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排序方式: 共有937条查询结果,搜索用时 125 毫秒
1.
Peralta Cecilia Mariana Acosta Gimena Henestrosa Cecilia Gil Raúl Andrés Fernández Liliana Patricia 《Journal of Analytical Chemistry》2022,77(3):308-317
Journal of Analytical Chemistry - The present development involved a flow injection strategy using a mini-column of multiwalled carbon nanotubes and fluorescent detection (λex of 283 nm,... 相似文献
2.
L. Resse L.G.S. Oliveira C.I.L. de Araujo A.R. Pereira R.L. Silva 《Physics letters. A》2019,383(14):1655-1659
In this work, we have used the MuMax3 software to simulate devices consisting of a ferromagnetic thin film placed over a heavy metal thin film. The devices are two interconnected partial-disks where a Néel domain wall is formed in the disks junction. In our simulations we investigate devices with disk radius nm and different distance d between the disks centers (from nm to nm). By applying strong sinusoidal external magnetic fields, we find a mechanism able to create, annihilate and even manipulate a skyrmion in each side of the device. This mechanism is discussed in terms of interactions between skyrmion and domain wall. The Néel domain wall formed in the center of the device interacts with the Néel skyrmion, leading to a process of transporting a skyrmion from one disk to the other periodically. Our results have relevance for potential applications in spintronics such as logical devices. 相似文献
3.
4.
Vanessa de Freitas Cunha Lins Geraldo Francisco de Andrade Reis Carlos Roberto de Araujo 《Applied Surface Science》2006,253(5):2875-2884
In this work, electrochemical impedance spectroscopy and linear polarization are used in determining porosity of zinc phosphates, and of nickel and manganese modified zinc phosphates on electrogalvanized steel. The porosity of the phosphate layers ranges from 0.1% for the manganese-modified hopeite to 8% for hopeite, using the linear polarization and the electrochemical impedance spectroscopy techniques. The porosity values measured using the two techniques were in agreement. All impedance spectra of coated samples showed two steps, with two capacitive arcs and an inductive looping. 相似文献
5.
B. F. Araujo H. T. Matsuda T. A. Kuada J. A. Araujo 《Journal of Radioanalytical and Nuclear Chemistry》1992,166(1):75-83
In the actinide separation process using TBP as extractant, hydrolytic and radiolytic reactions cause a gradual decomposition of the extractant, resulting in the formation of degradation products which can affect process performance adversely. The TBP diluent has to be cleaned from these degradation products before it is reused. This paper deals with a procedure for solvent cleanup, using a fourstage continuous contactor for increasing the scrubbing efficiency. 相似文献
6.
Alexander Linkov Liliana Rybarska-Rusinek 《Archive of Applied Mechanics (Ingenieur Archiv)》2008,78(10):821-831
The paper presents a general method to find asymptotics for a (multi-)wedge system containing a thin wedge. It employs separation
of the symmetric and anti-symmetric parts of the boundary displacements and tractions of the wedge. The method is applicable
when the angle of the thin wedge turns to zero. A physical interpretation of the derived equations is obtained by using power
expansions of non-polynomial functions, which appear after the Mellin transform. We establish that the first term in the expansion
of the symmetric part corresponds to shear, while the first term of the anti-symmetric part describes deflection of the wedge
axis. Numerical experiments, performed by using a code developed on the basis of the theory, show that using only the first
terms of the expansions insignificantly influence accuracy: the approximate results coincide with the exact values of roots
to the third significant digit even for the wedge angle of 30°. 相似文献
7.
A simple and easy method of analysis for diclofenac sodium is reported. A spectrofluorometric method for the microdetermination of diclofenac sodium has been developed through its reaction with cerium(IV) in an acidic solution and measurement of the fluorescence of the Ce(III) ions produced. Under the optimum experimental conditions for the oxidation reaction, 1.0 M H2SO4 with 90 min of heating time (100 degrees C), the range of application is 124.3-600 ng mL(-1) and the limit of detection is 72.7 ng mL(-1). The proposed method was applied to the determination of diclofenac sodium in pharmaceutical tablets. The results of the analysis show a good agreement with those obtained by the official USP 27 HPLC method. 相似文献
8.
Cruz A. J. G. Araujo M. L. G. C. Giordano R. C. Hokka C. O. 《Applied biochemistry and biotechnology》1998,(1):579-592
Cephalosporin C production process withCephalosporium acremonium ATCC 48272 in synthetic medium was investigated and the experimental results allowed the development of a mathematical model
describing the process behavior. The model was able to explain fairly well the diauxic phenomenon, higher growth rate during
the glucose-consumption phase, and the production occurring only in the sucrose-consumption phase.
Moreover, the process was simulated utilizing the neural-networks technique. Two feed-forward neural-networks with one hidden
layer were employed. Both models, phenomenological and neural-networks based, satisfactorily describe the bioprocess. The
difficulties in determining kinetic parameters are avoided when neural networks are utilized. 相似文献
9.
The understanding of contact line fluctuations in heterogeneous systems of controlled wettability is relevant to many industrial processes. Despite its importance, it is poorly understood. Here, we present results on an experimental study of fluid displacement on modified Hele-Shaw cells with surface defects as heterogeneities. The system wettability is controlled by defect surface coverage. Three different surface coverage regimes were studied. For each one, the morphology and deformation energy of the displacement front is determined. The width front is described in terms of two exponents, the roughness exponent (alpha) and the one that describes its growth (beta). In all cases, it is found that the width increases logarithmically in time up to a characteristic value, where a crossover to a saturation behavior is observed. The crossover time is a function of the surface coverage. For low coverage 0.51=beta=0.59 and 0.65=alpha=0.67. For medium and high coverage the values obtained for the exponents are similar to those of directed percolation. The deformation energy associated with the displacement front morphology makes it possible to identify the individual pinning role of the surface defects. Copyright 2000 Academic Press. 相似文献
10.
Ana M. Reverdito Liliana Orelli Mnica Dalmaso Isabel Perillo Beatriz M. Fernndez 《Journal of heterocyclic chemistry》1991,28(2):273-281
Reaction of 1,2-diaryl-3-methyl-1,4,5,6-tetrahydropyrimidinium iodides 1a-i with alkaline solutions afforded N-aroyl-N-aryl-N'-methyltrimethylenediamines 2a-i . Compounds 2 are stable under acid conditions but in neutral or alkaline media spontaneously rearrange giving N-aroyl-N'-aryl-N-methyltrimethylenediamines 3a-i . Treating compounds 3 with concentrated acids reverse reaction takes place. Kinetic studies were performed on this intramolecular N → N' aroyl transfer over the Ho-pH range -0.9 to 2.30. Compounds 3 undergo acyl transfer to give 2 by a mechanism which involves a change in the rate determining step from formation to acid-catalysed decomposition of a six-membered heterocyclic intermediate on going from Ho to pH values. The existence of maxima in the pH rate profile allow to determine apparent pKa values of the hexahydropyrimidine intermediates which gave good correlation with the Swain F substituent constants. Stability of these heterocycles was also predicted by determination of thermodinamic parameters. Comparisons are made with the behaviour of five-membered heterocyclic intermediates (imidazolidine derivatives) which were studied in an earlier paper. 相似文献