全文获取类型
收费全文 | 1844篇 |
免费 | 65篇 |
国内免费 | 7篇 |
专业分类
化学 | 1122篇 |
晶体学 | 12篇 |
力学 | 78篇 |
数学 | 365篇 |
物理学 | 339篇 |
出版年
2023年 | 17篇 |
2022年 | 55篇 |
2021年 | 74篇 |
2020年 | 71篇 |
2019年 | 73篇 |
2018年 | 41篇 |
2017年 | 55篇 |
2016年 | 85篇 |
2015年 | 61篇 |
2014年 | 86篇 |
2013年 | 117篇 |
2012年 | 130篇 |
2011年 | 137篇 |
2010年 | 64篇 |
2009年 | 67篇 |
2008年 | 80篇 |
2007年 | 69篇 |
2006年 | 64篇 |
2005年 | 60篇 |
2004年 | 51篇 |
2003年 | 38篇 |
2002年 | 47篇 |
2001年 | 26篇 |
2000年 | 25篇 |
1999年 | 15篇 |
1998年 | 19篇 |
1997年 | 8篇 |
1996年 | 19篇 |
1995年 | 7篇 |
1994年 | 10篇 |
1993年 | 13篇 |
1992年 | 12篇 |
1991年 | 9篇 |
1990年 | 10篇 |
1989年 | 9篇 |
1988年 | 11篇 |
1987年 | 12篇 |
1986年 | 9篇 |
1985年 | 13篇 |
1984年 | 19篇 |
1982年 | 23篇 |
1981年 | 17篇 |
1980年 | 19篇 |
1979年 | 17篇 |
1978年 | 5篇 |
1977年 | 11篇 |
1976年 | 11篇 |
1975年 | 7篇 |
1974年 | 5篇 |
1968年 | 3篇 |
排序方式: 共有1916条查询结果,搜索用时 15 毫秒
1.
2.
3.
Andrea Mühlbauer Stephan Seip Alexander Nowak VanSung Tran 《Helvetica chimica acta》2003,86(6):2065-2072
Chemical investigation of the roots of the Vietnamese plant Tacca paxiana resulted in the isolation of five new steroidal compounds, taccalonolide R ( 6 ), S ( 7 ), T ( 8 ), U ( 9 ), and V ( 10 ). Their structures were established on the basis of NMR and mass‐spectral data. In addition, the five known taccalonolides A ( 1 ), B ( 2 ), E ( 3 ), K ( 4 ), and N ( 5 ) were also isolated and identified. 相似文献
4.
Intramolecular electron spin exchange as a function of temperature and solvent viscosity and polarity has been studied by
X-band electron paramagnetic resonance (EPR) spectroscopy in two rigid nitroxide biradicals existing in one spatial conformation
only. Temperature variations of the isotropic hyperfine splitting constanta and exchange integral value |J/a| were measured from EPR spectra and subsequently analyzed. The interaction of polar solvent molecules with >N-O fragments
of nitroxide groups led to a slight decrease of the |J/a| value with the increase of temperatureT. In contrast, the interaction of polar solvent molecules with functional groups inside the bridge resulted in a noticeable
increase of |J/a| vs.T. In the last case, a coverse relationship between the values of |J/a| and the hyperfine splitting constanta has been observed for solvents with different polarity. 相似文献
5.
The aim of this paper is to present two different approachs in order to obtain an existence result to the so-called quadrature
surface free boundary problem. The first one requires the shape derivative calculus while the second one depends strongly
on the compatibility condition of the Neumann problem. A necessary and sufficient condition of existences is given in the
radial case. 相似文献
6.
This paper concerns methods by which a trusted authority can distribute keys and/or broadcast a message over a network, so that each member of a privileged subset of users can compute a specified key or decrypt the broadcast message. Moreover, this is done in such a way that no coalition is able to recover any information on a key or broadcast message they are not supposed to know. The problems are studied using the tools of information theory, so the security provided is unconditional (i.e., not based on any computational assumption).In a recent paper st95a, Stinson described a method of constructing key predistribution schemes by combining Mitchell-Piper key distribution patterns with resilient functions; and also presented a construction method for broadcast encryption schemes that combines Fiat-Naor key predistribution schemes with ideal secret sharing schemes. In this paper, we further pursue these two themes, providing several nice applications of these techniques by using combinatorial structures such as orthogonal arrays, perpendicular arrays, Steiner systems and universal hash families. 相似文献
7.
Tran Quang Minh Léon Christiaens Pierre Grandclaudon Alain Lablache-Combier 《Tetrahedron》1977,33(17):2225-2229
Photoirradiated in presence of acetophenone, benzo[b]selenophene and its 3-methyl derivative add to dimethyl acetylenedicarboxylate. In each ease, the primary reaction product is unstable and has not been isolated. Photoexeited in its triplet state (the energy of which is in the neighbourhood of 69 ) benzo[b]selenophene and its 2- and 3-methyl, 2,3 dimethyl, 3 acetoxy and 2-methyl-3-acetoxy derivatives add to 1,2 dichloroethylene leading to cyclobutanes. Neither cyclo-addition occurs in absence of photosensitiser. Single-crystal X-ray analysis gave the structures of the two adducts of 3-acetoxybenzo[b]selenophene with trans-1,2-dichloroethylene. In both compounds the chlorine atoms are trans. 相似文献
8.
Li YS Xiao Y Wright PB Tran T 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(7):1675-1681
3-(Triethoxysilyl)propionitrile (TESPN) sol-gel has been prepared under different conditions. It was employed for coating the surfaces of quartz and aluminum. Infrared (IR) and Raman spectra of TESPN and TESPN sol-gels have been recorded in the study of the sol-gel process. Transmission and reflection absorption IR (RAIR) spectra of TESPN sol-gel coated quartz and aluminum have also been collected for better understanding the film formation on the substrate surfaces. Spectra collected at different temperatures indicated that the silane film on quartz decomposes at 700 degrees C. Results from thermal gravimetric analysis (TGA) supported this result. Based on the group frequencies and the spectral behavior in different states, some vibrational modes were assigned to the observed bands. The anticorrosion behavior of the sol-gel coated aluminum in comparison with the uncoated metal was evaluated by measuring the potentiodynamic polarization and electrochemical impedance spectra (EIS). 相似文献
9.
10.
Heredia KL Bontempo D Ly T Byers JT Halstenberg S Maynard HD 《Journal of the American Chemical Society》2005,127(48):16955-16960
Protein-polymer conjugates are widely used in biotechnology and medicine, and new methods to prepare the bioconjugates would be advantageous for these applications. In this report, we demonstrate that bioactive "smart" polymer conjugates can be synthesized by polymerizing from defined initiation sites on proteins, thus preparing the polymer conjugates in situ. In particular, free cysteines, Cys-34 of bovine serum albumin (BSA) and Cys-131 of T4 lysozyme V131C, were modified with initiators for atom transfer radical polymerization (ATRP) either through a reversible disulfide linkage or irreversible bond by reaction with pyridyl disulfide- and maleimide-functionalized initiators, respectively. Initiator conjugation was verified by electrospray-ionization mass spectroscopy (ESI-MS), and the location of the modification was confirmed by muLC-MSMS (tandem mass spectrometry) analysis of the trypsin-digested protein macroinitiators. Polymerization of N-isopropylacrylamide (NIPAAm) from the protein macroinitiators resulted in thermosensitive BSA-polyNIPAAm and lysozyme-polyNIPAAm in greater than 65% yield. The resultant conjugates were characterized by gel electrophoresis and size exclusion chromatography (SEC) and easily purified by preparative SEC. The identity of polymer isolated from the BSA conjugate was confirmed by (1)H NMR, and the polydispersity index was determined by gel permeation chromatography (GPC) to be as low as 1.34. Lytic activities of the lysozyme conjugates were determined by two standard assays and compared to that of the unmodified enzyme prior to polymerization; no statistical differences in bioactivity were observed. 相似文献