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1.
Anna V. Gulevskaya Shee Van Dang Alexander F. Pozharskii 《Journal of heterocyclic chemistry》2005,42(3):413-419
Synthesis of some condensed pyrrolo‐, thieno‐, furo‐, pyrido‐ and pyranopteridines as well as isomeric pyrrolo‐ and thienopyrimido[4,5‐c]pyridazines from alkynyl derivatives of 6,8‐dimethylpyrimido[4,5‐c]pyridazine‐5,7(6H,8H)‐dione and 1,3‐dimethyllumazine is represented. 相似文献
2.
Sonogashira cross-coupling of 6-chloro-1,3-dimethyllumazine with terminal alkynes gave 6-alkynyl derivatives in good yields. Oxidative amination of the latter with primary alkylamines was accompanied by the pyrrole-ring closure to form 1-R"-2-R-6,8-dimethylpyrrolo[3,2-g]pteridine-5,7(6H,8H)-diones. The addition of bromine to 6-alkynyllumazines afforded the corresponding dibromoalkenes whose treatment with sodium trithiocarbonate gave rise to 2-R-6,8-dimethylthieno[3,2-g]pteridine-5,7(6H,8H)-diones. The latter compounds are close analogs of the metabolite of molybdenum cofactor (molybdopterine). 相似文献
3.
We consider the problem of constructing a graphG* from a collection of isomorphic copies of a graphG in such a way that for every two copies ofG, either no vertices or a section graph isomorphic to a graphH is identified. It is shown that ifG can be partitioned into vertex-disjoint copies ofH, thenG* can be made to have at most |H| orbits. A condition onG so thatG* can be vertextransitive is also included. 相似文献
4.
Y. G. Shee M. A. Mahdi M. H. Al-Mansoori A. Ismail N. A. M. A. Hambali A. K. Zamzuri R. Mohamad S. Yaakob 《Laser Physics》2009,19(12):2194-2196
A simple configuration for the reduction of stimulated Brillouin scattering threshold in photonic crystal fiber is presented.
The threshold reduction is contributed by the bidirectional pumping scheme through the reflection of transmitted Brillouin
pump back to the gain medium. The pump recycling scheme has greatly reduced the Brillouin threshold of a 200-m long of photonic
crystal fiber from 50 to 30 mW of Brillouin pump power. 相似文献
5.
6,7-Dialkynyl-1,3-dimethylpteridine-2,4(1H,3H)-diones and 2,3-dialkynylquinoxalines have been shown to react with sodium azide in DMF at room temperature giving rise 9,11-dimethyl-[1,2,3]triazolo[1′,5′;1,2]pyrido[4,3-g]pteridine-8,10(9H,11H)-diones and [1,2,3]triazolo[1′,5′;1,2]pyrido[3,4-b]quinoxalines. A novel tandem cyclization involves 1,3-dipolar cycloaddition of an azide ion to the carbon-carbon triple bond followed by intramolecular nucleophilic addition of the intermediate 1,2,3-triazole N-anion to another CC bond. 相似文献
6.
This is the first time that fouling of cation-exchange membranes during cheddar cheese whey electroacidification with bipolar membranes is reported. A mineral fouling was observed only on the cationic membrane side in contact with the base. The deposit was identified as magnesium hydroxide and this fouling was more important on the cation-exchange membrane situated close to the cathode. Little deposit was formed after six electroacidification runs, but on long time, the buildup of fouling film would lead after many electroacidifications to an important decrease of the system efficiency. Since, fouling of permselective membranes represents one of the major issues in electrodialytic processes, this result will be the basis for the determination of cleaning conditions allowing the prevention of such a fouling. 相似文献
7.
Nirmal K. Shee Shanti G. Patra Michael G. B. Drew 《Journal of Coordination Chemistry》2016,69(24):3677-3691
Using the 1 : 2 condensate of benzil and 2-hydrazinopyridine as the ligand LH2 (H: dissociable NH proton), the red complex Cu(LH2)(ClO4)2 (1) was synthesized. The ligand also afforded the orange [Zn(LH2)(OH2)2](ClO4)2 (2). The X-ray crystal structures of the ligand, 1 and 2 have been determined. The metals in 1 and 2 have octahedral N4O2 environments. 1 is paramagnetic with μeff of one unpaired electron (1.63 μB and displays an axial EPR spectrum in the solid state with <g> = 2.07, characteristic of a (dx2?y2)1 ground state (g|| > g⊥; A|| = 16 mT). In cyclic voltammetry, 1 displays a two-electron oxidation around 0.9 V versus NHE. The two-electron oxidized (coulometrically) solution of 1 (golden yellow) gives an EPR spectrum with <g> = 2.17 and g|| < g⊥. The reaction of PPh3 with 1 yields the orange complex [Cu(LH2)(PPh3)](ClO4)2 (4). With the assumed chemical formula, the effective magnetization of 4 corresponds to one electron. Its EPR spectrum in the solid state is isotropic with g = 2.07. This g value yields a theoretical μeff of 1.80 μB at 298 K from Curie’s law, which matches very well with the experimental value of 1.89 μB at room temperature. Since single crystals of 4 could not be obtained, DFT calculations at the UBP86/6–311G(2d,p) level have been carried out and indicate that the cation in 4 is square pyramidal with the phosphine at the apex. The ease of the oxidation of the metal in 1 leads to the stabilization of the rare Cu(II)-P bond in 4. 相似文献
8.
Sk. Sheriff Shah Maniklal Shee Yarra Venkatesh Amit Kumar Singh Samya Samanta Prof. N. D. Pradeep Singh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(17):3703-3708
The combination of an organic photocatalyst [4CzIPN (1,2,3,5-tetrakis(carbazol-9-yl)-4,6 dicyanobenzene) or 5MeOCzBN (2,3,4,5,6-pentakis(3,6-dimethoxy-9 H-carbazol-9-yl)benzonitrile)], quinuclidine, and tetra-n-butylammonium phosphate (hydrogen-bonding catalyst) was employed for amide bond formations. The hydrogen-bonded OH group activated the adjacent C−H bond of alcohols towards hydrogen atom transfer (HAT) by a radical species. The quinuclidinium radical cation, generated through single-electron oxidation of quinuclidine by the photocatalyst, employed to abstract a hydrogen atom from the α-C−H bond of alcohols selectively due to a polarity effect-produced α-hydroxyalkyl radical, which subsequently converted to the corresponding aldehyde under aerobic conditions. Then the coupling of the aldehyde and an amine formed a hemiaminal intermediate that upon photocatalytic oxidation produced the amide. 相似文献
9.
Density functional theory (DFT) has been employed to study the geometric and electronic structures, band gap, thermodynamic
properties, density, and performance properties of a series of polynitrotriazoles at the B3LYP/aug-cc-pVDZ level. The detonation
performances were evaluated by the Kamlet–Jacobs semi-empirical equations based on the calculated densities and heats of reaction.
It has been found that the model compounds with the predicted densities of 1.8 g/cm3, detonation velocities of 8.8 km/s, and detonation pressures of 35 GPa may be novel potential candidates of high energy density
materials. The discrepancies in the performance properties, stabilities or sensitivities among isomers are caused by the relative
position of NH2 and NO2 groups. 相似文献
10.
He Huang Zack M. Strater Michael Rauch James Shee Thomas J. Sisto Colin Nuckolls Tristan H. Lambert 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(38):13452-13456
Visible‐light photocatalysis and electrocatalysis are two powerful strategies for the promotion of chemical reactions. Here, these two modalities are combined in an electrophotocatalytic oxidation platform. This chemistry employs a trisaminocyclopropenium (TAC) ion catalyst, which is electrochemically oxidized to form a cyclopropenium radical dication intermediate. The radical dication undergoes photoexcitation with visible light to produce an excited‐state species with oxidizing power (3.33 V vs. SCE) sufficient to oxidize benzene and halogenated benzenes via single‐electron transfer (SET), resulting in C?H/N?H coupling with azoles. A rationale for the strongly oxidizing behavior of the photoexcited species is provided, while the stability of the catalyst is rationalized by a particular conformation of the cis‐2,6‐dimethylpiperidine moieties. 相似文献