排序方式: 共有7条查询结果,搜索用时 15 毫秒
1
1.
Makiabadi Batoul Zakarianezhad Mohammad Hosseini Seyede Samira 《Structural chemistry》2021,32(3):1019-1037
Structural Chemistry - In this work, the potential of BN, AlN, and CN nanotubes as the drug delivery systems of Tegafur (TG) was investigated by the density functional theory (DFT). The doping... 相似文献
2.
3.
4.
5.
Batoul Makiabadi Mohammad Zakarianejad Sotoodeh Bagheri Hamid Reza Masoodi Raziyeh Sadaat Aghaie 《International journal of quantum chemistry》2013,113(21):2361-2371
Molecular interactions between uracil and nitrous acid (U–NA) [C4N2O2H4? NO2H] have been studied using B3LYP, B3PW91, and MP2 methods with different basis sets. The optimized geometries, harmonic vibrational frequencies, charge transfer, topological properties of electron density, nucleus‐independent chemical shift (NICS), and nuclear magnetic resonance one‐ and two‐bonds spin–spin coupling constants were calculated for U–NA complexes. In interaction between U and NA, eight cyclic complexes were obtained with two intermolecular hydrogen bonds N(C)HU…N(O) and OHNA…OU. In these complexes, uracil (U) simultaneously acts as proton acceptor and proton donor. The most stable complexes labeled, UNA1 and UNA2, are formed via NH bond of U with highest acidity and CO group of U with lowest proton affinity. There is a relationship between hydrogen bond distances and the corresponding frequency shifts. The solvent effect on complexes stability was examined using B3LYP method with the aug‐cc‐pVDZ basis set by applying the polarizable continuum model (PCM). The binding energies in the gas phase have also been compared with solvation energies computed using the PCM. Natural bond orbital analysis shows that in all complexes, the charge transfer takes place from U to NA. The results predict that the Lone Pair (LP)(O)U → σ*(O? H) and LP(N(O)NA → σ*(N(C)? H)U donor–acceptor interactions are most important interactions in these complexes. Atom in molecule analysis confirms that hydrogen bond contacts are electrostatic in nature and covalent nature of proton donor groups decreases upon complexation. The relationship between spin–spin coupling constant (1hJH…Y and 2hJH…Y) with interaction energy and electronic density at corresponding hydrogen bond critical points and H‐bonds distances are investigated. NICS used for indicating of aromaticity of U ring upon complexation. © 2013 Wiley Periodicals, Inc. 相似文献
6.
Batoul Makiabadi Mehri Saddat Ekrami-Kakhki Shamsi Zareye 《Phosphorus, sulfur, and silicon and the related elements》2019,194(1-2):57-63
DFT calculations were performed to investigation of the influence of doping three atoms of aluminum on the electronic properties of the (4,0) zigzag boron nitride nanotube (BNNT). Also, adsorption properties of nitrosamine (NA) and thionitrosamine (TNA) molecules as carcinogen agents onto BN and BAl3N nanotubes were studied. The results show that the B3AlN nanotube is the most energetically favorable candidates for adsorption of these molecules. Also, B(B3Al)NNT/TNA complexes are more stable than B(B3Al)NNT/NA complexes. The HOMO–LUMO gap, electronic chemical potential (μ), hardness (?), softness (S), the maximum amount of electronic charge (ΔNmax) and electrophilicity index (ω) for monomers and complexes in the gas and polar solvent phases were calculated. The results show that the conductivity and reactivity of BNNT increase by doping Al atoms instead of B atoms. Also, the interaction of NA and TNA molecules with BN and BAl3N nanotubes results in significant changes in the electronic properties of nanotubes. Based on the natural bond orbital (NBO) analysis, in all complexes charge transfer occurs from NA and TNA molecules to nanotubes. Theory of atoms in molecules (AIM) was applied to characterize the nature of interactions in nanotubes. It is predicted that, BN and B3AlN nanotubes can be used to as sensor for detection of NA and TNA molecules. 相似文献
7.
Zakarianezhad Mohammad Makiabadi Batoul Habibi-Khorassani Sayyed Mostafa Shool Motahareh Eslamlou Masoomeh 《Research on Chemical Intermediates》2018,44(4):2653-2665
Research on Chemical Intermediates - The mechanism of the multicomponent reaction between tert-butyl isocyanide and dimethyl acetylenedicarboxylate in presence of ethanethiol and thiophenol (as... 相似文献
1