswamy Suresh Paulpandian Muthu Mareeswaran 《Journal of inclusion phenomena and macrocyclic chemistry》2017,87(3-4):239-250
The ligand salt, Me6[14]diene·2HClO4 (L·2HClO4) was prepared by condensation of acetone and ethylene diamine in the presence of perchloric acid. On reduction of this diene ligand salt, L·2HClO4 with sodium borohydride, the two isomeric ligands, ‘tet-a’ and ‘tet-b’ were produced. The ligands, on reaction with ZnX2 (X=Cl, ClO4, NO3 or CH3COO) and ZnSO4 produced the corresponding complexes. These complexes have been characterized on the basis of elemental analyses; IR, UV–Vis and 1H-NMR spectroscopies; magnetic and conductance data. Based on these data, all of the complexes of the diene ligand L, as well as the perchlorate complexes of all of the ligands attained a square-pyramidal arrangement, whereas the complexes of ‘tet-a’ and ‘tet-b’, with X=NO3, Cl or CH3COO and with ZnSO4 salt, were octahedral. Moreover, all complexes were monometallic except the nitrato complex, [(ZnL)2(µ-NO3)](ClO4)3 which is bimetallic. The structure of [(ZnL)2(µ-NO3)](ClO4)3 has been confirmed by X-ray crystallography. In this complex the zinc centres lie within a N4O donor set, with the four nitrogen donors from L and one of the oxygen atom stemming from the bridging NO3. The complexes show different electrolytic behavior in different solvents. The antibacterial activities of the ligands and complexes towards different phytopathogenic bacteria have been investigated. 相似文献
5.
Bosco Christin Maria Arputham Ashwin Chokalingam Saravanan Marimuthu Senthilkumaran Ragupathi Sumathi Palanisamy Suresh 《Supramolecular chemistry》2018,30(1):32-41
The host–guest interaction of α-tocopherol (vitamin E) with p-sulfonatocalix[4]arene (p-SC4) in solution state is studied using emission and cyclic voltammetric techniques. The lipid soluble α-tocopherol (α-T) forms a solid complex with p-SC4. FTIR and NMR spectral analysis of the solid complex reveals the tight packing of α-T inside the cavity of p-SC4. The structural deformation is confirmed by XRD analysis. SEM images differentiate the highly porous gel like structure of vitamin E aggregate and the solid structure of the host–guest complex prepared. NOESY spectra confirm the tight penetration of α-T within the hydrophobic cavity of p-SC4. 相似文献
6.
Subramanya Hegde Jayadevan Jayashankaran Atanu Ghosal T.S.R Prasanna Y. Shivaraj K. Mohana Raju 《Journal of heterocyclic chemistry》2013,50(2):442-449
A straightforward and general approach for the stereoselective synthesis of fused pyrrolo[1,2‐a] indoles frameworks from>intramolecular 1,3‐dipolar cycloaddition using N‐alkylated Baylis–Hillman derivatives is presented. It was found that the cycloaddition proceeded efficiently under microwave irradiation in solvent‐free condition to afford highly stereoselective cycloadducts in good yield. 相似文献
7.
8.
Dr. Srivari Chandrasekhar Kakita Veera Mohana Rao Mallikanti Seenaiah Police Naresh Ambure Sharada Devi Dr. Bharatam Jagadeesh 《化学:亚洲杂志》2014,9(2):457-461
Hybrid peptidic oligomers comprising natural and unnatural amino acid residues that can exhibit biomolecular folding and hydrogen‐bonding mimicry have attracted considerable interest in recent years. While a variety of hybrid peptidic helices have been reported in the literature, other secondary structural patterns such as γ‐turns and ribbons have not been well explored so far. The present work reports the design of novel periodic γ‐turns in the oligomers of 1:1 natural‐α/unnatural trans‐β‐norborenene (TNAA) amino acid residues. Through DFT, NMR, and MD studies, it is convincingly shown that, in the mixed conformational pool, the heterogeneous backbone of the hybrid peptides preferentially adopt periodic 8‐membered (pseudo γ‐turn)/7‐membered (inverse γ‐turn) hydrogen bonds in both polar and non‐polar solvent media. It is observed that the stereochemistry and local conformational preference of the β‐amino acid building blocks have a profound influence on accessing the specific secondary fold. These findings may be of significant relevance for the development of molecular scaffolds that facilitate desired positioning of functional side‐chains. 相似文献
9.
10.
Chandran Rankan Prabhakaran Santhi Marimuthu Keshri Nath Tiwari 《Journal of heterocyclic chemistry》2020,57(6):2628-2633
A greener, rapid and regioselective “on water” synthesis of spirooxindole-oxazoline by the reaction of isatin and isocyanoacetate at room temperature is described. The developed protocol has the advantage of being atom-economical, eco-friendly, and benign reaction conditions. Broader substrate scope, experimentally simple procedures, and easy purification of products with high yield further make this method attractive. The synthesized compounds have been fully characterized with spectral analysis. 相似文献