全文获取类型
收费全文 | 522篇 |
免费 | 4篇 |
国内免费 | 1篇 |
专业分类
化学 | 367篇 |
晶体学 | 69篇 |
力学 | 4篇 |
数学 | 33篇 |
物理学 | 54篇 |
出版年
2023年 | 1篇 |
2022年 | 13篇 |
2021年 | 19篇 |
2020年 | 13篇 |
2019年 | 16篇 |
2018年 | 13篇 |
2017年 | 10篇 |
2016年 | 16篇 |
2015年 | 6篇 |
2014年 | 8篇 |
2013年 | 31篇 |
2012年 | 22篇 |
2011年 | 28篇 |
2010年 | 31篇 |
2009年 | 26篇 |
2008年 | 38篇 |
2007年 | 36篇 |
2006年 | 30篇 |
2005年 | 26篇 |
2004年 | 23篇 |
2003年 | 18篇 |
2002年 | 24篇 |
2001年 | 10篇 |
2000年 | 11篇 |
1999年 | 8篇 |
1998年 | 4篇 |
1997年 | 6篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 3篇 |
1972年 | 3篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有527条查询结果,搜索用时 31 毫秒
1.
2.
E. L. Belokoneva A. G. Ivanova S. Yu. Stefanovich O. V. Dimitrova V. S. Kurazhkovskaya 《Crystallography Reports》2004,49(4):603-613
Crystals of new rare earth borates of the composition Ln[B6O9 (OH)3] (Ln = Sm-Lu), sp. gr. R3c are synthesized under hydrothermal conditions. Their crystal structures are determined on single crystals with Ln = Ho, Gd without preliminary determination of their chemical formulas. The polar anionic framework of the crystals consists
of BO3 triangles and BO4 tetrahedra and has wide channels along the threefold axis of the structure, which are similar to the channels along the a, b, and c axes in cubic Li4[B7O12]Cl boracite with Li conductivity. Rare earth atoms are arranged in the structure over the cubic F pseudolattice, whereas
the analogous positions in Li boracites are filled with Cl anions. The squared optical nonlinearity of the new crystals is
comparable with the nonlinearity of quartz, whereas the electrical conductivity in borates at 300°C exceeds 10−6 S/cm.
__________
Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 681–691.
Original Russian Text Copyright ? 2004 by Belokoneva, Ivanova, Stefanovich, Dimitrova, Kurazhkovskaya. 相似文献
3.
Tatiana B. Mikenas Vladimir A. Zakharov Lyudmila G. Echevskaya Mikhail A. Matsko 《Journal of polymer science. Part A, Polymer chemistry》2007,45(22):5057-5066
The effects of polymerization temperature, polymerization time, ethylene and hydrogen concentration, and effect of comonomers (hexene‐1, propylene) on the activity of supported catalyst of composition LFeCl2/MgCl2‐Al(i‐Bu)3 (L = 2,6‐bis[1‐(2,6‐dimethylphenylimino)ethyl] pyridyl) and polymer characteristics (molecular weight (MW), molecular‐weight distribution (MWD), molecular structure) have been studied. Effective activation energy of ethylene polymerization over LFeCl2/MgCl2‐Al(i‐Bu)3 has a value typical of supported Ziegler–Natta catalysts (11.9 kcal/mol). The polymerization reaction is of the first order with respect to monomer at the ethylene concentration >0.2 mol/L. Addition of small amounts of hydrogen (9–17%) significantly increases the activity; however, further increase in hydrogen concentration decreases the activity. The IRS and DSC analysis of PE indicates that catalyst LFeCl2/MgCl2‐Al(i‐Bu)3 has a very low copolymerizing ability toward propylene and hexene‐1. MW and MWD of PE produced over these catalysts depend on the polymerization time, ethylene and hexene‐1 concentration. The activation effect of hydrogen and other kinetic features of ethylene polymerization over supported catalysts based on the Fe (II) complexes are discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5057–5066, 2007 相似文献
4.
Lyudmila Kondakova Victor Yanishpolskii Valentin Tertykh Tat'yana Buglova 《Analytical sciences》2007,23(1):97-101
Galactose oxidase from Fusarium graminearum IMV-1060 adsorbed on, and covalently bound to, silica carriers has been used for analytical determinations of D-galactose and galactose-containing sugars. Using a flowing oxygen electrode of the Clark-type, sensor system for enzymatic analysis of water solutions of galactose-containing carbohydrates was made. Measurements were taken both in the pulse and continuous modes of a substrate flowing through a column with an immobilized biocatalyst. The linear measurement ranges for galactose-containing carbohydrates concentrations were determined. 相似文献
5.
Dimitrov S Dimitrova N Parkerton T Comber M Bonnell M Mekenyan O 《SAR and QSAR in environmental research》2005,16(6):531-554
The base-line modeling concept presented in this work is based on the assumption of a maximum bioconcentration factor (BCF) with mitigating factors that reduce the BCF. The maximum bioconcentration potential was described by the multi-compartment partitioning model for passive diffusion. The significance of different mitigating factors associated either with interactions with an organism or bioavailability were investigated. The most important mitigating factor was found to be metabolism. Accordingly, a simulator for fish liver was used in the model, which has been trained to reproduce fish metabolism based on related mammalian metabolic pathways. Other significant mitigating factors, depending on the chemical structure, e.g. molecular size and ionization were also taken into account in the model. The results (r(2)=0.84) obtained for a training set of 511 chemicals demonstrate the usefulness of the BCF base line concept. The predictability of the model was evaluated on the basis of 176 chemicals not used in the model building. The correctness of predictions (abs(logBSF(Obs)-logBCF(Calc))=0.75)) for 59 chemicals included within the model applicability domain was 80%. 相似文献
6.
Lyudmila V. Chernykh Jitka Eysseltova Mikhail Y. Skripkin 《Monatshefte für Chemie / Chemical Monthly》2003,134(5):751-761
Summary. Solubility isotherms in the CuBr2−MBr−H2O (M
+ = Li+, Na+, Cs+) systems at 298.15 K were measured. The results together with other available literature data for copper chloride and bromide
systems were treated by hydration analysis, and comparative discussion of ionic processes taking place in the respective saturated
solutions was performed.
Corresponding author. E-mail: jitka@prfdec.natur.cuni.cz
Received August 6, 2002; accepted (revised) November 29, 2002
Published online April 3, 2003 相似文献
7.
Z. Popova R. Dimitrova Chr Dimitrova G. Wendt 《Reaction Kinetics and Catalysis Letters》1989,39(1):27-32
Temperature programmed reduction (TPR) has been used to study the redox behavior of Ni(II) ions in nickel sodium mordenite (NiNaM) and decationated nickel mordenite (NiHM). The TPR profiles suggest that Ni(II) ions occupy nonequivalent sites with different cooridination states in the mordenite. The reducibility of Ni(II) depends strongly on the zeolite acidity.
() NiII NiNaM NiHM. . .相似文献
8.
Viktor A. Sipachev Lyudmila N. Reshetova Yurii S. Nekrasov Svetlana Yu. Sil'vestrova 《Journal of mass spectrometry : JMS》1980,15(4):192-194
The electron impact mass spectrum of Zn4O(CH3CO2)6 isostructural to Be4O(CH3CO2)6 studied earlier is reported. The principal fragmentation paths of both compounds involve the elimination of M(CH3CO2)2 where M is Zn, Be, or (CH3CO)2O. Further fragmentations proceed by the losses of CH2CO and H2O. The spectrum of Zn4O(CH3CO2)6 contains intense doubly charged ions. The results obtained are interpreted in terms of stereochemical considerations. 相似文献
9.
10.
Lyudmila V Saloutina Aleksandr Ya Zapevalov Konstantin A Lyssenko Victor I Saloutin 《Journal of fluorine chemistry》2003,120(1):41-47
The reaction of oxides of internal trans- and cis-perfluoroolefins with (1S, 4S)- or racemic camphor thiosemicarbazone leads to the formation of trans- and cis-isomers of (1S, 4S)- or racemic camphor 5′-fluoro-4′-hydroxy-4′,5′-di(perfluoroalkyl)-1′,3′-thiazolinyl-2′-hydrazones, respectively. Unsymmetrical dodecafluoro-2,3-epoxyhexane yields a mixture of regioisomeric hydrazones. The molecular structure of the trans-isomer of (1S, 4S)-camphor 5′-fluoro-4′-hydroxy-4′,5′-bis(trifluoromethyl)-1′,3′-thiazolinyl-2′-hydrazone has been established by X-ray crystallography. The quite rare example of cocrystallization of two diastereomers of the latter in homochiral crystal (sp. group P21) has been revealed. 相似文献