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1.
Summary Potassium dihydro-bis-(1-indazolyl)borate, synthesized from potassium borohydride and indazole, has been used as a reagent to yield complexes with copper(II), nickel(II), cobalt(II), manganese(II) and iron(III) ions. From i.r. spectral studies the ligand is uninegative and bidentate and coordination occurs through the nitrogen atom at position 2 of the indazole ring system in all cases. With the sole exception of the copper(II) complex, the nitrogen atom at position 1 is also involved in forming a bridge with an adjacent metal ion. On the basis of electronic spectral studies and magnetic susceptibility measurements a distorted square planar structure involving chlorine bridges has been proposed for the copper complex. An octahedral geometry with ligand bridges for all complexes is tentatively proposed and it appears that all are polymers. 相似文献
2.
Muhammad Ali Ehsan Muhammad Adil Mansoor Muhammad Mazhar Asif Ali Tahir Mazhar Hamid K. G. Upul Wijayantha 《应用有机金属化学》2012,26(9):493-498
A single molecular heterobimetallic complex, [Co2Ti(μ3‐O)(TFA)6(THF)3] (1) [TFA = trifluoroacetate, THF = tetrahydrofuran], was synthesized, structurally and spectroscopically characterized and implemented as a single‐source precursor for the preparation of CoTiO3–CoO composite thin films by aerosol‐assisted chemical vapour deposition (AACVD). The precursor complex was prepared by interaction of Co(OAc)2.4H2O [OAc = (CH3COO?)] with Ti(iso‐propoxide)4 in the presence of trifluoroacetic acid in THF, and was analysed by melting point, CHN, FT‐IR, single‐crystal X‐ray diffraction and thermogravimetric analysis. The precursor complex thermally decomposed at 480 °C to give a residual mass corresponding to a CoTiO3–CoO composite material. Good‐quality crystalline CoTiO3–CoO composite thin films deposited at 500 °C by AACVD and characterized through powder X‐ray diffraction and scanning electron microscopy/energy‐dispersive X‐ray spectroscopy show that the crystallites have a rose‐flower‐like morphology with an average petal size in the range of 2–6 µm. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
3.
Energy transfer across aluminum and silicon films through phonon transport is examined in line with the laser short-pulse interaction with the aluminum film. The modified two-equation model is incorporated to compute electron and lattice site temperatures in the aluminum film while phonon radiative transport is used to predict equilibrium temperature in the silicon film. The thermal boundary resistance is considered at the interface of the films in the analysis. The numerical scheme using the finite difference method is adopted to solve the governing equations of energy. It is found that lattice site temperature rise is gradual in the aluminum film in the late heating period. However, equilibrium temperature decay is sharp in the region of silicon interface during this period. The thermal boundary resistance lowers lattice site temperature considerably in the region of the aluminum interface. 相似文献
4.
The separation of Cd(II) and Ni(II) ions was studied in an aqueous sulphate medium using supported liquid membrane (SLM). D2EHPA/M2EHPA was used as a mobile carrier, microporous hydrophobic PTFE film was used as a solid support for the liquid membrane, and the strip phase was sulphuric acid. The effects of different parameters such as feed concentration, carrier concentration, feed phase pH, and strip phase pH on the separation factor and flux of Cd(II) and Ni(II) ions were studied. The optimum values obtained to achieve the maximum flux were 5.0 for feed pH, 40 vol. % for D2EHPA/M2EHPA concentration in the membrane phase, 0.5 for strip pH, and 0.012 mass % for feed concentration. Under these optimum conditions, the flux values of Cd(II) and Ni(II) were 15.7 × 10?7 kg m?2 s?1 and 2.6 × 10?7 kg m?2 s?1, respectively. The separation factors of Cd(II) over Ni(II) were studied under different experimental conditions. At a carrier concentration of 10 vol. % and feed concentration of 0.012 mass %, the maximum value of 185.1 was obtained for the separation factor of Cd(II) over Ni(II). After 24 h, the percentages of the extracted Cd(II) and Ni(II) were 83.3 % and 0.45 %, respectively. 相似文献
5.
Tanoori Betsabeh Zolghadri Jahromi Mansoor Mansoori Eghbal G. 《Journal of computer-aided molecular design》2021,35(8):883-900
Journal of Computer-Aided Molecular Design - In the field of drug–target interactions prediction, the majority of approaches formulated the problem as a simple binary classification task.... 相似文献
6.
An facile and efficient protocol for the synthesis of 13‐aryl‐indeno[1,2‐b]naphtha[1,2‐e]pyran‐ 12(13H)‐ ones has been developed that proceeds via the one‐pot three‐component sequential reaction of an aromatic aldehyde with β‐naphthol and 2H‐indene‐1,3‐dione under solvent‐free conditions in the presence of a poly(4‐vinylpyridinium)hydrogen sulfate(P(4‐VPH)HSO4) catalyst. The catalyst can be reused several times, making this procedure facile, practical, and sustainable. The simple experimental procedure, solvent‐free reaction conditions, use of an inexpensive catalyst, short react time, and excellent yields are some of the major advantages of this methodology. 相似文献
7.
Majid Ghashang Krishnamoorthy Aswin Syed Sheik Mansoor 《Research on Chemical Intermediates》2014,40(3):1135-1145
A facile and environmentally benign synthesis of some 2-amino-6-(2-oxo-2H-chromen-3-yl)-4-arylnicotinonitrile derivatives from the reaction of 3-acetylcoumarin, aromatic aldehydes, and malononitrile under solvent-free condition in the presence of silica-supported perchloric acid (HClO4–SiO2) is described. The ability to reuse the catalyst, the high yields, and ease of purification are the important features of this process. 相似文献
8.
Mansoor FarbodMorteza Zargar Shoushtari Saeed Parhoodeh 《Physica B: Condensed Matter》2011,406(2):205-210
In this paper we have introduced a simple method for the fabrication of aluminum doped zinc oxide (AZO) nanoparticles. The Zn1−xAlxO nanoparticles with different concentrations of Al (x=0.01, 0.03, 0.06, 0.09, 0.12) were fabricated successfully by this method. The samples were analyzed by the use of several techniques such as SEM, EDX, XRD, PL and UV-vis spectroscopy. The SEM images showed that the fabricated nanoparticles had spherical shapes. The XRD patterns of the samples indicated that the Al atoms substituted in the Zn positions in the crystal lattice of ZnO and there were some changes in the lattice parameters. A blue shift in the λmax of the absorption and a red shift in the λmax of the emission were observed. The results also indicated that the amount of shifts had a direct relationship with the changes in the lattice parameters. 相似文献
9.
10.
This paper proposes an efficient approach for four-dimensional(4D) parameter estimation of plane waves impinging on a 2-L shape array. The 4D parameters include amplitude, frequency and the two-dimensional(2D) direction of arrival,namely, azimuth and elevation angles. The proposed approach is based on memetic computation, in which the global optimizer, particle swarm optimization is hybridized with a rapid local search technique, pattern search. For this purpose,a new multi-objective fitness function is used. This fitness function is the combination of mean square error and the correlation between the normalized desired and estimated vectors. The proposed hybrid scheme is not only compared with individual performances of particle swarm optimization and pattern search, but also with the performance of the hybrid genetic algorithm and that of the traditional approach. A large number of Monte–Carlo simulations are carried out to validate the performance of the proposed scheme. It gives promising results in terms of estimation accuracy, convergence rate, proximity effect and robustness against noise. 相似文献