Atomic force microscope studies of membranes: Surface pore structures of Cyclopore and Anopore membranes

Non-contact atomic force microscopy has been used to investigate the surface pore structure of Cyclopore and Anopore microfiltration membranes in air. Three Cyclopore membranes and three Anopore membranes of different pore sizes were studied. Excellent high resolution images were obtained. Analysis of the images gave quantitative information on the surface pore structure, in particular the pore size distribution. Non-contact AFM is an excellent means of obtaining such information for microfiltration membranes.     

Direct Quantification of Aspergillus niger Spore Adhesion in Liquid Using an Atomic Force Microscope

An atomic force microscope has been used to quantify directly the adhesion between single Aspergillus niger spores and freshly cleaved mica surfaces. The measurements used "spore probes" constructed by immobilizing a single spore at the apex of a tipless AFM cantilever. Adhesion was quantified from force-distance data for the retraction of the spore from the surface. Studies in NaCl solutions over a range of pH and electrolyte concentration showed that the decrease of long-range electrostatic repulsion with decreasing pH provided a contribution in increasing the overall adhesion, but the variation of such repulsion with ionic strength did not correlate with changes in the magnitude of adhesion. Specific interactions between appendages and protusions on the spore surface must play an important role in adhesion. The AFM spore probe technique provides a useful new method for evaluating the interactions of spores and surfaces. It has the potential to become a powerful asset for both fundamental studies and the assessment of new materials with low adhesion properties. Copyright 2000 Academic Press.     

Mechanically Interlocked Chiral Self-Templated [2]Catenanes from 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Ligands

We report the efficient self-templated formation of optically active 2,6-bis(1,2,3-triazol-4-yl)pyridine ( btp ) derived homocircuit [2]catenane enantiomers. This represents the first example of the enantiopure formation of chiral btp homocircuit [2]catenanes from starting materials consisting of a classical chiral element; X-ray diffraction crystallography enabled the structural characterization of the [2]catenane. The self-assembly reaction was monitored closely in solution facilitating the characterization of the pseudo-rotaxane reaction intermediate prior to mechanically interlocking the pre-organised system via ring-closing metathesis.     

Consonant confusions in white noise

The classic [MN55] confusion matrix experiment (16 consonants, white noise masker) was repeated by using computerized procedures, similar to those of Phatak and Allen (2007). ["Consonant and vowel confusions in speech-weighted noise," J. Acoust. Soc. Am. 121, 2312-2316]. The consonant scores in white noise can be categorized in three sets: low-error set [/m/, /n/], average-error set [/p/, /t/, /k/, /s/, /[please see text]/, /d/, /g/, /z/, /Z/], and high-error set /f/theta/b/, /v/, /E/,/theta/]. The consonant confusions match those from MN55, except for the highly asymmetric voicing confusions of fricatives, biased in favor of voiced consonants. Masking noise cannot only reduce the recognition of a consonant, but also perceptually morph it into another consonant. There is a significant and systematic variability in the scores and confusion patterns of different utterances of the same consonant, which can be characterized as (a) confusion heterogeneity, where the competitors in the confusion groups of a consonant vary, and (b) threshold variability, where confusion threshold [i.e., signal-to-noise ratio (SNR) and score at which the confusion group is formed] varies. The average consonant error and errors for most of the individual consonants and consonant sets can be approximated as exponential functions of the articulation index (AI). An AI that is based on the peak-to-rms ratios of speech can explain the SNR differences across experiments.     

Reflection of plane waves from the boundary of a pre-stressed compressible elastic half-space

The effect of pre-stress on the propagation and reflection ofplane waves in an incompressible isotropic elastic half-spacehas been examined recently by the authors (Ogden & Sotiropoulos,1997). In the present paper the corresponding analysis for compressiblematerials is detailed. In the two-dimensional context consideredfor incompressible materials the (homogeneous) plane waves werenecessarily shear waves. By contrast, in the compressible contextpure shear waves can propagate only in specific directions inthe considered principal plane and, in a general direction,a quasi-shear wave may be accompanied by a quasi-longitudinalwave, as is the case in the anisotropic linear theory. The dependenceof the (in-plane) slowness section on the pre-stress (and finitedeformation) and on the choice of constitutive law is elucidated.This information is used to determine the reflection coefficientsfor reflection of either a (quasi-) shear wave or a (quasi-)longitudinal wave from the boundary of the half-space and tocharacterize the different cases which arise depending on thegeometry of the slowness section. The theoretical results are illustrated by numerical calculationsfor the range of possible types of behaviour with referenceforms of strain-energy function and different states of finitedeformation and to the question of stability of the half-space.