首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   442篇
  免费   34篇
  国内免费   59篇
化学   326篇
晶体学   2篇
力学   54篇
综合类   7篇
数学   58篇
物理学   88篇
  2023年   12篇
  2022年   15篇
  2021年   19篇
  2020年   26篇
  2019年   17篇
  2018年   16篇
  2017年   10篇
  2016年   18篇
  2015年   28篇
  2014年   15篇
  2013年   32篇
  2012年   30篇
  2011年   38篇
  2010年   19篇
  2009年   23篇
  2008年   28篇
  2007年   21篇
  2006年   38篇
  2005年   24篇
  2004年   14篇
  2003年   12篇
  2002年   6篇
  2001年   4篇
  2000年   10篇
  1999年   8篇
  1998年   5篇
  1997年   13篇
  1996年   10篇
  1995年   3篇
  1994年   6篇
  1993年   1篇
  1992年   5篇
  1991年   3篇
  1988年   1篇
  1987年   1篇
  1986年   2篇
  1982年   1篇
  1981年   1篇
排序方式: 共有535条查询结果,搜索用时 0 毫秒
1.
In this article, we report a technique for growing carbon nanotubes in a more controllable fashion, which enables us to synthesize nanotubes directly in various forms of designed patterns. This nanofabrication process is based on a combination of focused ion beam (FIB) and chemical vapor deposition (CVD) techniques. In this process, arrays of conductive patterns were first deposited on silicon substrates by directing a gaseous compound (C(9)H(16)Pt) via the capillary needle-sized nozzles within a FIB system. The substrates were then coated with catalyst and further modified by the FIB to localize the position of the catalyst. Finally, the growth of carbon nanotubes on the designed substrates was carried out by CVD of hydrocarbon gases. This fabrication technique has the advantage of positioning carbon nanotubes in selected locations. This may open up opportunities for the direct synthesis of carbon nanotubes onto almost any substrate material, thus allowing fabrication of carbon nanotube-based devices.  相似文献   
2.
报告了143例沈阳市健康人血清中Mg、Zn、Cu、Se、Cr含量及Cu/Zn值,并指出健康人血清中Mg与Cu量正相关,Mg与Cr呈负相关,Mg与Cu/Zn值呈正相关.Zn与Cr呈正相关.Zn与Cu/Zn呈负相关.Cu与Cr呈负相关。Cu与Cu/Zn值呈负相关.Cr与Cu/Zn值呈负相关.  相似文献   
3.
The mode of adsorption of bovine serum albumin (BSA) on porous polyethylene (PE) membrane was studied as a function of time and concentration, which may contribute to the surface coverage. An improved physical model for adsorption is initiated based on the results of the adsorptional and desorptional measurements, FTIR analysis, and AFM observations as well as streaming potential measurements. The results obtained indicate that the adsorptional mode depend on both time and concentration. It is shown that a critical concentration (about 1000 ppm here) exists in the adsorptional process. Below this concentration, the adsorption seems to be conducted in a normal side-on way but time elapse gives rise to greater conformational change than concentration increase; above this concentration, the aggregation of protein molecular plays a decisive role and the adsorption is in an aggregation way, which is similar to end-on, but a relative large gap between the adsorbed molecules exists due to aggregation. This conclusion is general and can be expected to apply in other globular protein-hydrophobic porous surface systems.  相似文献   
4.
Low-temperature growth and photoluminescence property of ZnS nanoribbons   总被引:2,自引:0,他引:2  
At a low temperature of 450 degrees C, ZnS nanoribbons have been synthesized on Si and KCl substrates by a simple chemical vapor deposition (CVD) method with a two-temperature-zone furnace. Zinc and sulfur powders are used as sources in the different temperature zones. X-ray diffraction (XRD), selected area electron diffraction (SEAD), and transmission electron microscopy (TEM) analysis show that the ZnS nanoribbons are the wurtzite structure, and there are two types-single-crystal and bicrystal nanoribbons. Photoluminescence (PL) spectrum shows that the spectrum mainly includes two parts: a purple emission band centering at about 390 nm and a blue emission band centering at about 445 nm with a weak green shoulder around 510 nm.  相似文献   
5.
Abstract. In this paper, for any continuous function  相似文献   
6.
A new zirconia-based stationary phase (DPZ) was prepared by modifying zirconia with dodecylamine-N,N-dimethylenephosphonic acid (DDPA). DDPA was adsorbed on zirconia with only one phosphonic group, with the other being free. Besides the hydrophobic interaction provided by nonpolar dodecyl, DPZ also has dipolar interaction, ion-exchange or electrostatic repellent interaction provided by the free phosphonic group and amino group at different conditions. Separation of bases on this stationary phase was achieved with satisfaction owing to the various retention mechanisms. The influence of methanol content, pH value, ion types, and ionic strength of mobile phase are studied in detail. Translated from Chinese Journal of Chromatography, 2005, 23(1) (in Chinese)  相似文献   
7.
高质量的前驱粉是制备高性能Bi-2212线材的基础.本文采用化学燃烧法制备纳米级Bi-2212前驱粉末,分析了Bi-2212纳米粉末的成相过程以及微观形貌,结果表明可以成功制备尺寸小于100 nm的氧化粉末,经过热处理后得到纯的Bi-2212成相粉.与传统共沉淀方法的前驱粉末相比,纳米生粉反应活性更高,Bi-2212成相温度降低,转化效率更高.该方法有利于实现高质量的Bi-2212前驱粉末的批量制备.  相似文献   
8.
We propose and demonstrate a polarization diversity two-dimensional grating coupler based on the lithium niobate on insulator platform, for the first time, to the best of our knowledge. The optimization design, performance characteristics,and fabrication tolerance of the two-dimensional grating coupler are thoroughly analyzed utilizing the three-dimensional finite-difference time-domain method. Experimentally,-7.2 d B of coupling efficiency is achieved with 1 d B bandwidth of64 nm. The polarization-dependent loss is about 0.4 d B around 1550 nm. Our work provides new polarization multiplexing approaches for the lithium niobate on insulator platform, paving the way for critical applications such as high-speed polarization multiplexed electro-optical modulators.  相似文献   
9.
热振动是一定温度下纳尺度结构的固有运动,对其动力学行为有着重要的影响. 当空间进入纳米尺度,结构呈现离散性,量子效应、边界效应、范德华力等变得不可忽略,纳尺度结构在热噪声随机激励下的动力学行为表现出众多异乎寻常的特性. 以碳纳米管和石墨烯为代表的纳尺度碳材料具有优良的力学、电学和化学性质. 在此介绍多种针对纳尺度结构热振动问题的研究方法、及碳纳米管和石墨烯的低温热振动、碳纳米管的非线性热振动研究进展.  相似文献   
10.
范立峰  丁昊  王梦 《力学与实践》2023,45(2):454-460

岩石力学作为一个重要的力学分支,是土木工程、水利水电、采矿工程等应用型学科的重要基础。本文首先调研了岩石力学教学中存在的难点,分析了数值仿真技术在教学中的优势。随后,以岩石单轴压缩实验为例,采用图像采集与颗粒流模拟相结合的数值仿真技术,演示了岩石瞬态破坏过程,揭示了岩石在受到外力时的破坏方式和破坏机理。表明了数值仿真技术在岩石力学教学中具有“全尺度、全维度、全时程”等优点。展示了数值仿真技术在描述岩石破坏过程中形象、直观的教学效果。

  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号