SPECTROSCOPIC STUDIES OF CHLOROPHYLL a AGGREGATES FORMED BY AQUEOUS DIMETHYL SULFOXIDE

Characteristic chlorophyll (Chl) a aggregates formed in aqueous dimethyl sulfoxide (DMSO) were investigated spectroscopically. Four chlorophyll forms were found with increasing DMSO concentration; they are called A-672, A-683, A-695 and A-665 according to the wavelengths of their absorption maxima. Transformation occurred only in this order. Reverse transformation could not be realized. A-683 and A-695 were apparently formed by the interaction of Chl a with DMSO in the linear dimer and linear polymer arrangements, respectively. Coordination of the Mg atom with a DMSO O atom and interaction between the S atom of one DMSO molecule and the O atom of an other DMSO molecule should lead to formation of a sandwich-type complex of partially overlapping chlorophyll macrocycles (Chl a-DMSO)_n. A-672 and A-665 were assigned to Chl a micelles and to dissolved monomeric Chl a in DMSO, respectively. Fluorescence spectra showed that the A-683 was highly fluorescent, while the A-695 was less fluorescent. Energy migration within the A-695 form to a trap with a low fluorescence yield might be responsible for this difference in the emission intensity.     

用于波导阵列——光纤阵列自动对接的多目标演化算法的研究

开发设计了一种新的列阵自动对接方法,该方法将多目标演化法导入光纤—光波导列阵—光纤列阵的自动对接,并行操作次数较常规遗传法大幅减少.数值仿真表明,对于模场非对称因子为0.4%的单模波导列阵与光纤列阵的双芯对接,能实现0.04 dB的平均端面耦合损耗.用于1×8波导分支耦合器与通道间距误差在0.35 μm以内的光纤列阵对接,自动耦合仿真达到了小于0.1 dB的平均端面耦合损耗,最大值与最小值的差小于0.06 dB.     

偏振脱敏高隔离度高分子波导分波器设计

提出了一种新的高分子波导分波器结构,用以改善波长串扰以及偏振变动、波长带宽等引起的劣化影响.主要技术特征是采用两支参量不同的波导来构成非对称定向耦合器.报告了用非对称定向耦合器构成的马赫-泽德尔干涉型波导分波器的结构特点、基本工作原理和光学特性,详细讨论了器件的设计原理和器件性能优化的处理方法.采用三维波束传播法做了仿真验证,结果表明,该器件在1 550±5 nm和1 310±5 nm的波长带域上、对两个正交偏振态均实现了串扰小于－40 dB的高隔离度分波特性.     

基于离子交换条波导的生物溶液浓度传感研究

提出并实施了一种实验推定离子交换单模条波导折射率分布的新方法,给出扩散系数可用常量等效的离子交换条件,导出了条波导离子交换制备过程的两维扩散方程的一般解,拟合推定了离子交换条波导的折射率分布.多波长测试的折射率色散通过引入玻璃色散关系解决,样品测试中表征导模吸收损耗的传播常量虚部由KK变换确定.在此基础上,试制了光纤-条波导-光纤一体化传感器结构,验证实测了多种不同浓度的葡萄糖溶液,最低检测限为0.1 μM,实现了低浓度微量测试,验证了条波导传感机制的有效性.     

支化聚甲基苯基硅烷薄膜波导的光折变效应研究

掺入0.33%苯基三氯硅烷制备了分子量为51 874的支化聚甲基苯基硅烷,由此改善了聚甲基苯基硅烷薄膜波导的成膜质量.报告了相应的成膜技术、膜厚控制技术、热处理技术和热氧化现象.采用紫外曝光手段研究了支化聚甲基苯基硅烷薄膜的光漂白效应,定性测试了曝光剂量与反应生成硅氧烷的正比关系.实验归纳了支化聚甲基苯基硅烷薄膜的光折变规律,获得了控制薄膜厚度和折射率的定量条件.     

非晶态As_2S_8半导体薄膜的光激励现象的研究及应用

实验研究了非晶态As2S8半导体薄膜在紫外汞灯和He_Cd激光照射下的光诱导现象,证实了光照射后的As2S8薄膜的折射率增大,体积缩小,可见光吸收谱的吸收带蓝移。在此基础上,应用光折变效应试制了As2S8条波导,观测到As2S8条波导的光阻断效应,实现了光_光效应的开关功能。