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Shenghao Li Jing Lin Mareen Schaller Sylvio Indris Xin Zhang Torsten Brezesinski Ce-Wen Nan Shuo Wang Florian Strauss 《Angewandte Chemie (International ed. in English)》2023,62(50):e202314155
Superionic solid electrolytes (SEs) are essential for bulk-type solid-state battery (SSB) applications. Multicomponent SEs are recently attracting attention for their favorable charge-transport properties, however a thorough understanding of how configurational entropy (ΔSconf) affects ionic conductivity is lacking. Here, we successfully synthesized a series of halogen-rich lithium argyrodites with the general formula Li5.5PS4.5ClxBr1.5-x (0≤x≤1.5). Using neutron powder diffraction and 31P magic-angle spinning nuclear magnetic resonance spectroscopy, the S2−/Cl−/Br− occupancy on the anion sublattice was quantitatively analyzed. We show that disorder positively affects Li-ion dynamics, leading to a room-temperature ionic conductivity of 22.7 mS cm−1 (9.6 mS cm−1 in cold-pressed state) for Li5.5PS4.5Cl0.8Br0.7 (ΔSconf=1.98R). To the best of our knowledge, this is the first experimental evidence that configurational entropy of the anion sublattice correlates with ion mobility. Our results indicate the possibility of improving ionic conductivity in ceramic ion conductors by tailoring the degree of compositional complexity. Moreover, the Li5.5PS4.5Cl0.8Br0.7 SE allowed for stable cycling of single-crystal LiNi0.9Co0.06Mn0.04O2 (s-NCM90) composite cathodes in SSB cells, emphasizing that dual-substituted lithium argyrodites hold great promise in enabling high-performance electrochemical energy storage. 相似文献
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Mueller M Tebbe M Andreeva DV Karg M Alvarez Puebla RA Pazos Perez N Fery A 《Langmuir : the ACS journal of surfaces and colloids》2012,28(24):9168-9173
Here, a new surface enhanced Raman spectroscopy (SERS) platform suitable for gas phase sensing based on the extended organization of poly-N-isopropylacrylamide (pNIPAM)-coated nanostars over large areas is presented. This system yields high and homogeneous SERS intensities, and simultaneously traps organic chemical agents as pollutants from the gas phase. pNIPAM-coated gold nanostars were organized into parallel linear arrays. The optical properties of the fabricated substrates are investigated, and applicability for advanced sensing is demonstrated through the detection in the gas phase of pyrene traces, a well-known polyaromatic hydrocarbon. 相似文献
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Mareen Stahlberger Noah Schwarz Christoph Zippel Jens Hohmann Dr. Martin Nieger Dr. Zahid Hassan Prof. Dr. Stefan Bräse 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(3):e202103511
This report describes the synthesis of a [2.2]paracyclophane-derived annulated 3-amino-imidazole ligand library through a Groebke-Blackburn-Bienaymé three-component reaction (GBB-3CR) approach employing formyl-cyclophanes in combination with diverse aliphatic and aromatic isocyanides and heteroaromatic amidines. The GBB-3CR process gives access to skeletally-diverse cyclophanyl imidazole ligands, namely 3-amino-imidazo[1,2-a]pyridines and imidazo[1,2-a]pyrazines. Additionally, a one-pot protocol for the GBB-3CR by an in situ generation of cyclophanyl isocyanide is demonstrated. The products were analyzed by detailed spectroscopic techniques, and the cyclophanyl imidazo[1,2-a]pyridine was confirmed unambiguously by single-crystal X-Ray crystallography. The cyclophanyl imidazole ligands can be readily transformed to showcase their useful utility in preparing N,C-palladacycles through regioselective ortho-palladation. 相似文献
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Multifunctional Coating Improves Cell Adhesion on Titanium by using Cooperatively Acting Peptides
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Mareen Pagel Dr. Rayk Hassert Torsten John Prof. Dr. Manfred Wießler Prof. Dr. Bernd Abel Prof. Dr. Annette G. Beck‐Sickinger 《Angewandte Chemie (International ed. in English)》2016,55(15):4826-4830
Promotion of cell adhesion on biomaterials is crucial for the long‐term success of a titanium implant. Herein a novel concept is highlighted combining very stable and affine titanium surface adhesive properties with specific cell binding moieties in one molecule. A peptide containing l ‐3,4‐dihydroxyphenylalanine was synthesized and affinity to titanium was investigated. Modification with a cyclic RGD peptide and a heparin binding peptide (HBP) was realized by an efficient on‐resin combination of Diels–Alder reaction with inverse electron demand and CuI catalyzed azide–alkyne cycloaddition. The peptide was fluorescently labeled by thiol Michael addition. Conjugating the cyclic RGD and HBP in one peptide gave improved spreading, proliferation, viability, and the formation of well‐developed actin cytoskeleton and focal contacts of osteoblast‐like cells. 相似文献
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Holger Dette Mareen Marchlewski Jens Wagener 《Annals of the Institute of Statistical Mathematics》2012,64(5):1045-1070
In the common nonparametric regression model, we consider the problem of testing the hypothesis that the coefficient of the scale and location function is constant. The test is based on a comparison of the standardized (by a local linear estimate of the scale function) observations with their mean. We show weak convergence of a centered version of this process to a Gaussian process under the null hypothesis and the alternative and use this result to construct a test for the hypothesis of a constant coefficient of variation in the nonparametric regression model. A small simulation study is also presented to investigate the finite sample properties of the new test. 相似文献