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1.
Y Sonoda K Ichinose T Yoshimura Y Sato T Sasaki 《Chemical & pharmaceutical bulletin》1991,39(1):100-103
Lanosterol derivatives with a functional group at C-32 have been synthesized from 3 beta-acetoxylanostan-7 alpha-ol. The key reaction of the synthesis is the hypoiodite reaction of 3 beta-acetoxylanostan-7 alpha-ol. In vitro antitumor activity testing of the lanosterol derivatives revealed that 3 beta-hydroxylanost-7-en-32-oic acid has antineoplastic activity. 相似文献
2.
S. B. Ellis S. J. Kiehl W. S. Hughes K. Schwabe W. C. Gardiner H. L. Sanders H. Yoshimura Hanna Jablezynska-Jedrzewska J. Domański W. A. Dorfman P. Nylén Barbara Stone F. Hovorka W. C. Dearing E. Biilmann W. Kordatzki P. Wulff G. Florence A. Drilhon P. Szigeti O. Tomiček F. Poupě O. Redlich W. Stricks 《Analytical and bioanalytical chemistry》1937,111(2-4):94-104
3.
Etsuro Yoshimura Mariko Akashi Tomonari Umemura Kin-ichi Tsunoda 《Analytical sciences》2004,20(2):373-374
27Al NMR spectra of an equimolar (10 mM) Al(III)-citrate system were obtained at different temperatures. The linewidths of the signals decreased in the spectra recorded at elevated temperatures, which enabled us to unequivocally identify the resonance lines. From the spectrum recorded at 65 approximately C, a mononuclear Al(III)-citrate complex was identified at a solution pH of 3.0 in addition to trinuclear Al(III)-citrate complex, which dominated at pH 4.0. 相似文献
4.
Yoshimi Egawa Mariko Hagita Ken-ichi Kawarabayashi Hong Wang 《Discrete Mathematics》2003,270(1-3):115-125
Let d, k and n be three integers with k3, d4k−1 and n3k. We show that if d(x)+d(y)d for each pair of nonadjacent vertices x and y of a graph G of order n, then G contains k vertex-disjoint cycles converting at least min{d,n} vertices of G. 相似文献
5.
Toshiaki Asakai Ryota Minegishi Norie Inaba Yutaka Ishimura Mariko Murayama Tatsuhiko Tanaka 《Analytical sciences》2006,22(3):461-463
The drying conditions for primary standards of volumetric analysis have a significant effect on the titration results due to changes in the purity, stability and homogeneity. Amidosulfuric acid, a strong acid used as a reference material for volumetric analysis in Japan, was dried in a vacuum desiccator or heated at different temperatures, and then measured by Karl-Fischer titration, thermogravimetry/mass spectroscopy (TG-MS), ion chromatography and coulometric titration. The optimum drying conditions were at 50 degrees C for 24 h with crushing. 相似文献
6.
7.
Masaaki Kubota Raul A. Reimer Kuniko Terajima Yuji Yoshimura Akio Nishijima 《Analytica chimica acta》1987
Inductively-coupled plasma/atomic emission spectrometry with a high-resolution vacuum scanning monochromator is described for the determination of sulfur at 180.734 nm. The behavior of the signal-to-background ratio is investigated as functions of RF power, argon gas flow rate and observation height above the load coil. Under the operating conditions selected, the detection limit is 3 μg l?1. The Se I 196.090-nm line is chosen as internal standard, because the S/Se line pair exhibited the least change with carrier gas flow rate and acid concentration of solution. Sulfur in NiMo and CoMo/ Al2O3 catalysts used for coal liquefaction is determined as S(II) and S(VI) species. The total amount of the species agreed well with the sulfur value obtained by the conventinal combustion method. 相似文献
8.
9.
Interactions between poly(amidoamine) dendrimer (PAMAM)-gold nanocomposites and alkanethiols and between the former nanocomposites and thiol-modified poly(amidoamine) dendrons in ethyl acetate were investigated by adding alkanethiols, such as 1-propanethiol and 1,3-propanedithiol, and thiol-modified poly(amidoamine) dendrons, generations 0.5 and 2.5 (G0.5-SH and G2.5-SH). The PAMAM dendrimers with surface methyl ester groups used were generations 1.5 and 5.5 (G1.5 and G5.5). The mean particle sizes of PAMAM-gold nanocomposites were about 2.1 for G1.5 and 2.4 nm for G5.5. In both nanocomposite systems where 1-propanethiol and 1,3-propanedithiol were added, the mean particle size was about 4 nm, twice that of the systems where these thiols were not added. Increasing the addition of 1,3-propanedithiol made the average particle size smaller for both nanocomposites systems. To compare with alkanethiol, thiol-modified poly(amidoamine) dendron with a highly branched structure on one side was synthesized. Using G2.5-SH as a protective agent, dendron-gold nanocomposites with mean diameters of 3 to 4 nm were obtained. The difference in particle size was seen only when the combination of PAMAM-gold nanocomposites and thiol-modified dendron was less sterically dense, modified dendron (G0.5-SH). The mechanisms for morphology changes in the dendrimer-gold nanocomposites by the addition of these thiols are discussed. 相似文献
10.
Kunihito Miyake Yasuhiro Masaki Ikuya Miyamoto Shozo Yanagida Takeshi Ohno Akio Yoshimura Chyongjin Pac 《Photochemistry and photobiology》1993,58(5):631-636
We have investigated the photosensitized monomerization of the cis,syn -cyclobutane dimer of 1,3-di-methylthymine using riboflavin tetraacetate and a 5-deazaflavin derivative as photosensitizer. Although little monomerization of the dimer is induced by photoexcitation of the flavins in the absence of any additives, the flavins can function as an efficient photosensitizer in the presence of magnesium perchlorate. Mechanistic studies involving spectroscopic, quantum-yield and flash-photolysis measurements demonstrated that the photosensitized monomerization exclusively proceeds through electron transfer from the dimer to the triplet flavins complexed with Mg2+ . The effects of magnesium perchlorate are compared with those on the chloranil-photosensitized monomerization and also with the effects of HClO4 on the flavin-photosensitized reaction. 相似文献