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Xu-Feng Tan Li-Yong Yuan Chang-Ming Nie Kui Lui Zhi-Fang Chai Wei-Qun Shi 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(1):281-288
Electrochemical behaviors of U(VI) in 1-butyl-3-methylimidazolium chloride (C4MimCl) with various water contents investigated by chronopotentiometry and cyclic voltammetry. The electrochemical reduction of U(VI) was identified to follow two processes: a lower valence intermediate U(V) was initially formed at the potential of ca. ?0.2 V(vs. Ag wire). Then, further deposition of UO2 was followed at around ?0.8 V. Little amount of water (1–4 wt%) in C4MimCl, however, has an effect on the U(VI) reduction by changing the current density of the redox reaction and the diffusion coefficient of U(VI) in C4MimCl. The deposited product by potentiostatic electrolysis on the surface of stainless steel electrode was characterized by the scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) methods. Although the electrodeposited black film was amorphous, the electrochemical reduced product of U(VI) can be still confirmed to be UO2 by XRD after the crystallization of the amorphous deposits at 1,073 K in nitrogen atmosphere. 相似文献
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分析了单模光纤中双宽带抽运的受激布里渊散射 (stimulated Brillouin scattering,SBS) 光速减慢效应.模拟了两高斯型宽带抽运光同时作用下的SBS增益谱和损耗谱,提出了一种获得均匀增益谱的方法.由于较强抽运光增益谱的中心频率与较弱抽运光损耗谱的中心频率相重合,通过调节较弱抽运光的功率和谱宽,能够部分地抵消掉较强增益谱的顶部从而构建出平坦的增益谱.研究了该平顶增益情形下信号脉冲畸变的性质.与单宽带抽运下脉冲畸变的对比表明,这种产生平顶增益谱的方法能有效地减小脉冲畸变.
关键词:
慢光
受激布里渊散射(SBS)
单模光纤
脉冲失真 相似文献
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研制了一个改进的激波管设备,对马赫数为1.2的弱激波冲击作用下空气中SF6气柱和气帘界面的演变过程进行了初步的实验研究。通过设计激波管实验段、烟雾发生器、气体箱、进气吸气系统和激波管尾段,控制混合气体中SF6的峰值浓度和初始气流速度,建立了稳定、可重复的无膜气柱和气帘初始界面形成技术。利用高速摄影技术,在水平面内观测了气柱和气帘的初始界面图像,沿垂直方向观测了界面RM(Richtmyer-Meshkov)不稳定性的演变过程。气柱演变图像显示了典型的对涡结构,气帘演变图像显示了早期的多蘑菇形结构和后期的相邻波长干扰效应。图像后处理表明,气柱的高度和宽度、气帘的宽度均随时间单调增加,且宽度比高度增加快得多。从二维涡量动力学方程出发,对图像中涡的演变过程进行了初步解释。 相似文献
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The influences of the acoustic impedance and shock strength on the jet formation in shock-heavy gas bubble interaction are numerically studied in this work. The process of a shock interacting with a krypton or a SF 6 bubble is studied by the numerical method VAS2D. As a validation, the experiments of a SF 6 bubble accelerated by a planar shock were performed. The results indicate that, due to the mismatch of acoustic impedance, the way of jet formation in heavy gas bubble with different species is diversified under the same initial condition. With respect to the same bubble, the manner of jet formation is also distinctly different under different shock strengths. The disparities of the acoustic impedance result in different effects of shock focusing in the bubble, and different behaviors of shock wave inside and outside the bubble. The analyses of the wave pattern and the pressure variation indicate that the jet formation is closely associated with the pressure perturbation. Moreover, the analysis of the vorticity deposition, and comparisons of circulation and baroclinic torque show that the baroclinic vorticity also contributes to the jet formation. It is concluded that the pressure perturbation and baroclinic vorticity deposition are the two dominant factors for the jet formation in shock-heavy gas bubble interaction. 相似文献
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采用改进化学汽相沉积结合溶液掺杂法制备了掺镱石英光纤预制棒,并研究了不同镱掺杂浓度下的吸收光谱和发光光谱.吸收光谱和发光光谱的强度随着YbCl3溶液浓度的增大而增强.在不产生失透的前提下,得到预制棒芯层能够掺杂的YbCl3溶液最大浓度为0.057 mol/L. 相似文献
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Lan JH Shi WQ Yuan LY Feng YX Zhao YL Chai ZF 《The journal of physical chemistry. A》2012,116(1):504-511
A thermodynamic investigation has been performed to study the complexation of trivalent metal (M) ions (M = Am(III), Eu(III)) with tetradentate ligands (L), 6,6'-bis(5,6-dialkyl-1,2,4-triazin-3-yl)-2,2'-bipyridines (BTBPs), by using relativistic quantum mechanical calculations. The structures and stabilities of the inner-sphere BTBPs complexes were explored in the presence of various counterions such as NO(3)(-), Cl(-), and ClO(4)(-). According to our calculations, Am(III) and Eu(III) can chelate eight or nine water molecules at most, whereas more stable species like M(NO(3))(3)(H(2)O)(4) tend to be formed in the presence of nitrate ions. The inner sphere of the BTBPs complexes can accommodate four water molecules or three nitrate ions based on our calculations, forming species such as [ML(H(2)O)(4)](3+) and ML(NO(3))(3). Compared with Eu(III) complexes, the Am(III) counterparts have obviously lower binding energies in both the gas phase and solution. In addition, the solvent effect significantly decreases the binding energies of the BTBPs complexes. It has been found that the complexing reactions, in which products and reactants possess the same or close number of nitrate ions, are more favorable for formation of the BTBPs complexes. In short, the reactions of M(NO(3))(3)(H(2)O)(4) → ML(NO(3))(3) and [M(NO(3))(H(2)O)(7)](2+) → [ML(2)(NO(3))](2+) are probably the dominant ones in the Am(III)/Eu(III) separation process. 相似文献