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1.
[reaction: see text] A facile and highly selective indium-mediated allylation of hydrazones utilizing BINOL ligands is described. Chiral (R)-3,3'-bistrifluoromethylBINOL afforded homoallylic amines in up to 97% ee with stoichiometric ligand. Employing only 10 mol % ligand afforded selectivity of up to 92% ee. 相似文献
2.
Subhasis Chakrabarti Ashim K. Maity T. N. Misra 《Journal of polymer science. Part A, Polymer chemistry》1992,30(8):1625-1631
Raman spectroscopy has been used to study solid-state photopolymerization reactions in dimethyl ester of α,α′-dicyano-p-phenylenediacrylic acid (p-CPAMe) and diethyl ester of p-phenylenediacrylic acid (p-PDAEt). The reactants and products were characterized by infrared and Raman spectroscopy. Excitation and emission spectra suggest that in p-CPAMe exciton–phonon coupling is strong, but in the other monomer it is very weak. Raman phonon spectroscopic study reveal that in both the samples the reaction mechanism is homogeneous in the initial stages. However, in the later stages the reaction becomes heterogeneous in p-PDAEt. In p-CPAMe the lattice becomes disordered with the progress of polymerization and finally becomes amorphous whereas in p-PDAEt the lattice remains highly ordered. © 1992 John Wiley & Sons, Inc. 相似文献
3.
2,8-Dimethyltricyclo[6.2.2.01,6]dodeca-2,5-diene-4,9-dione (
), 2,9-dimethyltricyclo [6.3.1.01,6]dodeca-2,5-diene-4,10-dione (
) and 2-methyltricyclo[6.3.1.01,6]dodeca-2,5-diene-4,10-dione (
) have been synthesised for entry into the ring systems of a few tetracyclic diterpenes. 相似文献
4.
5.
Zinc ion (Zn2+) is an important and a most useful biological trace nutrient responsible for the activity of several enzymes. Zn2+ concentrations in the environment as well as in the human body increase beyond permissible limits as a consequence of its mining and widespread industrial applications. Such excess Zn2+ concentrations are toxic to humans and many aquatic organisms. The magnetic inertness and spin paired electronic configuration of Zn2+ makes it hard to detect by common analytical techniques. Therefore, fluorometric detection using chemosensor is the most effective tool for the environmental and biological detection of Zn2+. We have developed a novel pyridine-constrained bis(triazole-linked hydroxyquinoline) ligand as a reversible fluorescent chemosensor for Zn2+. The symmetrical ligand is highly selective for Zn2+ and fluoresces brightly upon complexation compared with other metal ions based on chelation-enhanced fluorescence mechanism. Interestingly, free ligand can be regenerated by treating the ligand–Zn2+ complex with aqueous ammonia. 相似文献
6.
Shyamaprosad Goswami Abhishek Manna Sima Paul Avijit K. Das Prasanta K. Nandi Anup Kumar Maity Partha Saha 《Tetrahedron letters》2014
5(Benzothiazol-2-yl)-4-hydroxyisophthalaldehyde (BHI), an intense ESIPT containing molecule in mixed media loses its properties due to resonance-assisted H-bond (RAHB) in absolute water. Due to resonance-assisted H-bond the o-aldehyde is more reactive than the other one. With addition of cysteine/homocysteine into this solution the o-aldehyde group gets transformed into thiazolidine/thiazine ring, respectively, and the phenolic proton becomes free enough for transfer to nitrogen of the benzothiazole ring in excited state, that is, the ESIPT of BHI is turned on. Thus we can detect cysteine/homocysteine in water as well as in live cells. 相似文献
7.
8.
9.
Arindam Maity Debanjana ChakrabortyAbhijit Hazra Yogesh P. BharitkarSandip Kundu Prakas R. MaulikNirup B. Mondal 《Tetrahedron letters》2014
An inexpensive one-pot green methodology has been developed for the synthesis of thiazolo[2,3-a]isoquinolin-4-ium derivatives by the reaction of different derivatives of isoquinoline and 2-bromoacetophenone/bromoacetonitrile with benzoyl isothiocyanate in aqueous micellar medium. 相似文献
10.
Endophytes, being the co-evolution partners of green host plants, are factories of pharmaceutically valuable novel natural products. Cochliobolus sp. APS1, an endophyte of Andrographis paniculata (Green Chiretta), produces a plethora of natural bioactive compounds and the multipotent alkaloid Aziridine, 1-(2-aminoethyl)-, is the prime one among them. The isolate exhibited antibacterial, anti-biofilm, and antilarval potency. The MIC and MBC values of the ethyl-acetate culture extract ranged from 15.62 to 250 µg/mL against ten pathogenic microorganisms (including MRSA and VRSA). Killing kinetics data along with the leakage of macromolecules into the extracellular environment supports the cidal activity of the antibacterial principles. The broad spectrum antibacterial activity of Aziridine, 1-(2-aminoethyl)-, was optimized by a one-variable-at-a-time system coupled with response surface methodology, which led to a 45% enhancement of the antibacterial activity. The maximum response (22.81 ± 0.16 mm of zone of inhibition against MRSA) was marked in 250 mL Erlenmeyer flask containing 90 mL potato dextrose broth supplemented with (g%/L) glucose, 9.7; urea concentration, 0.74; with medium pH 6.48; after 8.76 days of incubation at 26 °C. APS1 strongly inhibited biofilm formation in the tested pathogenic microorganisms and acts as a larvicidal agent against the Dengue-vector Aedes aegypti. This is probably the first report of Aziridine, 1-(2-aminoethyl)-, from any endophytic source. Cochliobolus sp. APS1 possesses industrial importance for the production of bioactive alkaloids. 相似文献