Preparation of a dual-functionalized fumed silica nanoparticle catalysis for synthesis of azaluorenone derivatives

Research on Chemical Intermediates - A dual-functional silica-based catalyst was prepared by treating fumed silica with amino-containing silane then 1,4-butane sultone. The presence of functional...     

Sur la séparation des terres rares XIII. Systèmes de solubilité comprenant des chlorures de terres cériques [1]

In aqueous solution, the chlorides of lanthanum, cerium and praseodymium cristallize as heptahydrates, those of the other rare earth elements as hexahydrates. Therefore, a miscibility gap exists in the solid phases in all systems comprising the two types of chlorides. Five ternary systems and a quaternary one with this behaviour have been studied.     

Some aspects of gravitational quantum mechanics

String theory, quantum geometry, loop quantum gravity and black hole physics all indicate the existence of a minimal observable length on the order of Planck length. This feature leads to a modification of Heisenberg uncertainty principle. Such a modified Heisenberg uncertainty principle is referred as gravitational uncertainty principle(GUP) in literatures. This proposal has some novel implications on various domains of theoretical physics. Here, we study some consequences of GUP in the spirit of Quantum mechanics. We consider two problem: a particle in an one-dimensional box and free particle wave function. In each case we will solve corresponding perturbational equations and compare the results with ordinary solutions.     

The experimental/numerical investigation of variations in strip speed,water shower pattern and water temperature on high-temperature strip cooling rate in hot strip mill

Journal of Thermal Analysis and Calorimetry - Hot-rolled strips are cooled on the run-out table to achieve the customer-required mechanical properties. Cooling reduces the oxidation, which can...     

Antiinfective properties of ursolic acid-loaded chitosan nanoparticles against Staphylococcus aureus

The present study aimed to synthesize ursolic acid-loaded chitosan nanoparticles (UA-Ch-NPs) as an antiinfective agent against 21 Staphylococcus aureus isolates. The UA-Ch-NPs were synthesized by a simple method and then characterized by TEM, FTIR, DLS-zeta potential, and XRD analyses. According to the characterization results, highly dispersed spherical nanoparticles with a mean diameter of 258 nm and a zeta potential of + 40.1 mV were developed. The antibacterial properties of UA-Ch-NPs were investigated and their inhibitory effect on biofilm formation was demonstrated by AFM. Finally, the expression levels of icaA and icaD were measured using real-time PCR. Results indicated that the minimum inhibitory concentration (MIC) of UA and UA-Ch-NPs against S. aureus was 64 and 32 µg/mL, respectively. The treatment of bacterial cells with UA-Ch-NPs significantly decreased the expression of icaA and icaD genes which are engaged in biofilm formation. Our results indicated that UA-Ch-NPs could be a promising material for antibacterial and antibiofilm applications.     

Baryogenesis in f(R,T) Gravity

We study gravitational baryogenesis in the context of f(R, T) gravity where the gravitational Lagrangian is given by a generic function of the Ricci scalar R and the trace of the stress-energy tensor T. We explore how this type of modified gravity is capable to shed light on the issue of baryon asymmetry in a successful manner. We consider various forms of baryogenesis interaction and discuss the effect of these interaction terms on the baryon to entropy ratio in this setup. We show that baryon asymmetry during the radiation era of the expanding universe can be non-zero in this framework. Then, we calculate the baryon to entropy ratio for some specific f(R, T) models and by using the observational data, we give some constraints on the parameter spaces of these models.     

Non-singular model universe from a perfect fluid scalar-metric cosmology

To seek for a singularity free model universe from a perfect fluid scalar-metric cosmology, we work in the “Emergent Cosmology” (EC) paradigm which is a non-singular alternative for cosmological inflation. By using two methods including Linear Stability Theory and Effective Potential Formalism, we perform a classical analysis on the possible static solutions (that are called usually as Einstein Static Universes (ESU)in literature) in order to study EC paradigm in a FRW background. Our model contains a kinetic term of the scalar field minimally coupled to the background geometry without a potential term. The matter content of the model consists of a perfect fluid plus a cosmological constant \(\Lambda \) as a separate source. In the framework of a local dynamical system analysis, we show that in the absence or presence of \(\Lambda \), depending on some adopted values for the free parameters of the underlying cosmological model with flat and non-flat spatial geometries, one gets some static solutions which are viable under classical linear perturbations. By extending our study to a global dynamical system analysis, we show that in the presence of \(\Lambda \) with non-flat spatial geometries there is a future global de Sitter attractor in this model. Following the second method, we derive a new static solution that represents a stable ESU but this time without dependence on the free parameters of the cosmological model at hand. As a whole, our analysis suggests the possibility of graceful realization of a non-singular EC paradigm (i.e. leaving the initial static phase and entering the inflation period as the universe is evolving) through either preserving or violation of the strong energy condition.     

A New Distributional Approach to Signature Change

Colombeau's generalized functions are used to adapt the distributional approach to singular hypersurfaces in general relativity with signature change. Equations governing the dynamics of a singular hypersurface are derived and a specific non-vanishing form for the energy-momentum tensor of the singular hypersurface is obtained. It is shown that matching in the case of de Sitter space in the Lorentzian sector is possible along the boundary with minimum radius but leads to the vanishing of the energy-momentum tensor of the singular hypersurface.     

Engineered mesoporous ionic‐modified γ‐Fe2O3@hydroxyapatite decorated with palladium nanoparticles and its catalytic properties in water

A new mesoporous organic–inorganic nanocomposite was formulated and then used as stabilizer and support for the preparation of palladium nanoparticles (Pd NPs). The properties and structure of Pd NPs immobilized on prepared 1,4‐diazabicyclo[2.2.2]octane (DABCO) chemically tagged on mesoporous γ‐Fe₂O₃@hydroxyapatite (ionic modified (IM)‐MHA) were investigated using various techniques. The synergistic effects of the combined properties of MHA, DABCO and Pd NPs, and catalytic activity of γ‐Fe₂O₃@hydroxyapatite‐DABCO‐Pd (IM‐MHA‐Pd) were investigated for the Heck cross‐coupling reaction in aqueous media. The appropriate surface area and pore size of mesoporous IM‐MHA nanocomposite can provide a favourable hard template for immobilization of Pd NPs. The loading level of Pd in the nanocatalyst was 0.51 mmol g^?1. DABCO bonded to the MHA surface acts as a Pd NP stabilizer and can also lead to colloidal stability of the nanocomposite in aqueous solution. The results reveal that IM‐MHA‐Pd is highly efficient for coupling reactions of a wide range of aryl halides with olefins under green conditions. The superparamagnetic nature of the nanocomposite means that the catalyst to be easily separated from solution through magnetic decantation, and the catalytic activity of the recycled IM‐MHA‐Pd showed almost no appreciable loss even after six consecutive runs.