Cyclic deformation of aluminium and its alloys

The formation of slip bands is the main mechanism of cyclic deformation in pure Al. Their density, orientation and heights in polycrystalline Al were investigated during cycling. Types, sizes and densities of precipitates are responsible for the mode of cyclic deformation in AlCu4 pure alloy. In technical Al alloys intermetallic phases have detrimental effects on deformation homogeneity and largely govern the fatigue mechanism of the material and especially microcrack initiation.     

含氧光敏引发体系的研究——Ⅵ.二苯酮/三乙胺体系引发光聚合过程中的再次引发效应

过去,作者曾发表了多种光敏引发体系引发烯类单体光聚合的工作,在研究2,2-二甲氧基苯乙酮在氧存在下引发甲基丙烯酸甲酯光聚合时,结合在聚合物链端的引发剂碎片具有光化学活性,在光聚合反应中产生高分子自由基,发生再次聚合,出现高分子量     

Photolysis of 2-dialkylamino-3-amino(or alkylamino)-1,4-naphthoquinones

Using¹H and¹³C NMR spectroscopy, naphthodihydroimidazolediols were identified as the primary products of photolysis of 2-dialkylamino-3-amino(alkylamino)-1,4-naphthoquinones. Their further non-photochemical (thermal) transformations depend on their structure and on the photolysis conditions.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 358–362, February, 1993.     

Synthesis of 2-amino-5,5-dialkyl-4-arylmethylidene-2-oxazolines from 2-alkyl-4-arylbut-3-yn-2-ols and guanidine

Reaction between 2-alkyl-4-arylbut-3-yn-2-ols and guanidine in refluxing pyridine affords 2-amino-5,5-dialkyl-4-arylmethylidene-2-oxazolines.     

Photochemical synthesis of 2-amino-1-hydroxy-9,10-anthraquinone-9-alkyl(aryl)imines

Irradiation of a mixture of 1-aryloxy-2-amino-9,10-anthraquinone and amines in benzene results in formation of the derivatives of 2-amino-1-hydroxy-9,10-anthraquinone-9-alkyl(aryl)imines in a high yield. 2-Amino-1-hydroxy-9,10-anthraquinone-9-aikylimines were shown by¹³C and¹⁵N NMR to exist predominantly in the enaminoquinoid form whereas 2-amino-1-hydroxy-9,10-anthraquinone-9-arylimines exist in the oxyimine form. Sunlight irradiation of the derivatives of 2-benzoylamino-9,10-anthraqumone-9-alkylimines results in formation of the photocyclization products — 4-benzoylaminoanthra-[9,1-d,e]-1,3-oxasinones-7.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 940–944, May, 1993.