Formation of Azulene-Embedded Nanographene: Naphthalene to Azulene Rearrangement During the Scholl Reaction

Incorporation of a non-hexagonal ring into a nanographene framework can lead to new electronic properties. During the attempted synthesis of naphthalene-bridged double [6]helicene and heptagon-containing nanographene by the Scholl reaction, an unexpected azulene-embedded nanographene and its triflyloxylated product were obtained, as confirmed by X-ray crystallographic analysis and 2D NMR spectroscopy. A 5/7/7/5 ring-fused substructure containing two formal azulene units is formed, but only one of them shows an azulene-like electronic structure. The formation of this unique structure is explained by arenium ion mediated 1,2-phenyl migration and a naphthalene to azulene rearrangement reaction according to an in-silico study. This report represents the first experimental example of the thermodynamically unfavorable naphthalene to azulene rearrangement and may lead to new azulene-based molecular materials.     

Lipase‐Supported Metal–Organic Framework Bioreactor Catalyzes Warfarin Synthesis

A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors.     

Planar AIEgens with Enhanced Solid-State Luminescence and ROS Generation for Multidrug-Resistant Bacteria Treatment

Planar luminogens have encountered difficulties in overcoming intrinsic aggregation-caused emission quenching by intermolecular π-π stacking interactions. Although excited-state double-bond reorganization (ESDBR) can guide us on designing planar aggregation-induced emission (AIE) luminogens (AIEgens), its mechanism has yet been elucidated. Major challenges in the field include methods to efficiently restrict ESDBR and enhance AIE performance without using bulky substituents (e.g., tetraphenylethylene and triphenylamine). In this study, we rationally developed fluoro-substituent AIEgens with stronger intermolecular H-bonding interaction for restricted molecular motions and increased crystal density, leading to decreased nonradiative decay rate by one order of magnitude. The adjusted ESDBR properties also show a corresponding response to variation in viscosity. Furthermore, their aggregation-induced reactive oxygen species (ROS) generations have been discovered. The application of such planar AIEgen in treating multidrug-resistant bacteria has been demonstrated in a mouse model. The relationship between ROS generation and distinct E/Z-configurational stacking behaviors have been further understood, providing a design principle for synthesizing planar AIEgen-based photosensitizers.     

Crystallographic report: Diiodo[tris(2‐pyridyl)amine]mercury(II), [(C5H4N)3N]HgI2

In mononuclear HgI₂[(C₅H₄N)₃N], mercury is tetrahedrally coordinated by two nitrogen atoms of a tris(2‐pyridyl)amine ligand and two iodides. The coordination moieties are connected by weak intermolecular Hg(II)···I interactions to give a one‐dimensional structure. Copyright © 2003 John Wiley & Sons, Ltd.     

审讯过程的数学模型

本文从经济学的观点出发，利用对策论方法建立了审讯过程的数学模型，并由此研究了讯问人三种主要策略对审讯成功的效度。     

正态分布下任意秩有限总体中的Minimax预测

对于任意秩有限总体,在二次损失下,有关文献已给出了线性可预测变量在齐次线性预测类中的唯一线性Minimax预测．本文在正态假设下,证明了这个线性Minimax预测也是线性可预测变量在一切预测类中的唯一Minimax预测．     

Stability of a deflagration front in compressible media

A two-dimensional linear analysis of the planar flame front stability for a compressible fluid is presented. The analysis shows that there are two types of perturbations. The first type, corresponding to waves in incompressible media, has already been studied by Landau. It predicts absolute instability of the flame front. The second type of perturbations is due to fluid compressibility and the dependence on upstream flow parameters of the flame front velocity. Three different regimes for these perturbations are possible: stable, acoustically unstable, and absolutely unstable. The instability results in a pronounced pressure wave generation.A one-dimensional analysis of the interaction of the flame front with flow boundaries is performed. Under some circumstances, this interaction is shown to cause exponential growth of the perturbations.     

Superferromagnetic state of α-Fe in Fe implanted Co6Ag94 studied by Mössbauer spectroscopy

After having introduced by ion implantation ⁵⁷Fe to a local concentration of 7 at% into Co₆Ag₉₄, we observed it by conversion electron Mössbauer spectroscopy in the as-prepared state and after isochronal annealing. A superferromagnetic state is inferred, which is correlated with the ordering of the magnetic moments on the Fe clusters through chain-like or dendritic Co/Fe linear structures. The magnetic moment disordering temperature lies above 473 K.     

NAA of IAEA lake sediment RM SL-3 for 45 elements

45 elements have been determined by NAA in an IAEA Lake Sediment RM SL-3 Multitechniques were used to fully tap the potential of NAA in terms of the number of the determinable elements and the accuracy of each data.