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1.
T. Engel M. Würtz S. Borneis St. Becker I. Klaft A. Kohl T. Kühl F. Laeri D. Marx K. Meier R. Neumann F. Schmitt P. Seelig L. Völker 《Hyperfine Interactions》1997,108(1-3):251-258
Laser spectroscopy at storage rings often suffers from a limited resolution due to Doppler-broadened resonances. Broadening
is caused by the velocity spread of the ions stored in the beam. In the following, the present status of our work on laser
systems specialized on the specific needs of laser spectroscopy at storage rings is reported.
Two pulsed laser systems were developed. One is a dye laser whose spectral bandwidth can be switched by inserting different
Littrow-prisms into the resonator. An increase in bandwidth up to a factor of 45 was achieved. This laser was used for fast
qualitative scans and high resolution measurements. The other laser system is a Nd : YAG laser pumped optical parametric oscillator.
It is a tunable laser system covering the spectral range from 410 to 4000 nm. Furthermore, a continuous wave laser with a
frequency shifted feedback cavity is described. It shows broadband emission with an adjustable bandwidth of up to 4.5 GHz.
This laser can be advantageous for laser cooling of ion beams.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
2.
The magnetic properties of a TbNi2Si2 single crystal have been investigated experimentally by specific heat, anisotropy of the susceptibility and magnetization, and inelastic neutron scattering, leading to the determination of its fundamental coupling parameters. The lowest crystalline electric field states are two singlets close to each other, that explains the different magnetic structures evidenced in TbNi2Si2: an amplitude modulated structure, close to T N , a simple antiferromagnetic one at low temperature and an antiphase one when an external magnetic field is applied along the c direction. 相似文献
3.
The gedanken experiment of the clock paradox is solved exactly using the general relativistic equations for a static homogeneous gravitational
field. We demonstrate that the general and special relativistic clock paradox solutions are identical and in particular that
they are identical for finite acceleration. Practical expressions are obtained for proper time and coordinate time by using the destination distance as
the key observable parameter. This solution provides a formal demonstration of the identity between the special and general
relativistic clock paradox with finite acceleration and where proper time is assumed to be the same in both formalisms. By
solving the equations of motion for a freely falling clock in a static homogeneous field elapsed times are calculated for
realistic journeys to the stars.
1 Both authors contributed equally to this paper. 相似文献
4.
5.
The synthesis of a specific isotopomer, C6D4H(ortho)-H(ortho)D4C6 of biphenyl is reported. The intramolecular dipolar coupling of the protons leads to a well-resolved single-crystal proton
nuclear magnetic resonance (NMR) spectrum and allows one to study the dynamics of the phenyl rings in a unique way. At room
temperature and above, the most conspicuous dynamical mode consists of 180° ring flips. The present data together with previous
measurements of the total flip rate allow us to conclude that the rings flip almost exclusively independently of each other.
Between the incommensurate (IC) phase transition of biphenyl at 38 K andT=250 K, the prominent namical mode consists of oscillatory twists ϕ(t) of the two rings. The data allow us to infer the mean square, (φ2), of these twists. (φ2) is found to grow linearly withT for 50<T<200 K. From the slope of (φ2) vs.T the frequency (the wave number[(v)\tilde]\tilde v) is derived. The result is[(v)\tilde] = 20\tilde v = 20 cm−1. ForT<38 K, the spectra give direct evidence of the IC phase transition and its nature (stripelike rather than quiltlike). The
temperature dependence of the magnitude of the order parameter of the IC phase is obtained. 相似文献
6.
We analyze the well-posedness of the initial value problem for the dissipative quasi-geostrophic equations in the subcritical
case. Mild solutions are obtained in several spaces with the right homogeneity to allow the existence of self-similar solutions.
While the only small self-similar solution in the strong
Lp{\cal L}^{p}
space is the null solution, infinitely many self-similar solutions do exist in weak-
Lp{\cal L}^{p}
spaces and in a recently introduced [7] space of tempered distributions. The asymptotic stability of solutions is obtained
in both spaces, and as a consequence, a criterion of self-similarity persistence at large times is obtained. 相似文献
7.
We exhibit a characteristic structure of the class of all regular graphs of degree d that stems from the spectra of their adjacency matrices. The structure has a fractal threadlike appearance. Points with coordinates given by the mean and variance of the exponentials of graph eigenvalues cluster around a line segment that we call a filar. Zooming-in reveals that this cluster splits into smaller segments (filars) labeled by the number of triangles in graphs. Further zooming-in shows that the smaller filars split into subfilars labeled by the number of quadrangles in graphs, etc. We call this fractal structure, discovered in a numerical experiment, a multifilar structure. We also provide a mathematical explanation of this phenomenon based on the Ihara-Selberg trace formula, and compute the coordinates and slopes of all filars in terms of Bessel functions of the first kind. 相似文献
8.
Audrey A S G Lonni Ieda S Scarminio Lucas M C Silva Dalva T Ferreira 《Analytical sciences》2003,19(7):1013-1017
Phytochemical investigation of the aerial parts of three Baccharis species (Asteraceae family) was performed using HPLC and chemometric methods, with the objective of distinguishing between three morphologically very similar species: Baccharis genistelloides Persoon var. trimera (Less.) DC, B. milleflora (Less.) DC and B. articulata (Lam.) Persoon. With the help of Principal Component Analysis (PCA) and variance weights, it was possible to characterize the chromatographic profiles of the alcoholic extracts of the three species. Application of Soft Independent Modeling of Class Analogy (SIMCA) and K-Nearest Neighbor (KNN) methods on a training set of 74 extracts resulted in models that correctly classified all eight samples in an independent test set. 相似文献
9.
We use the PCP-SAFT equation of state, which is of the Van der Waals type and has a sound physical basis, to predict mixture properties, such as vapor–liquid and liquid–liquid equilibria, as well as excess enthalpies. We use molecular properties, such as dipole moment, quadrupole moment, polarizability and dispersion interaction coefficients, that have been determined quantum mechanically in Part I of this publication and adjust the remaining three pure compound parameters to pure compound data. We finally present a new combination rule for the dispersion energy parameter ? that is based on the quantum mechanically determined data. The predictions based on quantum mechanically determined pure compound properties along with the new combination rule show an improved performance compared to the original PCP-SAFT combination rule. 相似文献
10.
Lucas Hernández Pedro Hernández José Vicente 《Fresenius' Journal of Analytical Chemistry》1993,345(11):712-715
Summary The determination of methyl-parathion (MPT), ortho (ONP), meta (MNP) and para nitrophenol (PNP) has been studied by differential pulse voltammetry with a carbon-paste electrode modified with 50% (w/w) of C18. A study of the influence of the pH in the preconcentration cell and the measurement cell was carried out for an electrode with 50% modifier and an accumulation time of 5 min. The voltammograms were recorded with a sweep rate of 40 mV s–1 and a pulse amplitude of 50 mV. With the optimum conditions of pH for both of the steps, various other variables were studied. The variables for each compound were optimized and the possibility of application to the determination of a mixture of the four compounds was investigated. The determination limits found for all the compounds are: 2 ng ml–1 for ONP, 5 ng ml–1 for MNP, 4.3 ng ml–1 for PNP and 7.9 ng ml–1 for MPT. The method was applied to samples of a small lake which gathers rain water and water filtered from land on which cereals are grown. 相似文献