全文获取类型
收费全文 | 577篇 |
免费 | 23篇 |
国内免费 | 6篇 |
专业分类
化学 | 326篇 |
晶体学 | 8篇 |
力学 | 18篇 |
数学 | 146篇 |
物理学 | 108篇 |
出版年
2023年 | 3篇 |
2022年 | 15篇 |
2021年 | 25篇 |
2020年 | 22篇 |
2019年 | 27篇 |
2018年 | 20篇 |
2017年 | 19篇 |
2016年 | 46篇 |
2015年 | 15篇 |
2014年 | 31篇 |
2013年 | 42篇 |
2012年 | 37篇 |
2011年 | 36篇 |
2010年 | 18篇 |
2009年 | 12篇 |
2008年 | 23篇 |
2007年 | 9篇 |
2006年 | 12篇 |
2005年 | 13篇 |
2004年 | 17篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 11篇 |
1995年 | 9篇 |
1994年 | 14篇 |
1993年 | 9篇 |
1992年 | 6篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 4篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1978年 | 6篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有606条查询结果,搜索用时 15 毫秒
1.
Hypersonic longitudinal sound velocities in five silicate and alumino-silicate liquids have been measured between 293 and 2550 K by Brillouin spectroscopy. Together with previous observations for four other glasses and liquids of the system SiO2-Al2O3-CaO-MgO, these results are used to discuss changes in hypersonic velocities in three adjacent temperature domains, i.e., below, in, and above the glass transformation range. The temperature dependence of Brillouin velocities is consistent with the observed variations with temperature of viscosity, density, and mean heat capacity for the same three temperature domains. These variations of physical properties of alumino-silicate liquids are qualitatively in agreement with the Inherent Structure Theory for liquids. 相似文献
2.
Doan Nguyen 《Ukrainian Mathematical Journal》2004,56(10):1633-1645
We prove a generalization of the Brody reparametrization lemma.__________Published in Ukrains’kyi Matematychnyi Zhurnal, Vol. 56, No. 10, pp. 1369 – 1377, October, 2004. 相似文献
3.
We consider the first initial boundary-value problem for strongly parabolic systems in an infinite cylinder with nonsmooth boundary. We establish conditions for the existence of generalized solutions, an estimate for this solutions, and an estimate for the derivative of the solution. 相似文献
4.
5.
Transport of yttrium(III) from nitrate medium through liquid membrane containing tri-n-octyl-phosphine oxide (TOPO) in n-dodecane, supported on a nucleoporous filter, into a strip solution with ethylenediaminetetraacetic acid (EDTA) has been studied. The kinetic dependences of transport were obtained and compared with a model, resulting in calculation of permeability coeffients and initial fluxes of yttrium. The influence of salting-out agent, initial metal and nitric acid concentrations in the feed, and of concentration of carrier in membrane are discussed. 相似文献
6.
Hibaone has been synthesized from manool through a photochemical cycloaddition of Δ8(14) podocarpene-13-one to ethylene or 1,2 dichloroethylene. 相似文献
7.
Hong-Jie ZhangGhee Teng Tan Vu Dinh HoangNguyen Van Hung Nguyen Manh CuongDjaja Doel Soejarto John M PezzutoHarry H.S Fong 《Tetrahedron》2003,59(2):141-148
Bioassay directed-fractionation led to the identification of litseaverticillols A-H (1-8) from the leaves and twigs of Litsea verticillata Hance. These new sesquiterpenes possess a unique skeleton that was recently designated as ‘litseane’. The structures of these compounds were determined by spectroscopic means including 1D and 2D NMR data. Structural configurations were determined by ROESY experiments. Mosher ester reactions and optical rotation measurements established the sesquiterpenes 1-8 as racemates. Isolates 1-8 inhibited HIV-1 replication in HOG.R5 cells with IC50 values ranging from 2 to 15 μg/ml (8-58 μM) while affecting the growth of HOG.R5 at concentrations 2-3-fold higher. Based on this data, structure-activity relationships can be discerned, suggesting compounds of this class are good candidates for analog production. 相似文献
8.
9.
Dixon FM Masar MS Doan PE Farrell JR Arnold FP Mirkin CA Incarvito CD Zakharov LN Rheingold AL 《Inorganic chemistry》2003,42(10):3245-3255
The ligand 1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene, 3, was used to synthesize a mononuclear Rh(II) complex [(eta(1):eta(6):eta(1)-1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene)Rh][PF(6)](2), 6+, in a two-legged piano-stool geometry. The structural and electronic properties of this novel complex including a single-crystal EPR analysis are reported. The complex can be cleanly interconverted with its Rh(I) form, allowing for a comparison of the structural properties and reactivity of both oxidation states. The Rh(I) form 6 reacts with CO, tert-butyl isocyanide, and acetonitrile to form a series of 15-membered mononuclear cyclophanes [(eta(1):eta(1)-1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene)Rh(CO)(3)][PF(6)] (8), [(eta(1):eta(1)-1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene)Rh(CNC(CH(3))(3))(2)][PF(6)] (10), and [(eta(1):eta(1)-1,4-bis[4-(diphenylphosphino)butyl]-2,3,5,6-tetramethylbenzene)Rh(CO)(CH(3)CN)][PF(6)] (11). The Rh(II) complex 6+ reacts with the same small molecules, but over shorter periods of time, to form the same Rh(I) products. In addition, a model two-legged piano-stool complex [(eta(1):eta(6):eta(1)-1,4-bis[3-(diphenylphosphino)propoxy]-2,3,5,6-tetramethylbenzene)Rh][B(C(6)F(5))(4)], 5, has been synthesized and characterized for comparison purposes. The solid-state structures of complexes 5, 6, 6+, and 11 are reported. Structure data for 5: triclinic; P(-)1; a = 10.1587(7) A; b = 11.5228(8) A; c = 17.2381(12) A; alpha = 96.4379(13) degrees; beta = 91.1870(12) degrees; gamma = 106.1470(13) degrees; Z = 2. 6: triclinic; P(-)1; a = 11.1934(5) A; b = 12.4807(6) A; c = 16.1771(7) A; alpha = 81.935(7) degrees; beta = 89.943(1) degrees; gamma = 78.292(1) degrees; Z = 2. 6+: monoclinic; P2(1)/n; a = 11.9371(18) A; b = 32.401(5) A; c = 12.782(2) A; beta = 102.890(3) degrees; Z = 4. 11: triclinic; P(-)1; a = 13.5476(7) A; b = 13.8306(7) A; c = 14.9948(8) A; alpha = 74.551(1) degrees; beta = 73.895(1) degrees; gamma = 66.046(1) degrees; Z = 2. 相似文献
10.