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排序方式: 共有91条查询结果,搜索用时 46 毫秒
1.
在G2 (CC ,MP2 )理论水平上研究了C2 (a3 Πu)自由基与NO分子的反应 .计算了反应体系最低二重态势能面上各驻点的构型参数、振动频率和能量 ,揭示了此反应存在两种反应机理 :由NO中的O原子进攻C2 自由基形成CCON中间体的CCON机理和NO中的N进攻C2 自由基形成CCNO中间体的CCNO机理 ,分析了对应与这两种反应机理的五个可能的反应通道 ,得出了由NO中的N原子进攻3 C2 自由基 ,生成中间体CCNO自由基 ,最终得到产物CN +CO的通道是最有利的通道 . 相似文献
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A nonsmooth Levenberg-Marquard (LM) method with double parameter adjusting strategies is presented for solving vertical complementarity problems based on the computation of an element of a vextor-valued minimum function’s B-differential in this paper. At each iteration, the LM parameter is adjusted based on the norm of the vector-valued minimum function and the ratio between the actual reduction and the predicted reduction. Under the local error bound condition, which is strictly weaker than nonsingular assumption, the local convergence rate is discussed. Finally, the numerical tests indicate that the present algorithm is effective. 相似文献
3.
Yue Sun Dr. Tiandu Dong Dr. Chunxin Lu Weiwen Xin Linsen Yang Pei Liu Yongchao Qian Yuanyuan Zhao Dr. Xiang-Yu Kong Prof. Liping Wen Prof. Lei Jiang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(40):17576-17581
Osmotic energy, obtained through different concentrations of salt solutions, is recognized as a form of a sustainable energy source. In the past years, membranes derived from asymmetric aromatic compounds have attracted attention because of their low cost and high performance in osmotic energy conversion. The membrane formation process, charging state, functional groups, membrane thickness, and the ion-exchange capacity of the membrane could affect the power generation performance. Among asymmetric membranes, a bipolar membrane could largely promote the ion transport. Here, two polymers with the same poly(ether sulfone) main chain but opposite charges were synthesized to prepare bipolar membranes by a nonsolvent-induced phase separation (NIPS) and spin-coating (SC) method. The maximum power density of the bipolar membrane reaches about 6.2 W m−2 under a 50-fold salinity gradient, and this result can serve as a reference for the design of bipolar membranes for osmotic energy conversion systems. 相似文献
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In this paper we obtain a new strong type of Steckin inequality for the linear combinations of Bernstein operators, which gives the optimal approximation rate. Moreover, a method to prove lower estimates for linear operators is introduced. As a result the lower estimate for the linear combinations of Bernstein operators is obtained by using the Ditzian–Totik modulus of smoothness. 相似文献
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In the present paper, we investigate the convergence and the approximation order of the localized Szsz–Mirakjan operators, and obtain some new results to improve the results due to Omey [Note on operators of Szsz–Mirakjan type, J. Approx. Theory 47 (1986) 246–254]. 相似文献
8.
Integrated Photoelectrochemical Solar Energy Conversion and Organic Redox Flow Battery Devices
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Wenjie Li Hui‐Chun Fu Dr. Linsen Li Dr. Miguel Cabán‐Acevedo Prof. Jr‐Hau He Prof. Song Jin 《Angewandte Chemie (International ed. in English)》2016,55(42):13104-13108
Building on regenerative photoelectrochemical solar cells and emerging electrochemical redox flow batteries (RFBs), more efficient, scalable, compact, and cost‐effective hybrid energy conversion and storage devices could be realized. An integrated photoelectrochemical solar energy conversion and electrochemical storage device is developed by integrating regenerative silicon solar cells and 9,10‐anthraquinone‐2,7‐disulfonic acid (AQDS)/1,2‐benzoquinone‐3,5‐disulfonic acid (BQDS) RFBs. The device can be directly charged by solar light without external bias, and discharged like normal RFBs with an energy storage density of 1.15 Wh L?1 and a solar‐to‐output electricity efficiency (SOEE) of 1.7 % over many cycles. The concept exploits a previously undeveloped design connecting two major energy technologies and promises a general approach for storing solar energy electrochemically with high theoretical storage capacity and efficiency. 相似文献
9.
具有存储功能的衍射图像光刻系统的研制 总被引:1,自引:1,他引:0
研制了一种在衍射光变图像器件上进行信息存储的新型数字化激光光刻系统。采用空间光调制器作图形自动输入,双远心投影成像系统在光刻记录面上缩微图形。通过光栅干涉光学头对记录面上的微图形进行干涉调制,使微图形上产生干涉条纹,条纹空间频率范围为500-1200lp/mm。在光刻胶干版上的存储实验表明,在衍射光变图像上的单角度存储信息密度大于3.7Mbit/cm^2。改变干涉条纹取向、条纹间隔和需要存储的图形,光刻系统可实现信息的旋转复用存储。上述光刻系统将会在防伪和衍射光变图像器件制造领域有良好应用。 相似文献
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