全文获取类型
收费全文 | 863篇 |
免费 | 33篇 |
国内免费 | 1篇 |
专业分类
化学 | 691篇 |
晶体学 | 5篇 |
力学 | 10篇 |
数学 | 66篇 |
物理学 | 125篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 51篇 |
2021年 | 51篇 |
2020年 | 27篇 |
2019年 | 42篇 |
2018年 | 20篇 |
2017年 | 20篇 |
2016年 | 30篇 |
2015年 | 36篇 |
2014年 | 48篇 |
2013年 | 64篇 |
2012年 | 72篇 |
2011年 | 89篇 |
2010年 | 47篇 |
2009年 | 30篇 |
2008年 | 50篇 |
2007年 | 53篇 |
2006年 | 38篇 |
2005年 | 27篇 |
2004年 | 24篇 |
2003年 | 15篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 8篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1991年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1976年 | 1篇 |
1969年 | 1篇 |
1965年 | 2篇 |
排序方式: 共有897条查询结果,搜索用时 15 毫秒
1.
Peralta Cecilia Mariana Acosta Gimena Henestrosa Cecilia Gil Raúl Andrés Fernández Liliana Patricia 《Journal of Analytical Chemistry》2022,77(3):308-317
Journal of Analytical Chemistry - The present development involved a flow injection strategy using a mini-column of multiwalled carbon nanotubes and fluorescent detection (λex of 283 nm,... 相似文献
2.
Marilena Vasilescu Titus Constantinescu Mariana Voicescu Helge Lemmetyinen Elina Vuorimaa 《Journal of fluorescence》2003,13(4):315-322
The spectrophotometric study of luminol (LH2) in dimethyl sulfoxide (DMSO), DMSO-water solutions, and alkaline DMSO and DMSO-water solutions has been done, focusing on the effect of the KOH additon on LH2 absorption and fluorescence properties. The absorption spectra indicate an acid-base equilibrium, and the luminol dianion (L2–) formation at 3 × 10–4 – 2.4 × 10–3
M KOH. The decrease of the fluorescence intensity and the variation of the excitation spectra of LH2-DMSO-KOH solutions with KOH concentration have been similarly explained. The acid-base process is reversible. The addition of HCl to the solution with 3.0 × 10–3 M KOH leads to an increase of the fluorescence intensity to its highest value, observed in pure DMSO. The addition of HCl to the LH2-DMSO solution leads to the decrease of the fluorescence intensity as a result of the LH+
3 cation formation. In LH2-DMSO-water, the fluorescence band is shifted from 405 nm to 424 nm and increased in the intensity. In the presence of KOH (in LH2-DMSO-water-KOH solution) a new band appears, with the maximum at 485 nm and the band at 405 nm decreased. The changes in fluorescence lifetimes also evidence the different chemical species formed. 相似文献
3.
Alvaro P. Raposo Hans J. Weber David E. Alvarez-Castillo Mariana Kirchbach 《Central European Journal of Physics》2007,5(3):253-284
We briefly review the five possible real polynomial solutions of hypergeometric differential equations. Three of them are
the well known classical orthogonal polynomials, but the other two are different with respect to their orthogonality properties.
We then focus on the family of polynomials which exhibits a finite orthogonality. This family, to be referred to as the Romanovski
polynomials, is required in exact solutions of several physics problems ranging from quantum mechanics and quark physics to
random matrix theory. It appears timely to draw attention to it by the present study. Our survey also includes several new
observations on the orthogonality properties of the Romanovski polynomials and new developments from their Rodrigues formula. 相似文献
4.
Mariana Weissmann Andres Saul 《Physica C: Superconductivity and its Applications》1991,180(5-6):381-386
An alloy model is proposed for the electronic structure of high-temperature superconductors. It is based on the assumption that holes and extra electrons are localized in small copper-oxygen clusters, that would be the components of such an alloy. This model, when used together with quantum chemical calculations on small clusters, can explain the structure observed in the experimental densities of states of both hole and electron superconductors close to the Fermi energy. The main point is the strong dependence of the energy level distribution and composition on the number of electrons in a cluster. The alloy model also suggests a way to correlate Tc with the number of holes, or extra electrons, and the number of adequate clusters to locate them. 相似文献
5.
6.
Mariana Graña 《Letters in Mathematical Physics》2006,78(3):279-305
String theory is consistently defined in ten dimensions. In order to extract any information about four-dimensional physics, we need to understand the properties of the six-dimensional compact manifold orthogonal to our four-dimensional universe. A possibility that is being very much explored lately is to look at manifolds on which background fluxes are turned on. In this article, we present an introduction to string theory, focusing on its massless sector. We then review traditional compactifications to four–dimensions, and finally motivate and describe the so-called flux compactifications. We interpret the allowed six-dimensional manifolds from the point of view of generalized complex geometry. 相似文献
7.
Jorge F. J. Coelho Ana M. F. P. Silva Anatoliy V. Popov Virgil Percec Mariana V. Abreu Pedro M. O. F. Gonalves M. H. Gil 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):3001-3008
The synthesis of a block copolymer poly(vinyl chloride)‐b‐poly(n‐butyl acrylate)‐b‐poly(vinyl chloride) is reported. This new material was synthesized by single‐electron‐transfer/degenerative‐chain‐transfer‐mediated living radical polymerization (SET‐DTLRP) in two steps. First, a bifunctional macroinitiator of α,ω‐di(iodo)poly (butyl acrylate) [α,ω‐di(iodo)PBA] was synthesized by SET‐DTLRP in water at 25 °C. The macroinitiator was further reinitiated by SET‐DTLRP, leading to the formation of the desired product. This ABA block copolymer was synthesized with high initiator efficiency. The kinetics of the copolymerization reaction was studied for two PBA macroinitiators with number–average molecular weight of 10 k and 20 k. The relationship between the conversion and the number–average molecular weight was found to be linear. The dynamic mechanical thermal analysis suggests just one phase, indicating that copolymer behaves as a single material with no phase separation. This methodology provides the access to several block copolymers and other complex architectures that result from combinations of thermoplastics (PVC) and elastomers (PBA). From industrial standpoint, this process is attractive, because of easy experimental setup and the environmental friendly reaction medium. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3001–3008, 2006 相似文献
8.
Jorge F. J. Coelho Ana M. F. P. Silva Anatoliy V. Popov Virgil Percec Mariana V. Abreu Pedro M. O. F Gonalves M. H. Gil 《Journal of polymer science. Part A, Polymer chemistry》2006,44(9):2809-2825
Living radical polymerization of n‐butyl acrylate was achieved by single electron transfer/degenerative‐chain transfer mediated living radical polymerization in water catalyzed by sodium dithionate. The plots of number–average molecular weight versus conversion and ln[M]0/[M] versus time are linear, indicating a controlled polymerization. This methodology leads to the preparation of α,ω‐di(iodo) poly (butyl acrylate) (α,ω‐di(iodo)PBA) macroinitiators. The influence of polymerization degree ([monomer]/[initiator]), amount of catalyst, concentration of suspending agents and temperature were studied. The molecular weight distributions were determined using a combination of three detectors (TriSEC): right‐angle light scattering (RALLS), a differential viscometer (DV), and refractive index (RI). The methodology studied in this work represents a possible route to prepare well‐tailored macromolecules made of butyl acrylate in an environmental friendly reaction medium. Moreover, such materials can be subsequently functionalized leading to the formation of different block copolymers of composition ABA. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2809–2825, 2006 相似文献
9.
Gerhard Laus Johannes Schütz Herwig Schottenberger Max Andre Klaus Wurst Mariana Spetea Karl‐Hans Ongania AdrianG. Müller Helmut Schmidhammer 《Helvetica chimica acta》2003,86(10):3274-3280
The two diastereoisomeric ferrocenyl‐substituted orvinols 2 and 3 were prepared. The modified alkaloids are still able to interact with opioid receptors (see Table). The ferrocene moiety allows highly selective and sensitive electrochemical detection. The X‐ray crystal structure of the major isomer 2 was determined. The combination of a metallocene and a morphinan alkaloid holds promise for useful antitumor activity. 相似文献
10.
The asymmetric total synthesis of (-)-reveromycin A is described. The key steps involved a Lewis acid catalyzed inverse electron demand hetero-Diels-Alder reaction followed by hydroboration/oxidation to afford the spiroketal core 4 in a highly stereoselective manner and introduction of the C18 hemisuccinate by high-pressure acylation. 相似文献