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1.
Regioselective demethylation of 3,4-dihydropapaveraldine (2a) at 7 and 3' positions affords a properly substituted diphenolic key intermidiate (2d) for the synthesis of reticuline and N-norreticuline.  相似文献   
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The charged particle multiplicity distribution has been studied for non-single-diffractive π+ p andpp collisions at \(\sqrt s = 22\) GeV, for full phase space as well as for intervals in rapidity, azimuthal angle and transverse momentum. In general, the multiplicity distribution is well described by a negative binomial. From comparison of the distribution for negative or positive particles to that of all charged particles, cascading is favoured as an interpretation over stimulated emission. Interesting consequences follow from a comparison of our results to those at collider energies and toe + e ? data at comparable energy. Furthermore, evidence is given that the multiplicity distribution is not exactly of negative binomial type in every (connected or disconnected) phase space region.  相似文献   
4.
The intermittency phenomenon is investigated in proton-gold, oxygen-gold, sulphur-gold and sulphur-sulphur collisions at 200 GeV per nucleon. The data were taken with the NA 35 streamer chamber detector at the CERN SPS. The data samples are carefully corrected for double counting of tracks and for contamination from photon conversions, particle decays and secondary interactions. The analysis is carried out in terms of factorial moments, using a new definition, and of correlation integrals. Both methods show the presence of nonstatistical fluctuations (intermittency). The main conclusions are: The observation of the effect for pairs of hadrons with negative charges and its near absence for pairs of opposite charges is consistent with the assumption that Bose-Einstein correlations yield the dominant contribution. The intermittency effect is not proportional to (dn/dy)–1 which would be expected in superposition models. The measured relation between the second and third factorial moment for negative hadrons indicates that genuine 3-particle correlations are small. The predictions of a Monte Carlo simulation which is based on the Lund Fritiof model with the inclusion of Bose-Einstein correlations agree with the experimental results.Deceased  相似文献   
5.
The mercury perrhenates with the empirical formulas HgReO4 and Hg2ReO5 were prepared by annealing powdered mixtures of mercury(II)oxide and mercury(II)metaperrhenate Hg(ReO4)2 in sealed silica tubes. Their crystal structures were determined from single-crystal X-ray data. HgReO4 crystallizes dimeric with nearly linear O3Re? O? Hg? Hg? O? ReO3 molecular units and Hg2ReO5 has a solid state structure, where Hg(I) and Hg(II) together with oxygen atoms form 14-membered rings, which are condensed to two-dimensionally infinite polycationic nets of composition (Hg22+ · 2 HgO)n. These nets are separated from each other by tetrahedral ReO4? anions.  相似文献   
6.
Complexation stoichiometries and formation constants of tri- and tetra-protonated forms of 1,4,8,12-tetraazacyclopentadecane with NO 3 , Cl, IO 3 and SO 4 2– ions are determined by pH potentiometric and13C NMR spectrometric measurements. Estimates of H and S are obtained from the values of the temperature dependent formation constants and acid dissociation constants. All four anions form only 1 : 1 complexes with the triprotonated amine species. NO 3 and Cl form 1 : 1 complexes only with the tetraprotonated amine, while IO 3 and SO 4 2– form both 1 : 1 and 2 : 1 complexes. The complexation behavior is interpreted in terms of solvation and internal hydrogen bonding interactions.  相似文献   
7.
Central limit theorem estimates of anomalous fractal dimensions of self-similar random cascades are studied. It is found that, in general, the normal approximation fails badly. A systematic series of approximations which converges to the exact result (both for the fractal dimensions and for the distribution itself) is derived for the -model. Consequences for the empty bin effect are indicated.Supported by the World Laboratory/HED and the CERN/LAA Projects  相似文献   
8.
New chromium(III) complexes, [Cr(C2O4)2(2-hnic)]2− and [Cr(C2O4)2(3-hpic)]2− (where 2-hnic = O,O′-bonded 2-hydroxynicotinic acid and 3-hpic = N,O-bonded 3-hydroxypicolinic acid), were obtained and characterized in solution. The acid-catalyzed aquation of the both complexes leads to liberation of the appropriate pyridinecarboxylic acid and formation of cis-[Cr(C2O4)2(H2O)2]. Kinetics of these reactions were studied spectrophotometrically in the 0.1–1.0 M HClO4 range, at I = 1.0 M. In the case of [Cr(C2O4)2(2-hnic)]2−, a slow chelate-ring opening at the Cr–O (phenolate) bond is followed by a fast Cr–O (carboxylate) bond breaking. The rate law: kobs = kHQH[H+] was established, where kH is the acid-catalyzed rate constant and QH is the protonation constant of the coordinated phenolate oxygen atom. In the case of [Cr(C2O4)2(3-hpic)]2−, the reversible chelate-ring opening at Cr–N bond is followed by the rate determining step – the one-end bonded ligand liberation. The rate law for the first step was determined: kobs = k1+k−1/Q1[H+], where k1 and k−1 are the rate constants of the chelate-ring opening and closure and Q1 is the protonation constant of the pyridine nitrogen atom. The aquation mechanisms are proposed and the effect of ligand coordination mode on complex reactivity is discussed.  相似文献   
9.
Motzkin numbers are derived from a special case of Random Domino Automaton – recently proposed a slowly driven system being a stochastic toy model of earthquakes. It is also a generalisation of 1D Drossel–Schwabl forest-fire model. A solution of the set of equations describing stationary state of Random Domino Automaton in inverse-power case is presented. A link with Motzkin numbers allows to present explicit form of asymptotic behaviour of the automaton.  相似文献   
10.
Abstract

The synthesis of a variety of substituted bisphenol A polysulfones, including nitro, amino, aminomethyl, ethyl, and methyl derivatives, is described. Nuclear magnetic resonance (NMR) (both proton and carbon, and several 2-D experiments) data confirm conclusions on the substitution site based on arguments on inductive effects in the phenyl rings. The proton ortho to the oxygen in the bisphenol A (BPA) residue is replaced in electrophilic substitution reactions. The degree of substitution was also calculated from the NMR results. The ethyl and methyl derivatives were expected, from the starting reactants, to each have a BPA ring substituted. The NMR data showed that, on the average, this is true. The nitro derivative also has substitution in every BPA ring, while the amino and aminomethyl derivatives have only intermittent BPA rings substituted. Measured degrees of substitution (DS) varied from 0.11 to 2.25.  相似文献   
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