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WILLIAM H. MILLER 《Molecular physics》2013,111(4):397-400
It is shown that the Herman—Kluk (or coherent state) initial value representation (IVR) of the semiclassical propagator (time evolution operator) can be obtained by application of a modified Filinov filtering procedure to the standard Van Vleck (coordinate space) expression for the propagator. This further illustrates the effective equivalence, semiclassically, of these various IVRs. 相似文献
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学习体验是学生对学习内容、过程、方法、意义的自我感受和评估,对学生学习志趣、学习素养提升有积极正向作用。以钠及其化合物复习为例,将各类别物质间转化关系的构建、物质制备原理和条件的优选作为学习体验对象,依据学习体验的内在发展历程设计学习任务及活动,引导学生亲身体验学科认知方式、学科思维方法、学科应用价值,评价体验结果,激励学生自主学习发生。 相似文献
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Charge transport properties of polyimide films implanted with 80 keV Co ions at two different fluences (series I: 1.25 × 10^17 ions/cm^2, series Ⅱ: 1.75 × 10^17 ions/cm^2) are studied in detail. For series I, the temperature dependence of surface resistivity fits Mott's equation very well. It is on the insulating side of the insulator-metal transition (IMT). However, for series Ⅱ, the temperature dependence of surface resistivity is not in agreement with Mott's equation. It is on the metallic side of lMT. The magnetotransport properties of these two series are also studied. No significant magnetoresistive effect is observed for series I at both 5 K and 300 K. For series Ⅱ, an obvious magnetoresistive effect is observed at 5 K, while there is no magnetoresistive effect at 300 K. Rutherford backscattering spectrometry (RBS) is applied to confirm the actual fluence for these two series. 相似文献
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Accurate disturbance models are necessary to predict the effects of vibrations on the performance of precision space-based telescopes, such as the Space Interferometry Mission (SIM). There are many possible disturbance sources on such spacecraft, but mechanical jitter from the reaction wheel assembly (RWA) is anticipated to be the largest. A method has been developed and implemented in the form of a MATLAB toolbox to extract parameters for an empirical disturbance model from RWA micro-vibration data. The disturbance model is based on one that was used to predict the vibration behaviour of the Hubble Space Telescope (HST) wheels and assumes that RWA disturbances consist of discrete harmonics of the wheel speed with amplitudes proportional to the wheel speed squared. The MATLAB toolbox allows the extension of this empirical disturbance model for application to any reaction wheel given steady state vibration data. The toolbox functions are useful for analyzing RWA vibration data, and the model provides a good estimate of the disturbances over most wheel speeds. However, it is shown that the disturbances are under-predicted by a model of this form over some wheel speed ranges. The poor correlation is due to the fact that the empirical model does not account for disturbance amplifications caused by interactions between the harmonics and the structural modes of the wheel. Experimental data from an ITHACO Space Systems E-type reaction wheel are used to illustrate the model development and validation process. 相似文献
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建立了超高效液相色谱-电喷雾离子源-串联三重四极杆质谱(UPLC-ESI MS/MS)分析饮用水中高氯酸盐的方法.以300Extend-C18为分析柱,10%甲醇水溶液为流动相,ESI MS/MS串联质谱为检测器,以多重反应监测(MRM)模式监测高氯酸盐m/z 99.5→82.9离子对.方法的线性范围为0.2 ~10 μg/L,相关系数为r2=0.999 9,方法检出限为0.15 μg/L,平均加标回收率为82%,相对标准偏差为4.4%.应用UPLC-ESI MS/MS法测定北京市部分城区饮用水中的高氯酸盐,其中5个水样中检出ClO-4,质量浓度为0.040 ~0.262 μg/L,但在安全阈值范围内,不会对居民健康构成威胁. 相似文献
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计算表明,与场的相干态类似的原子相干态,具有不同于场的相干态的压缩行为;进一步证明:直接类比于(?)(ξ)不能得到“原子压缩算符”. 相似文献
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