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Seliverstov AN Suleimanov EV Chuprunov EV Somov NV Zhuchkova EM Lelet MI Rozov KB Depmeier W Krivovichev SV Alekseev EV 《Dalton transactions (Cambridge, England : 2003)》2012,41(28):8512-8514
Three new uranyl tungstates, α-, β-Cs(2)[(UO(2))(2)(W(2)O(9))], and Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)], have been obtained by high temperature solid state reactions. All three compounds display novel structure topologies: α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] are based upon layers with a new topology that can be related to the uranophane topology; Rb(6)[(UO(2))(7)(WO(5))(2)(W(3)O(13))O(2)] is a rare example of a non-molecular inorganic phase with layers containing oxo-tungstate trimers. The structural relationship between α- and β-Cs(2)[(UO(2))(2)(W(2)O(9))] can be assigned to polytypism. 相似文献
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Nipruk O. V. Chernorukov N. G. Bakhmetiev M. O. Elipasheva E. V. Lelet M. I. Chaplieva K. A. 《Russian Journal of General Chemistry》2019,89(8):1630-1636
The interaction of hydrated uranium(VI) oxide UO3·2.25H2O (schoepite) with an aqueous solution of rubidium hydroxide in an autoclave at 100°C has yielded rubidium uranate Rb2(UO2)6O3(OH)8·6H2O. Composition and structure of the obtained compound have been determined by chemical analysis, IR spectroscopy, X-ray diffraction, and differential thermal analysis. The processes of its dehydration and thermal decomposition have been studied.
相似文献3.
Knyazev A. V. Shipilova A. S. Lelet M. I. Knyazeva S. S. Gusarova E. V. Amosov A. A. 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2020,94(1):23-29
Russian Journal of Physical Chemistry A - In the present work temperature dependence of heat capacity of inulin has been measured for the first time in the range from 5 to 340 K by precision... 相似文献
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