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Dr. William Lecroq Jules Schleinitz Mallaury Billoue Anna Perfetto Prof. Dr. Annie-Claude Gaumont Prof. Jacques Lalevée Dr. Ilaria Ciofini Dr. Laurence Grimaud Dr. Sami Lakhdar 《Chemphyschem》2021,22(12):1237-1242
We report herein an unprecedented combination of light and P(III)/P(V) redox cycling for the efficient deoxygenation of aromatic amine N-oxides. Moreover, we discovered that a large variety of aliphatic amine N-oxides can easily be deoxygenated by using only phenylsilane. These practically simple approaches proceed well under metal-free conditions, tolerate many functionalities and are highly chemoselective. Combined experimental and computational studies enabled a deep understanding of factors controlling the reactivity of both aromatic and aliphatic amine N-oxides. 相似文献
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